Each chapter in this volume is focused on a specific set of solvent properties which determine its choice, effect on properties of solutes and solutions, properties of different groups of solvents and the summary of their applications' effect. This includes effectson health and environment (given in tabulated form), swelling of solids in solvents, solvent diffusion and drying processes, nature of interaction of solvent and solute in solutions, acid-base interactions, effect of solvents on spectral and other electronic properties of solutions, effect of solvents on rheology of solution, aggregation of solutes, permeability, molecular structure, crystallinity, configuration, and conformation of dissolved high molecular weight compounds, methods of application of solvent mixtures to enhance the range of their applicability, and effect of solvents on chemical reactions and reactivity of dissolved substances.
Provides key insight to help engineers and scientists select the best solvent for the jobPractical information and ideas to improve existing processes involving solventsBrings together the latest advances in solvent technology and applications"

This book introduces readers to gas flows and heat transfer in pebble bed reactor cores. It addresses fundamental issues regarding experimental and modeling methods for complex multiphase systems, as well as relevant applications and recent research advances. The numerical methods and experimental measurements/techniques used to solve pebble flows, as well as the content on radiation modeling for high-temperature pebble beds, will be of particular interest. This book is intended for a broad readership, including researchers and practitioners, and is sure to become a key reference resource for students and professionals alike.

This book provides a detailed explanation of the cold spray process from a practical standpoint. Drawing on the authors' 36 years of research and development experience, it is firmly rooted in theory but also substantiated by empirical data and practical knowledge, offering potential users the information they need to recognize the advantages, as well as the limitations, of cold spray. This sets it apart from previous works on the subject, which have been purely academic. Cold spray technology has made great dramatic strides over the last 10 years and is now being used extensively in the aerospace, electronics, automotive, medical, and even the petrochemical industries. Most recently, cold spray of near-net shaped parts was accomplished - something previously assumed to be impossible because of the limitations of commercially available cold spray systems and a lack of fundamental understanding regarding the process. The cost of cold spray has also declined, making it appealing to industry through the introduction of new powders, surface preparation techniques, and recovery systems tailored to the cold spray process. Though primarily intended for users of the technology, this handbook is also a valuable resource for researchers interested in advances in cold spray materials, improved feedstock powders, advanced hardware and software development, surface preparation techniques, and the numerous applications developed to date. For example, cold spray aluminum alloys have been developed that offer the strength and ductility of wrought material in the as-sprayed condition. This has yet to be achieved by conventional powder consolidation methods including laser sintering, electron beam, and ultrasonic techniques. Other topics covered include additive manufacturing, structural repair, nondestructive evaluation, advanced cold spray materials, qualification requirements, cold spray systems comparison, and, finally, helium recovery. Thanks to its practical focus, the book provides readers with everything they need to understand, evaluate, and implement cold spray technology.

PARTIAL CONTENTS - PART - I. BOILER BASICS - Chapter 1. Boiler - An Introduction - Chapter 2. Classification of Boilers - Chapter 3. Common Terms and Explanation - PART - II. BOILER WATER TROUBLES - Chapter 4. Impurities in Water and Their Effects - Chapter 5. Boiler Water Troubles - A Prelude - Chapter 6. Scale Formation - Chapter 7. Silica Carryover - Chapter 8. Scale Formation in Economizers - Chapter 9. Super Heater and Turbine Deposits - Chapter 10. Corrosion - Basic Information - Chapter 11. General Corrosion (Overall Corrosion / Acidic Corrosion) - Chapter 12. Dissolved Oxygen Corrosion (Pitting Corrosion) - Chapter 13. Carbondioxide Corrosion - Chapter 14. Corrosion caused by Unstable Salts - Chapter 15. Corrosion caused by Other Substances - Chapter 16. Corrosion caused by Chelants (Chelant Corrosion) - Chapter 17. Caustic Embrittlement and Caustic Gouging - Chapter 18. Hydrogen Embrittlement - Chapter 19. Condensate Corrosion - Chapter 20. Preboiler Corrosion - Chapter 21. Economizer Corrosion - Chapter 22. Super Heater and Turbine Corrosion - Chapter 23. Foaming, Priming & Carryover - PART - III. WATER QUALITY REQUIREMENTS AND TREATMENT PROGRAMS - Chapter 24. Quality Requirements for Feed Water and Boiler Water - Chapter 25. Objectives of Boiler Water Treatment - Chapter 26. External Treatment and Internal Treatment - Chapter 27. Water Treatment programs - Guidelines - PART - IV. EXTERNAL TREATMENT - Chapter 28. External Treatment - A Prelude - Chapter 29. Coagulation (Removal of Color, Turbidity and Suspended Matter) - Chapter 30. Filtration - Chapter 31. Softening by Chemical Method (Lime - Soda Softening) - Chapter 32. Ion Exchange Resins and Treatment Methods - Chapter 33. Softening by Ion-Exchange Method - Chapter 34. Dealkalization - Chapter 35. Demineralization (Deionization) - Chapter 36. Mixed Bed Deionization - Chapter 37. Reverse Osmosis - Chapter 38. Evaporation - Chapter 39. Silica Removal - Chapter 40. Oil Removal - Chapter 41. Condensate Treatment (Condensate Polishing) - Chapter 42. Deaeration (Mechanical Removal of Oxygen) - PART - V. INTERNAL TREATMENT - Chapter 43. Internal Boiler Water Treatment - A Prelude - Chapter 44. Organic Polymers and Their Role as Scale Inhibitors, Dispersants and Sludge Conditioners in Boiler Water Treatment - Chapter 45. Internal Treatment - Chemical Feeding - Chapter 46. Prevention of Scale Formation - Chapter 47. Sludge Conditioning - Chapter 48. Prevention of Corrosion - An Introduction - Chapter 49. Prevention of Corrosion Due to Low pH - Chapter 50. Prevention of Pitting Corrosion Using Oxygen Scavengers (Chemical Removal of Oxygen) - Chapter 51. Prevention of Caustic Embrittlement and Caustic Gouging - Chapter 52. Prevention of Chelant Corrosion - Chapter 53. Prevention of Condensate Corrosion - Chapter 54. Prevention of Pre-Boiler Corrosion - Chapter 55. Prevention of Economizer Corrosion - Chapter 56. Prevention of Foaming, Priming & Carryover - Chapter 57. Prevention of Silica Carryover - Chapter 58. Boiler Blow Down - PART - VI. BOILER WATER TREATMENT - IMPORTANT CALCULATIONS - Chapter 59. Basic Conversion Factors - Chapter 60. Water Softening - Calculations - Chapter 61. Cycles of Concentration, Blowdown, Feed Water and Makeup Water - Calculations - Chapter 62. Determination of Dosage of Chemicals - PART - VII. BOILER START UP, CLEANING, LAY UP AND MAINTENANCE - Chapter 63. Boiler Startup (Pre-operational Cleaning) - Chapter 64. Descaling and Boiler Cleaning - Chapter 65. Boiler LayUp - Chapter 66. Boiler Maintenance - PART - VIII. CHEMICALS HANDLING, SOLUTION PREPARATION AND FEEDERS - Chapter 67. Chemicals Handling and Storage - Chapter 68. Preparation of Solutions and Suspensions - Chapter 69. Chemical Feeders - PART - IX. ANALYSIS OF WATER AND STEAM - See Website for full TOC

This book details two elements of textile chemistry namely- sustainable/eco-friendly dyes and green chemistry. It presents latest topics in sustainable dyeing techniques, low impact dyeing methods, wool dyeing techniques and green chemistry. Certain case studies are also highlighted.

This book investigates a wide range of phase equilibrium modelling and calculation problems for compositional thermal simulation. Further, it provides an effective solution for multiphase isenthalpic flash under the classical framework, and it also presents a new flash calculation framework for multiphase systems, which can handle phase equilibrium and chemical reaction equilibrium simultaneously. The framework is particularly suitable for systems with many phases and reactions. In this book, the author shows how the new framework can be generalised for different flash specifications and different independent variables. Since the flash calculation is at the heart of various types of compositional simulation, the findings presented here will promote the combination of phase equilibrium and chemical equilibrium calculations in future simulators, aiming at improving their robustness and efficiency.

This book presents the latest advances in flowsheet simulation of solids processes, focusing on the dynamic behaviour of systems with interconnected solids processing units, but also covering stationary simulation. The book includes the modelling of solids processing units, for example for comminution, sifting and particle formulation and also for reaction systems. Furthermore, it examines new approaches for the description of solids and their property distributions and for the mathematical treatment of flowsheets with multivariate population balances.

This book summarizes the research results of carbide control in special steel from the authors. It includes the evolution and control of carbide in special steel in the process of electroslag remelting, rolling, and heat treatment, as well as the effect of alloying treatment (rare earth, magnesium, nitrogen, titanium) as heterogeneous nucleating agent on the carbides in special steel. It helps the readers to understand the formation mechanism and control technology of carbide in special steel deeply for improving the quality of special steel further. The book is useful as a reference for researchers, practitioners, teachers, and engineering management team in the fields of metallurgy and materials.

This book summarizes science and technology of a new generation of high-energy andinsensitive explosives. The objective is to provide professionals with comprehensiveinformation on the synthesis and the physicochemical and detonation properties ofthe explosives. Potential technologies applicable for treatment of contaminated wastestreams from manufacturing facilities and environmental matrices are also be included.This book provides the reader an insight into the depth and breadth of theoreticaland empirical models and experimental techniques currently being developed in thefield of energetic materials. It presents the latest research by DoD engineers andscientists, and some of DoD's academic and industrial researcher partners. The topicsexplored and the simulations developed or modified for the purposes of energetics mayfind application in other closely related fields, such as the pharmaceutical industry.One of the key features of the book is the treatment of wastewaters generated duringmanufacturing of these energetic materials.

This book introduces the synthesis and modification of 3D hierarchical porous graphene materials and presents various applications of it. By directly constructing a 3D graphene framework with sp2 hybridization and hierarchical porosity, this book is aimed to bridge the gap between 2D ideal nanostructure and 3D practical materials by systematically studying the growth mechanism, synthetic methodology, customized application, and system promotion of 3D hierarchical porous graphene (hpG) materials. The achievements presented offer a valuable contribution to the fundamental research and the industrial development of graphene with significantly improved performance and also inspire further research into various nanomaterials beyond graphene.

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

This book focuses on biodiesel combustion, including biodiesel performance, emissions and control. It brings together a range of international research in combustion studies in order to offer a comprehensive resource for researchers, students and academics alike. The book begins with an introduction to biodiesel combustion, followed by a discussion of NOx formation routes. It then addresses biodiesel production processes and oil feedstocks in detail, discusses the physiochemical properties of biodiesel, and explores the benefits and drawbacks of these properties. Factors influencing the formation of emissions, including NOx emissions, are also dealt with thoroughly. Lastly, the book discusses the mechanisms of pollution and different approaches used to reduce pollutants in connection with biodiesel. Each approach is considered in detail, and diagrams are provided to illustrate the points in line with industry standard control mechanisms.

Fuelled by advances in computer technology, model-based approaches to the control of industrial processes are now widespread. While there is an enormous literature on modelling, the difficult first step of selecting an appropriate model structure has received almost no attention. This book fills the gap, providing practical insight into model selection for chemical processes and emphasizing structures suitable for control system design.

This book discusses chemical engineering and processing, presenting selected contributions from PAIC 2019. It covers interdisciplinary technologies and sciences, like drug-delivery systems, nanoscale technology, environmental control, modelling and computational methods. The book also explores interdisciplinary aspects of chemical and biochemical engineering interconnected with process system engineering, process safety and computer science.

This book reviews the assessment of industrial biotechnology products and processes from a sustainable perspective. Industrial Biotechnology is a comparably young field which comes along with high expectations with regard to sustainability issues. These stem from the promise of reducing greenhouse gas emissions and replacing fossil resources in the near or later future and using green technology, i.e. more environmentally friendly technologies. The intended economic, ecological and social benefits, however, need to be proven, resulting in a variety of challenges, both from a methodological and application point of view. In this book, specific assessment and application topics of industrial biotechnology are addressed, highlighting challenges and solutions for both developers and users of assessment methods. In twelve chapters, experts in their particular fields define the scope, characterize industrial biotechnology and show in their contributions the state of the art, challenges and prospects of assessing industrial biotechnology products and processes. The chapter 'Societal and Ethical Aspects of Industrial Biotechnology' of this book is available open access under a CC BY 4.0 license at link.springer.com

Coverage in this annual review of the literature presents a comprehensive and critical survey of the vast field of study involving organophosphorus compounds. From phosphines and related P-C bonded compounds through tervalent phosphorus acid derivatives, phosphine chalcogenides, and recent developments in green synthetic approaches in organophosphorus chemistry, the volume reflects established and current interests in the area. With an emphasis on interdisciplinary content, this book is aimed at the worldwide organic chemistry and engineering research communities.

This book systematically introduces readers to the fundamental physics and a broad range of applications of acoustic levitation, one of the most promising techniques for the container-free handling of small solid particles and liquid droplets. As it does away with the need for solid walls and can easily be incorporated into analysis instruments, acoustic levitation has attracted considerable research interest in many fields, from fluid physics to material science. The book offers a comprehensive overview of acoustic levitation, including the history of acoustic radiation force; the design and development of acoustic levitators; the technology's applications, ranging from drop dynamics studies to bio/chemical analysis; and the insightful perspectives that the technique provides. It also discusses the latest advances in the field, from experiments to numerical simulations. As such, the book provides readers with a clearer understanding of acoustic levitation, while also stimulating new research areas for scientists and engineers in physics, chemistry, biology, medicine and other related fields.

This book presents the applications of ion-exchange materials in the biomedical industries. It includes topics related to the application of ion exchange chromatography in determination, extraction and separation of various compounds such as amino acids, morphine, antibiotics, nucleotides, penicillin and many more. This title is a highly valuable source of knowledge on ion-exchange materials and their applications suitable for postgraduate students and researchers but also to industrial R&D specialists in chemistry, chemical, and biochemical technology. Additionally, this book will provide an in-depth knowledge of ion-exchange column and operations suitable for engineers and industrialists.

This book reviews the wide range of products and applications of solid state fermentation as well as the development of this cultivation technology over the last years. In this book, readers will also learn about the challenges of solid state fermentation, including process management, reactor design, scale-up and the formation of process-specific products. Solid fermentation is a traditional cultivation technique of food technology and involves all cultivations of microorganisms on a solid substrate without free liquid phase. In the course of development of Biotechnology it was replaced by liquid cultivation mainly in the western countries. Over the past few years, solid-state fermentation is now becoming more important and has moved more back into focus. Especially, it is suitable for the cultivation of filamentous organisms, like ascomycetes and basidiomycetes, but also for various yeasts and bacteria. The products and applications of solid-state fermentation are as diverse as the microorganisms. They range from enzyme production to the production of antibiotics and pigments to the use in environmental technology and energy production.

This book is intended as a text for upper undergraduate and graduate courses on kinetics of metallurgical processes for students of materials science, metallurgical engineering, and chemical engineering. Focusing on basic and essential topics, selected from the authors' teaching and research, it serves as a comprehensive guide to metallurgical kinetics. Chapters 1-10 discuss the "logic" of various kinetics processes, while Chapter 11 explores the systematic analysis of raw rate data generated from controlled experiments. The final chapters illustrate how the fundamental concept of thermal activation is used to describe the kinetics of rate-dependent plastic deformation and creep fracture. With numerous examples, illustrations, and step-by-step tutorials, it is ideally suited for both self-study and classroom use. The examples were selected from research papers to highlight how the topics discussed can be, and are, used to solve real-world technological problems. Providing a comprehensive list of resources for further study, and end-of-chapter review questions to help students test their knowledge, it can be used for university coursework or as a text for professional development courses.

This book addresses microwave chemistry at both the physical and molecular level. Its main goal is to elaborate the highly complex scientific issues involved in the fundamental theory of microwave chemistry, and in industrialized applications in the near future.The book provides detailed insights into the characterization and measurement of dielectric properties under complex conditions, such as chemical reactions, high-temperature environments, etc. Considerable attention is paid to the theory of dynamics in microwave chemistry, from the view of both physical level and molecular level. Microwave-Material Interactions simulation is used for physical dynamical analysis, while a Microwave-Molecules Interactions methodology is proposed for molecular dynamical analysis. In turn, calculational examples are introduced for better description and validation, respectively. Lastly, the book proposes design strategies and calculational examples for large-scale application. Richly illustrated and including a wealth of worked-out examples, this book is ideal for all researchers, students and engineers who are just getting started in the dynamics of microwave chemistry.

This book brings out the innovations in textile wet or chemical processing to alleviate the environmental impacts arising from this sector. The major challenge in the textiles and fashion sector is that it requires a massive sustainable innovation to mitigate the huge environmental impacts arising from chemical or wet processing. This book also discusses innovations in eco-friendly methods for textile wet processes and applications of enzymes in textiles.

Uniting the key organic topics of total synthesis and efficient synthetic methodologies, this book clearly overviews synthetic strategies and tactics applied in total synthesis, demonstrating how the total synthesis of natural products enables scientific and drug discovery. Focuses on efficiency, a fundamental and important issue in natural products synthesis that makes natural product synthesis a powerful tool in biological and pharmaceutical science Describes new methods like organocatalysis, multicomponent and cascade reactions, and biomimetic synthesis Appeals to graduate students with two sections at the end of each chapter illustrating key reactions, strategies, tactics, and concepts; and good but unfinished total synthesis (synthesis of core structure) before the last section Compiles examples of solid phase synthesis and continuing flow chemistry-based total synthesis which are very relevant and attractive to industry R&D professionals

This book analyses the use of a pulsed gas flow to structure bubbling gas-solid fluidised beds and to induce a special fluidisation state, called "dynamically structured flow", as a promising approach to process intensification. It explores the properties of bubbles rising in staggered periodic arrays without direct interaction, assessing their size, separation, and velocity, and explains how a highly uniform, scalable flow offers tight control over the system hydrodynamics. These features are desirable, as they not only bypass engineering challenges occurring in traditional operations, such as maldistribution and non-uniform contact, but also allow to decouple conflicting design objectives, such as mixing and gas-solid contact. The thesis also presents computational simulations which reveal the periodic transitions of the particulate phase between fluid-like and solid-like behaviour. This book will be of interest to researchers, engineers, and graduate students alike, particularly those working in industrial drying, combustion, and chemical production.