Modeling and Control of Batch Processes presents state-of-the-art techniques ranging from mechanistic to data-driven models. These methods are specifically tailored to handle issues pertinent to batch processes, such as nonlinear dynamics and lack of online quality measurements. In particular, the book proposes: a novel batch control design with well characterized feasibility properties; a modeling approach that unites multi-model and partial least squares techniques; a generalization of the subspace identification approach for batch processes; and applications to several detailed case studies, ranging from a complex simulation test bed to industrial data. The book's proposed methodology employs statistical tools, such as partial least squares and subspace identification, and couples them with notions from state-space-based models to provide solutions to the quality control problem for batch processes. Practical implementation issues are discussed to help readers understand the application of the methods in greater depth. The book includes numerous comments and remarks providing insight and fundamental understanding into the modeling and control of batch processes. Modeling and Control of Batch Processes includes many detailed examples of industrial relevance that can be tailored by process control engineers or researchers to a specific application. The book is also of interest to graduate students studying control systems, as it contains new research topics and references to significant recent work. Advances in Industrial Control reports and encourages the transfer of technology in control engineering. The rapid development of control technology has an impact on all areas of the control discipline. The series offers an opportunity for researchers to present an extended exposition of new work in all aspects of industrial control.

Many cooling systems use water as cooling medium. They are found in public buildings, industrial production systems or power plants. Almost every cooling system using water is degraded by deposition, corrosion and microbiological fouling.

This book identifies the whole bunch of problems due to water cooling systems and proposes specific solutions to all of them. The authors have an expertise of over 20 years solving cooling water problems. In this book, they advise all practitioners which need to plan, buy or operate cooling systems.

Hydrogen fuel cells are emerging as a major alternative energy source in transportation and other applications. Central to the development of the hydrogen economy is safe, efficient and viable storage of hydrogen. Solid-state hydrogen storage: Materials and chemistry reviews the latest developments in solid-state hydrogen storage.
Part one discusses hydrogen storage technologies, hydrogen futures, hydrogen containment materials and solid-state hydrogen storage system design. Part two reviews the analysis of hydrogen interactions including structural characterisation of hydride materials, neutron scattering techniques, reliably measuring hydrogen uptake in storage materials and modelling of carbon-based materials for hydrogen storage. Part three analyses physically-bound hydrogen storage with chapters on zeolites, carbon nanostructures and metal-organic framework materials. Part four examines chemically-bound hydrogen storage including intermetallics, magnesium hydride, alanates, borohydrides, imides and amides, multicomponent hydrogen storage systems, organic liquid carriers, indirect hydrogen storage in metal ammines and technological challenges in hydrogen storage.
With its distinguished editor and international team of contributors, Solid-state hydrogen storage: Materials and chemistry is a standard reference for researchers and professionals in the field of renewable energy, hydrogen fuel cells and hydrogen storage.
Assesses hydrogen fuel cells as a major alternative energy sourceDiscusses hydrogen storage technologies and solid-state hydrogen storage system designExplores the analysis of hydrogen interactions including reliably measuring hydrogen uptake in storage materials

This unique thesis discusses the development of conceptually novel and synthetically valuable methods that use visible light photocatalysis. Each chapter addresses a different topic in the emerging field of photocatalysis, which has become an indispensable tool for organic synthesis. Photocatalysis employs environmentally harmless and abundant visible light in the presence of a photosensitizer, and as such offers an attractive alternative to harmful UV light in photo-mediated reactions. This book introduces the novel concept of merging gold catalysis with visible light photocatalysis in a dual catalytic fashion, which demonstrates their compatibility with each other for first time and has inspired the development of various reactions. Moreover, a novel trifluoromethylation method, which combines radical addition chemistry with a polar rearrangement to synthesize valuable fluorinated compounds, is presented, since compounds featuring fluorinated functionality are the subject of increasing attention in pharmaceutical, agrochemical and material research. It also develops an external photocatalyst-free photochemical method for the synthesis of valuable indolizine heterocycles, where the product mediates its own formation. Lastly, it describes the synthesis and characterization of two novel highly porous metal-organic frameworks (MOFs). The comprehensive text is rounded out with illustrations and color figures.

Special distillation processes are required for separation of mixtures close to boiling point or for forming azeotrope mixtures into their pure components. In Special Distillation Processes, the authors focus on latest developments in the field, such as separation methods that may prove useful for solving problems encountered during research. Topics include extraction, membrane and adsorption distillation involving the separation principle, process design and experimental techniques. The relationship between the processes and the techniques are also presented. Comprehensive and easy-to-read, this book provides key information needed to understand the processes and is a valuable reference source for chemical engineers as well as students wishing to branch out in chemical engineering.
* The only comprehensive book available on special distillation processes
* Contains a thorough introduction to recent developments in the field
* A valuable reference for students and engineers in chemical engineering

This book treats modeling and simulation in a simple way, that builds on the existing knowledge and intuition of students. They will learn how to build a model and solve it using Excel. Most chemical engineering students feel a shiver down the spine when they see a set of complex mathematical equations generated from the modeling of a chemical engineering system. This is because they usually do not understand how to achieve this mathematical model, or they do not know how to solve the equations system without spending a lot of time and effort. Trying to understand how to generate a set of mathematical equations to represent a physical system (to model) and solve these equations (to simulate) is not a simple task. A model, most of the time, takes into account all phenomena studied during a Chemical Engineering course. In the same way, there is a multitude of numerical methods that can be used to solve the same set of equations generated from the modeling, and many different computational languages can be adopted to implement the numerical methods. As a consequence of this comprehensiveness and combinatorial explosion of possibilities, most books that deal with this subject are very extensive and embracing, making need for a lot of time and effort to go through this subject. It is expected that with this book the chemical engineering student and the future chemical engineer feel motivated to solve different practical problems involving chemical processes, knowing they can do that in an easy and fast way, with no need of expensive software.

The book covers a wide range of materials used in biocomposite products, from biopolymer, wood fiber, wood, and non-wood species. It discusses the preparation of the material, processing and end applications, and also reviews wood quality improvement through different types of treatments.

Understanding and modeling the kinetics of chemical reactions is crucial to any research and development effort aimed at process optimization and innovation. This volume provides four complementary points of view. It reflects state-of-the-art developments as well as views on the way to proceed by reporting on the efforts of a representative, sample of research and development groups.
A first contribution by W.H. Green Jr. sets the scene. The author advocates a paradigm shift in chemical kinetics from "postdictive" to predictive models.
The contribution from the Politecnico di Milano reports on the tremendous experience accumulated over the years in the field of steam cracking, one of the largest scale production processes of the petrochemical industry. The Russian school of chemical kinetics is represented by a chapter on oxidation of alkanes, this contribution addresses more "philosophical" issues. The last chapter gives an indication of the state-of-the-art in an industrial environment.
* Provides original reviews
* Presents leading chemical engineers as authors
* Reviews state-of-the-art developments

Evolving technologies in mass production have led to the development of advanced techniques in the field of manufacturing. These technologies can quickly and effectively respond to various market changes, necessitating processes that focus on small batches of multiple products rather than large, single-product lines. Formal Methods in Manufacturing Systems: Recent Advances explores this shifting paradigm through an investigation of contemporary manufacturing techniques and formal methodologies that strive to solve a variety of issues arising from a market environment that increasingly favors flexible systems over traditional ones. This book will be of particular use to industrial engineers and students of the field who require a detailed understanding of current trends and developments in manufacturing tools. This book is part of the Advances in Civil and Industrial Engineering series collection.

The tracer method was first introduced to measure the actual flow of fluid in a vessel, and then to develop a suitable model to represent this flow. Such models are used to follow the flow of fluid in chemical reactors and other process units, in rivers and streams, and through soils and porous structures. Also, in medicine they are used to study the flow of chemicals, harmful or not, in the blood streams of animals and man.

Tracer Technology, written by Octave Levenspiel, shows how we use tracers to follow the flow of fluids and then we develop a variety of models to represent these flows. This activity is called tracer technology.

Written by one of the most prolific and well-respected chemical engineers in the industry, this is the most comprehensive and thorough volume ever written on the thermodynamic properties of hydrocarbons and chemicals. This volume covers the spectrum, including chapters on the heat capacity and entropy of gas, solids and liquids, the entropy of formation, and many other topics. The design of heat exchangers and other equipment for heating or cooling substances to temperatures necessary in process applications requires knowledge of heat capacity, covered in the first portion of the book. The heat effects of chemical reactions are ascertained from enthalpy of formation. Other chapters cover the Helmholtz energy of formation and internal energy of formation, which is useful in modeling and ascertaining the energy of explosions. This coverage greatly exceeds the coverage of any other book and makes "The Yaws Handbook of Thermodynamic Properties of Hydrocarbons and Chemicals" a must-have for anyone working in the fields of chemical engineering, process engineering, refining and chemistry.

This book covers all major areas of operation, pollution control, safety, modernization, diversification, and resource management for cost control in the industrial production of chemicals. The author details the importance of obtaining the right type of raw materials and equipment for maximum plant efficiency and discusses revival of plants that have been idle for long periods. He also presents important issues concerning product quality, energy recovery, safety, pollution control and improving profitability by proper management of resources. The book is ideal for shop floor engineers, middle level management, and owners of small- and medium-scale facilities in many countries as it serves as a guide for keeping the plant operations running in adverse situations, for reducing energy consumption; improving profitability, resource allocation, and workforce planning.

This valuable guide to compounding elastomers with precipitated silica covers principles, properties, mixing, testing and formulations from a practical perspective. This handbook and reference manual will serve those who work on part design, elastomer formulation, manufacturing and applications of elastomers. Ample discussion of compound specifications adds to the usefulness of this book to practitioners. Comparisons of carbon black and silica compounds throughout the book allow readers to select the most suitable formulation for applications ranging from tires to electrical insulation to shoe soles. The author has over forty years of experience in the rubber industry highlighted by his 39 years at the PPG Rubber Research laboratories. A highlight of the book is the inclusion of studies conducted by the author which greatly adds to the richness of the contents.

This book describes different approaches for solving industrial problems like product design, process optimization, quality enhancement, productivity improvement and cost minimization. Several optimization techniques are described. The book covers case studies on the applications of classical as well as evolutionary and swarm optimization tools for solving industrial issues. The content is very helpful for industry personnel, particularly engineers from the Operation, R&D and Quality Assurance sectors, and also the academic researchers of different engineering and/or business administration background.

The theme of the present volume is Computational Fluid Dynamics (CFD) and aims to show the state-of-the-art of the application of CFD in chemical engineering.
The volume is made up of five complementary contributions, providing a style of between a tutorial and a research paper. Some contributions are entirely limited to velocity and temperature fields. Others emphasize the difficulties associated with the combination of transport and reaction.
Contributions include dealing with the simulation of gas-liquid bubble columns and gas-liquid-solid fluidized beds. Addressing the different levels of modeling that are required in order to cover the full spectrum of length scales that are important for industrial applications. Stirred turbulent vessels and the chemical reactions. The importance of chemical reaction kinetics and the interaction with transport phenomena. Finally, looking at reactor engineering: the catalytic fixed bed reactor.
* Original reviews
* Leading chemical engineers as authors
* Reviewing the state-of-the-art of Computational Fluid Dynamics (CFD)

Volume 2 of the updated and extended 3rd edition of this work focuses on the chemistry and technology of rigid polyurethanes. Recent developments in obtaining polyols from renewable resources and the field of rigid polyurethanes have been included. This book is of interest to chemists and engineers in industry and academia as well as anyone working with polyols for the manufacture of PUs.

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Polyvinyl chloride (PVC) is one of the most versatile and widely used polymers, with applications as diverse as doors and window frames, flooring, piping, electric wire insulation, toys, food packaging and car interiors.

In this book, George Wypych has brought together in one place the core data and reference information needed by PVC manufacturers, processors, and users:

Polymer properties and data for material selection

Reference data on the 23 groups of additives are used in PVC processing to improve its properties and obtain the set of product characteristics required by the end-user.

A comprehensive collection of 500 formulations compiled from recent patents, journal articles, and information from suppliers. A broad selection of formulations is used in each category to determine the essential components of formulations used in a particular method of processing, the most important parameters of successful products, troubleshooting information, and suggestions of further sources of information on the method of processing.

Data on PVC and its products: general data and nomenclature, chemical composition and properties, physical properties, mechanical properties, health and safety, environmental information, use and application information.
A comprehensive and data-rich guide to PVC and its additives

Essential reference data for scientists and engineers involved in the design and production of PVC products, and their applications across a range of sectors such as construction and packaging

Includes over 500 formulations: a unique data set

The 5th volume of Green Chemical Processing considers sustainable chemistry in the context of governmental and corporate interests, explaining how "red tape" can help or hinder the "greening" of industry processes. The American Chemical Society's 12 Principles of Green Chemistry are woven throughout this text as well as the series to which this book belongs.

I: Perfumery as An Art.- 1: The Art of Perfumery.- II: Perfumery as A Topic in Life Sciences.- 2: Odours and Perfumes as a System of Signs.- 3: Semiochemicals: Mevalogenins in Systems of Chemical Communication.- 4: Origin of Natural Odorants.- 5: A Consideration of Some Psychological and Physiological Mechanisms of Odor Perception.- III: Trapping and Measuring of Odours.- 6: The Measuring of Odors.- 7: Trapping, Investigation and Reconstitution of Flower Scents.- IV: Classification of Odours.- 8: Empirical Classification of Odours.- 9: Chemical Classification and Structure-Odour Relationships.- V: Compository Techniques and Application Segments.- 10: Creative Perfumery: Composition Techniques.- 11: Support Materials for Odorant Mixtures.- 12: Perfumery Applications: Functional Products.- 13: The Impact of Market Research.- VI: Production of Perfumes.- 14: The Chemistry of Synthetic Raw Materials Production.- 15: Compounding.- 16: The Toxicology and Safety of Fragrances.- 17: The Fragrance Industry in a Changing World.- VII: Topics in Perfumery Research.- 18: Receptors: Current Status and Future Directions.- 19: Natural Products.- 20: Synthetic Products.- Outlook.- List of Contributors.

In recent years the use of liquid—liquid extraction equipment has attracted widespread interest from all major chemical engineering, petroleum and pharmaceutical companies as well as university-based scientists and engineers. Liquid—Liquid Extraction Equipment presents :

• a critical analysis of all available information, including practical recommendations
• new ideas on performance enhancement and equipment selection
• an up-to-date review of research results on equipment performance
• illustrations of present understanding using well-known equipment
• a concise survey of past, present and forthcoming procedures

The Role of Metals and Ligands in Organic Hydroformylation, by Luca Gonsalvi, Antonella Guerriero, Eric Monflier, Frederic Hapiot, Maurizio Peruzzini.

Hydroformylation in Aqueous Biphasic Media Assisted by Molecular Receptors, by Frederic Hapiot, Herve Bricout, Sebastien Tilloy, Eric Monflier.

Asymmetric Hydroformylation, by Bernabe F. Perandones, Cyril Godard, Carmen Claver.

Domino Reactions Triggered by Hydroformylation, by Elena Petricci, Elena Cini.

Rhodium-Catalyzed Hydroformylation in Fused Azapolycycles Synthesis, by Roberta Settambolo.

Hydroformylation in Natural Product Synthesis, by Roderick W. Bates, Sivarajan Kasinathan."

As the availability of fossils fuels becomes more limited, the negative impact of their consumption becomes an increasingly relevant factor in our choices with regards to primary energy sources. The exponentially increasing demand for energy is reflected in the mass generation of by-products and waste flows which characterize current society's development and use of fossil sources. The potential for recoverable material and energy in these ever-increasing refuse flows is huge, even after the separation of hazardous constituent elements, allowing safe and sustainable further exploitation of an otherwise 'wasted' resource. Fuel Cells in the Waste-to-Energy Chain explores the concept of waste-to-energy through a 5 step process which reflects the stages during the transformation of refuse flows to a valuable commodity such as clean energy. By providing selected, integrated alternatives to the current centralized, wasteful, fossil-fuel based infrastructure, Fuel Cells in the Waste-to-Energy Chain explores how the concept of waste-to-energy can be constructed and developed into a realistic solution. The entire spectrum of current and future energy problems is illuminated through the explanation of the operational, integration and marketing implications of high efficiency technological solutions using the real context of developed regions such as Europe. Up-to-date reviews are provided on the status of technology and demonstration, implementation and marketing perspectives. The detailed technological information and insight gathered from over twenty years of experience in the field makes Fuel Cells in the Waste-to-Energy Chain a valuable resource for all engineers and researchers in the fields of energy supply systems and waste conversion, as well as providing a key reference for discussions by policy makers, marketing experts and industry developers working in energy supply and waste management.