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Books > Professional & Technical > Industrial chemistry & manufacturing technologies > Industrial chemistry > General
This book outlines the methodologies, approaches and tools for modelling chemicals in a Life Cycle Assessment (LCA) perspective, and also covers the main advantages and drawbacks of applying LCA to chemical processes. In the first part of this book, authors pay close attention to the limitations of modelling the environmental and social impacts of chemical processes, providing valuable insights to the problems of the Life Cycle Inventory (LCI) analysis for chemical processes. In the second part of this book, readers will learn about the LCA application to chemical processes in the laboratory and industrial scale. In each chapter of this book, readers will also find specific case studies on the modelling and application of LCA in the chemical industry.
Membrane Reactors for Hydrogen Production Processes deals with technological and economic aspects of hydrogen selective membranes application in hydrogen production chemical processes. Membrane Reactors for Hydrogen Production Processes starts with an overview of membrane integration in the chemical reaction environment, formulating the thermodynamics and kinetics of membrane reactors and assessing the performance of different process architectures. Then, the state of the art of hydrogen selective membranes, membrane manufacturing processes and the mathematical modeling of membrane reactors are discussed. A review of the most useful applications from an industrial point of view is given. These applications include: natural gas steam reforming, autothermal reforming, water gas shift reaction, decomposition of hydrogen sulphide, and alkanes dehydrogenation. The final part is dedicated to the description of a pilot plant where the novel configuration was implemented at a semi-industrial scale. Plant engineers, researchers and postgraduate students will find Membrane Reactors for Hydrogen Production Processes a comprehensive guide to the state of the art of membrane reactor technology.
Technical literature in the Portuguese language is very rare; this is the reason for the compilation of this technical dictionary. The material is rich in synonyms in each of the three languages, English, German and Portuguese. The dictionary encompasses some of the most important technical fields related to industrial activity, such as: Petrochemical industry. Geological history; Oil exploration, oil drilling, offshore drilling; Oil shale processing; Coal mining; Oil refining, cracking, distillation. Textile Industry. Machinery; Textile fabrics, fibres; Spinning, weaving, knitting, weaves, knits; Treatment and finishing, dyes. Leather Industry. Leather types; Leather treatment. Engineering Materials. Modified natural products; Synthetic plastics; Polymers, polycondensation products, polyaddition products; Glass; Paper, wood, glues, paints and varnishes; Metals. Cleaners Industry. Detergents; Waxes, emulsifiers. Industrial Processes. Fermentation; Catalysis and catalysts; Sulphuric-acid production. Machinebuilding Industry. Machines; Tools; Machine parts. Nucleonics, Nuclear Energy. Electrical Engineering. Electrical technology; Electronics; Semiconductor technology. Motor Car Industry. Motor car; Internal combustion engine; Lorries; Agricultural machines; Road construction machines.
This book provides insights into the development and usage of coal in chemical engineering. The reactivity of coal in processes such as pyrolysis, gasification, liquefaction, combustion and swelling is related to its structural properties. Using experimental findings and theoretical analysis, the book comprehensively answers three crucial issues that are fundamental to the optimization of coal chemical conversions: What is the structure of coal? How does the underlying structure determine the reactivity of different types of coal? How does the structure of coal alter during coal conversion? This book will be of interest to both individual readers and institutions involved in teaching and research into chemical engineering and energy conversion technologies. It is aimed at advanced- level undergraduate students. The text is suitable for readers with a basic knowledge of chemistry, such as first-year undergraduate general science students. Higher-level students with an in-depth understanding of the chemistry of coal will also benefit from the book. It will provide a useful reference resource for students and university-level teachers, as well as practicing engineers.
CONTENTS - PART I. ATOMS, MOLECULES AND CHEMICAL BONDING - I. Atom: Wave Nature and Configuration - II. Electron Clouds, Covalent and Ionic Radii - III. Molecular Orbitals - IV. Valence Bond Theory of Chemical Bonding - V. Hybridization - VI. Chemical Bonding and its Molecular Orbital Theory - VII. Coupling of Angular Momenta and Magnetic Moments - VIII. Transitional Elements - IX. Complexes, Ligands and Molecular Orbital Field Theory - PART II. NON-TRANSITIONAL ELEMENTS - X. Inert Gases of the Zero Group - Rare Elements of the Alkali Group - XI. Lithium - XII. Rubidium, Caesium and Francium - Rare Elements of the Alkaline Earth Group - XIII. Beryllium - XIV. Radium and Radon - Rare Elements of Boron-Aluminium Group - XV. Gallium - XVI. Indium - XVII. Thallium - Rare Elements of Carbon Group - XVIII. Germanium - Rare Elements of Oxygen-Sulphur Group - XIX. Selenium - XX. Tellurium and Polonium - XXI. Element 85, Alabamine or Astatine of Halogen Group - PART III. TRANSITIONAL ELEMENTS - XXII. Scandium - XXIII. Lathanide Series or Rare Earths - Rare Elements of the Titanium Sub-Group - XXIV. Titanium - XXV. Zirconium - XXVI. Hafnium - XXVII. Thorium - Rare Elements of the Vanadium Sub-Group - XXVIII. Vanadium - XXIX. Columbium or Niobium - XXX. Tantalum - Rare Elements of the Chromium Sub-Group - XXXI. Molybdenum - XXXII. Tungsten or Wolfram - XXXIII. Uranium - Rare Elements of the Manganese Sub-Group - XXXIV. Rhenium and Technetium - Platinum Metals - XXXV. Ruthenium - XXXVI. Rhodium - XXXVII. Palladium - XXX VIII. Osmium - XXXIX. Iridium - XL. Platinum - XLI. Actinium and Protoactinium - XLII. Trans-Uranium Elements - Rare Earth Homologues in the Actinide Series - Index -
As a result of the advancements in algorithms and the huge increase in speed of computers over the past decade, electronic structure calculations have evolved into a valuable tool for characterizing surface species and for elucidating the pathways for their formation and reactivity. It is also now possible to calculate, including electric field effects, STM images for surface structures. To date the calculation of such images has been dominated by density functional methods, primarily because the computational cost of - curate wave-function based calculations using either realistic cluster or slab models would be prohibitive. DFT calculations have proven especially valuable for elucidating chemical processes on silicon and other semiconductor surfaces. However, it is also clear that some of the systems to which DFT methods have been applied have large non-dynamical correlation effects, which may not be properly handled by the current generation of Kohn-Sham-based density functionals. For example, our CASSCF calculations on the Si(001)/acetylene system reveal that at some geometries there is extensive 86 configuration mixing. This, in turn, could signal problems for DFT cal- lations on these systems. Some of these problem systems can be addressed using ONIOM or other "layering" methods, treating the primary region of interest with a CASMP2 or other multireference-based method, and treating the secondary region by a lower level of electronic structure theory or by use of a molecular mechanics method. ACKNOWLEDGEMENTS We wish to thank H. Jonsson, C. Sosa, D. Sorescu, P. Nachtigall, and T. -C."
Green Chemistry is an inventive science based on fundamental research towards the development of new sustainable chemical processes. There is a great need to create a new type of chemistry focused on a new production system, in order to prepare the younger generation to get a greener future. The globalization pushes the chemistry community to adopt ethical issues. In this prospect Green Chemistry can achieve the approval of the society by teaching students to be confident in science and at the same time by convincing people that it is possible to attain technological development with respect and care for the environment we live in. This is why it is of foremost importance that education and fundamental research remain strictly connected, so that democracy and development can grow and progress side by side. This book has been prepared to extend the knowledge of Green Chemistry not disregarding, however, the industrial interest. It is the result of the effort to put together and share the expertise of leading practitioners in the field of Green Chemistry. The Interuniversity Consortium 'Chemistry for the Environment' is a non-profit organisation established in 1993 in Italy. At present it includes 31 member universities and 80 research units.
Reviews all known antifoam mechanisms, and discusses the appropriate practical approaches for solving foam control problems in a variety of industrial contexts. These range from crude oil production to detergent formulation.
This book provides a comprehensive overview of digital signal processing for a multi-disciplinary audience. It posits that though the theory involved in digital signal processing stems from electrical, electronics, communication, and control engineering, the topic has use in other disciplinary areas like chemical, mechanical, civil, computer science, and management. This book is written about digital signal processing in such a way that it is suitable for a wide ranging audience. Readers should be able to get a grasp of the field, understand the concepts easily, and apply as needed in their own fields. It covers sampling and reconstruction of signals; infinite impulse response filter; finite impulse response filter; multi rate signal processing; statistical signal processing; and applications in multidisciplinary domains. The book takes a functional approach and all techniques are illustrated using Matlab.
The porous structure of molecular sieves, combined with their chemical composition, makes them uniquely suitable for use as catalysts or catalytic supports. As such, the materials are used in a wide range of chemical reactions, and as components of formulated products. The shape selectivity of the materials further enhances their chemical usefulness, and exploitation of their unique absorption properties holds the key to improving their catalytic properties. To that end, great efforts are being made to find new of different molecular sieves, with altered or tailored structures or chemical composition. The synthesis and characterisation of molecular sieve materials is a considerable challenge, testing both the chemist's understanding and practical skills. In a thorough overhaul of the very successful first edition of this book, the author guides the reader in the basics of sieve structure, synthesis and characterisation, and points the way to the development of new or improved sieve materials. By covering both the principles and practical aspects of sieve synthesis and characterisation, professional chemists, particularly those involved in industrial research and development, will find this book an essential guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate students, will find this book an invaluable guide to this exciting and important area of chemistry.
CONTENTS - INTRODUCTION - 1. BASIC CONSIDERATIONS - Solutions-Suspensions-Emulsions-Surface Activity - 2. PROPERTIES OF EMULSIONS - Particle size and arrangement ; Rheology ; Micelle Theory ; Stability and Interfacial Phenomena ; Causes of Unstable Emulsions - 3. INGREDIENTS AND ADDITIVES - Surfactants-Emulsifying Agents ; Wetting Agents ; Foamers ; Protective Colloids ; Preservatives - 4. ANALYSIS AND TESTING OF EMULSIONS - Type of Emulsion ; Density ; Viscosity ; Surface Tension ; Particle Size ; Water ; PH-Color OdorCorrosion ; Stability ; Performance ; Analytical Procedures ; ASTM Specifications - 5. TECHNIQUES OF EMULSIFICATION - English Method-Continental Method - 6. EMULSIFYING EQUIPMENT - Low-Shear-High-Shear-Rotor-Stator ; Pressurized Fluid ; Vibrational Devices ; Laboratory Equipment - 7. EMULSION PLANTS AND PRODUCTION MACHINERY - Over-all Plan ; Modes of Operation ; Power Requirements ; Mixing Tanks ; Pumps ; Conveyors ; Materials of Construction ; Instrumentation ; Packaging - 8. SELECTED TOPICS - Formulation of Emulsions-HLB-Biodegradability - Regulations - BIBLIOGRAPHY - LIST OF EMULSIFYING AGENTS - SUPPLIERS OF EMULSIFYING AGENTS - GLOSSARY - INDEX - Introduction - Emulsions, though not new, are finding new and wider applications daily. One of the first references to emulsions was recorded by Galen (131-c.201), the Greek physician. Beginning with that early reference to the emulsifying power of beeswax, the art and science of emulsification has flourished. Emulsions are prepared and used for a variety of reasons. As oil paint cannot be applied to a damp surface, it is emulsified in water. The oil paint, then, in the form of an emulsion, can be applied to a damp surface. Therefore, the emulsion can change the application characteristics of a material. Water is a desirable, cheap diluent, and an emulsion is an easy method of using water to dilute materials that are not soluble in water. In addition, the fire hazard of flammable water-insoluble materials can be decreased through emulsification. The odor and taste of water-insoluble materials can be reduced by the use of an emulsion. Cod-liver oil, for example, loses much of its fishy, oily taste when it is emulsified. The kinetics of many reactions are enhanced through the use of emulsion polymerization techniques. On the other hand, emulsions are difficult to manufacture. A small deviation in temperature or mixing speed or small amounts of impurities can prevent the formation of a stable emulsion. Emulsions are sensitive in varying degrees to heat, cold, and age. The production of good, stable emulsions, therefore, is the combination of science and art. It is the purpose of this book to describe the art and technique of emulsification.
Over the last 15 years, there has been renewed interest in supercritical fluids owing to their unique properties and relatively low environmental impact. Greatest attention has been given to the extraction and separation of organic compounds. Supercritical fluids have also been successfully used for particle production, as reaction media, and for the destruction of toxic waste. Supercritical carbon dioxide has been the most widely used supercritical fluid, mainly because it is cheap, relatively nontoxic, and has convenient critical values. Supercritical fluids have also been used on analytical and preparative scales for many biological and other applications. Many papers have been published on the use of supercritical fluids. However, few have acted as a detailed instruction manual for those wanting to use the techniques for the first time. We anticipate that this Methods in Biotechnology volume, Supercritical Fluid Methods and Protocols will s- isfy the need for such a book. Every chapter has been written by experienced workers and should, if closely followed, enable workers with some or no previous experience of supercritical fluids to conduct experiments successfully at the first attempt.
Industrial radiography is a well-established non-destructive testing (NDT) method in which the basic principles were established many years ago. However, during 1993-95 the European Standards Organisa tion (CEN) commenced drafting many new standards on NDT including radiographic methods, and when completed these will replace national standards in all the EC member countries. In some cases these standards vary significantly from those in use in the UK at present. These CEN standards are accepted by majority, not unanimous voting, so they will become mandatory even in countries which vote against them. As most are likely to be legal by the time this second edition is published, they are described in the appropriate places in the text. The most important new technical development is the greater use of computers in radiology. In the first edition, computerized tomography was only briefly mentioned at the end of Chapter 11, as it was then largely a medical method with only a few equipments having found a place in industrial use. The method depends on a complex computer program and a large data store. Industrial equipments are now being built, although their spread into industry has been slow. Computer data storage is also being used for radiographic data. Small computers can now store all the data produced by scanning a radiographic film with a small light-spot, and various programs can be applied to these data."
Provides a fascinating and at times amusing insight into the real world uses of chemicals. Chemicals are everywhere. Many are natural and safe, others synthetic and dangerous. Or is it the other way around? Walking through the supermarket, you might ask yourself: Should I be eating organic food? Is that anti-wrinkle cream a gimmick? Is it worth buying BPA-free plastics? This Sixth Edition of Chemistry in the Marketplace provides fresh explanations, fascinating facts and funny anecdotes about the serious science in the products we buy and the resources we use. It might even save you some money. With chapters on the chemistry found in different parts of our home, in the backyard and in the world around us, Ben Selinger and Russell Barrow explain how things work, where marketing can be deceptive and what risks you should really be concerned about. Chemistry in the Marketplace is a valuable text book for university lecturers, high school teachers and students of chemistry and chemistry related subjects and disciplines, such as biochemistry, microbiology and science in society.
A growing proportion of the world's population is dependent on Seawater Desalination as a source of fresh water for both potable and civil use. One of the main drawbacks of conventional desalination technologies is the substantial energy requirement, which is facing cost increases in the global energy market. "Seawater Desalination" presents an overview of conventional and non-conventional technologies, with a particular focus on the coupling of renewable energies with desalination processes. The first section of this book presents, in a technical but reader-friendly way, an overview of currently-used desalination processes, from thermal to membrane processes, highlighting the relevant technical features, advantages and disadvantages, and development potential. It also gives a rapid insight into the economic aspects of fresh water production from seawater. The second section of the book presents novel processes which use Renewable Energies for fresh water production. From the first solar still evaporators, which artificially reproduced the natural cycle of water, technology has progressed to develop complex systems to harness energy from the sun, wind, tides, waves, etc. and then to use this energy to power conventional or novel desalination processes. Most of these processes are still at a preliminary stage of development, but some are already being cited as examples in remote areas, where they are proving to be valuable in solving the problems of water scarcity. A rapid growth in these technologies is foreseen in the coming years. This book provides a unique foundation, within the context of present and future sustainability, for professionals, technicians, managers, and private and public institutions operating in the area of fresh water supply.
This book presents comprehensive information on the relay auto-tuning method for unstable systems in process control industries, and introduces a new, refined Ziegler-Nichols method for designing controllers for unstable systems. The relay auto-tuning method is intended to assist graduate students in chemical, electrical, electronics and instrumentation engineering who are engaged in advanced process control. The book's main focus is on developing a controller tuning method for scalar and multivariable systems, particularly for unstable processes. It proposes a much simpler technique, avoiding the shortcomings of the popular relay-tuning method. The effects of higher-order harmonics are incorporated, owing to the shape of output waveforms. In turn, the book demonstrates the applicability and effectiveness of the Ziegler-Nichols method through simulations on a number of linear and non-linear unstable systems, confirming that it delivers better performance and robust stability in the presence of uncertainty. The proposed method can also be easily implemented across industries with the help of various auto-tuners available on the market. Offering a professional and modern perspective on profitably and efficiently automating controller tuning, the book will be of interest to graduate students, researchers, and industry professionals alike.
This volume chronicles the proceedings of the 8th International Symposium on Surfactants in Solution (SIS) held in Gainesville, FL, June 10-15, 1990. This series of symposia have been smoothly running since 1976, but the appellation "Surfactants in Solution" was used for the first time in 1982 in Lund. Since then our logo "SIS" has become very familiar to everyone involved in surfactants. In Lund the meeting was billed as the Fourth International Symposium on Surfactants in Solution. Earlier three events were held under different rubrics, but proceedings of all these symposia, except the 7th SIS held in Ottawa in 1988, have been properly documented. As a matter of fact so far 10 volumes have appeared under the title "Surfactants in Solution". 1,2,3 The program for the 9th SIS was very comprehensive and many ramifications of surfactants were covered, and it was a veritable international event. It contained a total of 384 papers by 869 authors from practically every corner of our planet. Just the sheer number of papers is a testimonial to the high tempo of research and tremendous interest in this wonderful class of materials. As in the past, there were plenary lectures (5), invited talks (37), oral presentations (195) and poster presentations (147). The plenary lectures were given by Prof. J. Th. G. Overbeek, Prof. C. A. Bunton, Prof. H. Ti Tien and Dr. J. Swalen. The lecture by Prof. Overbeek, the doyen of surface and colloid science, was a real treat.
This book reports on multidisciplinary research focusing on the analysis, synthesis and design of bionanomaterials. It merges the biophysicists', the biochemists' and bioengineers' perspectives, covering the study of the basic properties of materials and their interaction with biological systems, the development of new devices for medical purposes such as implantable systems, and new algorithms and methods for modeling the mechanical, physical or biological properties of biomaterials. The different chapters, which are based on selected contributions presented at the second edition of BIONAM, held on October 4-7, 2016, in Salerno, Italy, cover both basic and applied research. This includes novel synthetic strategies for nanomaterials, as well as the implementation of bio- and smart materials for pharmacological and medical purposes (e.g. drug delivery, implantable systems), environmental applications, and many others. The book provides a broad audience of academic and professionals with a comprehensive, timely snapshot of the field of biomaterials. Besides offering a set of innovative theories together with the necessary practical tools for their implementation, it also highlights current challenges in the field, thus fostering new discussions and possible future collaborations between groups with different backgrounds.
Concern for the environment has become one of the big issues in modern society, and one of the chief concerns is the environmental impact of modern industrial production. A particularly sensitive issue is the possibility of accidents in industries where there may be severe consequences for people, property and the environment. At one time the nuclear industry was seen as the most likely to be the cause of significant environmental damage, but after the occurrence of several major accidents such as Seveso, Flixborough and Bhopal, that concern extends to much of the chemicals industry. Pressure from society, reflected by strong legislation, coupled with a greater understanding of the impact that chemical processing operations can have, has led to the adoption of higher profile safety and environmental management programs within the chemical industry. Under these programmes existing and new processes are rigorously examined to determine the possible causes and consequences of failure, and the results used to improve the process to make failure less likely. Any process audit, aimed at improving safety or lessening the environmental impact, cannot be carried out using intuition or experience alone, so the discipline of risk analysis has grown as a collection of tools and methods which can be utilized to give a quantitative assessment of the risks involved in operating any given process. In this new book the authors present risk analysis and reduction in a clear and unified way, emphasizing the various different methods which can be used together in a global approach to risk analysis in the chemical process industries. Originally conceived as a text book for graduate level courses in chemical engineering, the clear presentation and thorough coverage will ensure that anyone involved in risk assessment, environmental impact assessment or safety planning will find this book an invaluable source of reference.
This volume contains an archival record of the NATO Advanced Institute on Microscale Heat Transfer - Fundamental and Applications in Biological and Microelectromechanical Systems held in Cesme - Izmir, Turkey, July 18-30, 2004. The ASIs are intended to be high-level teaching activity in scientific and technical areas of current concern. In this volume, the reader may find interesting chapters and various Microscale Heat Transfer Fundamental and Applications. The growing use of electronics, in both military and civilian applications has led to the widespread recognition for need of thermal packaging and management. The use of higher densities and frequencies in microelectronic circuits for computers are increasing day by day. They require effective cooling due to heat generated that is to be dissipated from a relatively low surface area. Hence, the development of efficient cooling techniques for integrated circuit chips is one of the important contemporary applications of Microscale Heat Transfer which has received much attention for cooling of high power electronics and applications in biomechanical and aerospace industries. Microelectromechanical systems are subject of increasing active research in a widening field of discipline. These topics and others are the main themeof this Institute."
This book summarizes the author's findings on the functional principle of flotation reagents, gathered over the past few decades. The fundamentals of and approaches common to surface chemistry are applied to study the reagents' structure and performance, as well as their interaction with minerals. In particular, the book establishes the theoretical criteria for collector performance. It also includes the quantum chemistry parameters, steric configuration, HOMO and LUMO surface of various reagents. The book offers a valuable resource for all university graduate students, researchers and R&D engineers in minerals processing and extractive metallurgy who wish to explore innovative reagents and technologies that lead to more energy efficient and environmentally sustainable solutions.
An understanding of the processes involved in the basic and applied physics and chemistry of the interaction of plasmas with materials is vital to the evolution of technologies such as those relevant to microelectronics, fusion and space. The subjects dealt with in the book include: the physics and chemistry of plasmas, plasma diagnostics, physical sputtering and chemical etching, plasma assisted deposition of thin films, ion and electron bombardment, and plasma processing of inorganic and polymeric materials. The book represents a concentration of a substantial amount of knowledge acquired in this area - knowledge which was hitherto widely scattered throughout the literature - and thus establishes a baseline reference work for both established and tyro research workers.
The complete control system engineering solution for continuous and batch manufacturing plants. This book presents a complete methodology of control system design for continuous and batch manufacturing in such diverse areas as pulp and paper, petrochemical, chemical, food, pharmaceutical, and biochemical production. Geared to practicing engineers faced with designing increasingly more sophisticated control systems in response to present-day economic and regulatory pressures, Plantwide Process Control focuses on the engineering portion of a plant automation improvement project. It features a full control design information package (Control Requirements Definition or CRD), and guides readers through all steps of the automation process—from the initial concept to design, simulation, testing, implementation, and operation. This unique and practical resource:
This book provides an analysis of the reaction mechanisms relevant to a number of processes in which CO2 is converted into valuable products. Several different processes are considered that convert CO2 either in specialty chemicals or in bulk products or fuels. For each reaction, the mechanism is discussed and the assessed steps besides the dark sites of the reaction pathway are highlighted. From the insertion of CO2 into E-X bonds to the reduction of CO2 to CO or other C1 molecules or else to C2 or Cn molecules, the reactions are analysed in order to highlight the known and obscure reaction steps. Besides well known reaction mechanisms and energy profiles, several lesser known situations are discussed. Advancing knowledge of the latter would help to develop efficient routes for the conversion of CO2 into valuable products useful either in the chemical or in the energy industry. The content of this book is quite different from other books reporting the use of CO2. On account of its clear presentation, "Reaction Mechanisms in Carbon Dioxide Conversion" targets in particular researchers, teachers and PhD students.
Recognized experts present incisive analysis of both fundamental and applied problems in this continuation of a highly acclaimed series. Topics discussed include: A thorough and mathematical treatment of periodic phenomena, with consideration of new theories about the transition between `order' and `chaos'; Impedance spectroscopy as applied to the study of kinetics and mechanisms of electrode processes; The use of stoichiometric numbers in mechanism analysis; The electro-osmotic dewatering of clays with important implications for the processing of industrial waste and geotechnical; stabilization; Magnetic effects in electrolytic processes and the electrolytic Hall effect; and The computer analysis and modeling of mass transfer and fluid flow. These authoritative studies will be invaluable for researchers in engineering, electrochemistry, analytical chemistry, materials science, physical chemistry, and corrosion science. |
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