Organometallic compounds are utilized as reagents in the preparation and processing of advanced nanostructured materials, as catalysts in the production of a wide variety of specialty chemicals and polymers, and as drugs. Supercritical fluid science and technology has a wide variety of applications ranging from extraction of pharmaceutically active compounds to the synthesis of advanced materials. The combination of organometallic chemistry and supercritical fluids has significant potential. This book covers the fundamental aspects and related applications in this rapidly growing area.
Covers the preparation of nanostructured composite materials using supercritical fluidsFocuses on the intersection of organometallic chemistry and supercritical fluids Addresses the behavior of organometallic compounds in supercritical fluid environments

This book highlights the latest research on waste processing technologies, particularly for domestic, agricultural, and petroleum based pollutants, intended to achieve waste valorisation. In addition, it discusses the important role of plastic recycling, as well as advanced waste processing techniques.

This volume provides an overview of recent developments and scope in the use of flow chemistry in relevance to heterocyclic synthesis. The heterocyclic ring is the most prominent structural motif in the vast majority of natural products as well as pharmaceutical compounds since this facilitates tuneable interactions with the biological target besides conferring a degree of structural and metabolic stability. In recent times, flow chemistry has heralded a paradigm shift in organic synthesis as it offers several unique advantages over conventional methods like drastic acceleration of sluggish transformations, enhanced yields, cleaner reactions etc and is gradually gaining a lot of attention among organic chemist worldwide. Given the importance of heterocycles in natural products, medicinal chemistry and pharmaceuticals, this is a well warranted volume and complements the previous volume of Topics in Organometallic Chemistry 'Organometallic Flow Chemistry'. This volume offers a versatile overview of the topic, besides discussing the recent progress in the flourishing area of flow chemistry in relevance to heterocyclic chemistry; it will also help researchers to better understand the chemistry behind these reactions. This in turn provides a platform for future innovations towards the designing of novel transformations under continuous flow. Thus, this volume will appeal to both the novices in this field as well as to experts in academia and industry.

Closing the gap between electrochemical engineering science and electrochemical technology, this volume is for all electrochemists and electrochemical engineers, metallurgists, engineers in chemical process, galvanic, metallurgical and electric power industries.

This book presents new application processes in the context of anaerobic digestion (AD), such as phosphorus recovery, microbial fuel cells (MFCs), and seaweed digestion. In addition, it introduces a new technique for the modeling and optimization of AD processes. Chapters 1 and 2 review AD as a technique for converting a range of organic wastes into biogas, while Chapter 3 discusses the recovery of phosphorus from anaerobically digested liquor. Chapters 4 and 5 focus on new techniques for modeling and optimizing AD. Chapters 6 and 7 then describe the state of the art in AD effluent treatment. The book's final three chapters focus on more recent developments, including microbial fuel cells (MFCs) (Chapter 8), seaweed production (Chapter 9), and enzyme technologies (Chapter 10).

This book systematically explains the application principles and green processing technologies of industrial oil plant. Firstly, the industrial plant oil resources are elaborated as an independent discipline for systematic research. Secondly, it has laid a solid theoretical foundation for the utilization of industrial plant oil resources, and will greatly promote the development of industrialization and modernization of industrial plant oil resources worldwide. Thirdly, it constructs integrated technology system of oil plant cultivation, oil extraction technology and products application. Finally, it elaborates a series of environmental issues including the protection of biodiversity and the balance of the forest ecology during the industrial plant oil resources processing. The technological process for green conversion of industrial plant oil resources to the oil-based materials and high value products will be of particular interest to the readers among oil researchers, producers and managers.

As the subtitle indicates, the overriding intention of the authors has been to provide a practical guide to the design of electrolytic plant. We wanted to show that the procedures for the design and optimization of such a plant are essentially simple and can be performed by readers comparatively new to the electrochemical field. It was important to realize that electrochemical engineering should not be confused with applied electrochemistry but had to be based on the principles of chemical engineering. For this reason, reference is often made to standard chemical engineering texts. Since this is a practical guide rather than a textbook, we have included a large number of worked examples on the principle that a good worked example is worth many paragraphs of text. In some examples we have quoted costs, e.g., of chemicals, plant or services. These costs are merely illustrative; current values will have to be obtained from manufacturers or journals. If this is not possible, approximate methods are available for updating costs to present-day values (see Refs. 1 and 3, Chapter 6).

This book provides a comprehensive overview of digital signal processing for a multi-disciplinary audience. It posits that though the theory involved in digital signal processing stems from electrical, electronics, communication, and control engineering, the topic has use in other disciplinary areas like chemical, mechanical, civil, computer science, and management. This book is written about digital signal processing in such a way that it is suitable for a wide ranging audience. Readers should be able to get a grasp of the field, understand the concepts easily, and apply as needed in their own fields. It covers sampling and reconstruction of signals; infinite impulse response filter; finite impulse response filter; multi rate signal processing; statistical signal processing; and applications in multidisciplinary domains. The book takes a functional approach and all techniques are illustrated using Matlab.

Essentials of Radiation Heat Transfer focuses only on the essential topics required to gain an understanding of radiation heat transfer to enable the reader to master more challenging problems. The strength of the book lies in its elaborate presentation of the powerful radiosity-irradiation method and shows how this technique can be used to solve a variety of problems of radiation in enclosures made of one to any number of surfaces in both transparent and participating media. The book also introduces atmospheric radiation in which engineers can contribute to the technology of remote sensing and atmospheric sciences in general, by a better understanding of radiation. The author has included pedagogical features such as end-of-chapter exercises and worked examples with varying degrees of difficulty to augment learning and self-testing. The book has been written in an easy- to- follow conversational style to enhance reader engagement and learning outcomes. This book will be a useful guide for upper undergraduate and graduate students in the areas of mechanical engineering, aerospace engineering, atmospheric sciences, and energy sciences.

Motivation for this Book Ontologies have received increasing attention over the last two decades. Their roots can be traced back to the ancient philosophers, who were interested in a c- ceptualization of the world. In the more recent past, ontologies and ontological engineering have evolved in computer science, building on various roots such as logics, knowledge representation, information modeling and management, and (knowledge-based) information systems. Most recently, largely driven by the next generation internet, the so-called Semantic Web, ontological software engineering has developed into a scientific field of its own, which puts particular emphasis on the theoretical foundations of representation and reasoning, and on the methods and tools required for building ontology-based software applications in diverse domains. Though this field is largely dominated by computer science, close re- tionships have been established with its diverse areas of application, where - searchers are interested in exploiting the results of ontological software engine- ing, particularly to build large knowledge-intensive applications at high productivity and low maintenance effort. Consequently, a large number of scientific papers and monographs have been p- lished in the very recent past dealing with the theory and practice of ontological software engineering. So far, the majority of those books are dedicated to the th- retical foundations of ontologies, including philosophical treatises and their re- tionships to established methods in information systems and ontological software engineering.

Solvent Extraction in Biotechnology deals with the reco- very and purification of primary and secondary metabolites by solvent extraction. In the first part the reaction engineering principles: definitions, thermodynamic fundamentals, and system models, the kinetics of mass transfer between two phases without and with chemical reaction as well as extraction equipment, which are important for downstream processing in biotechnology, are considered in detail. The special part of the book describes the recovery of low-molecular metabolites: alcohols, acids and antibiotics with organic solvents, carrier-modifier-solvent systems, supercritical gases as well as with liquid membrane techniques. Several practical examples are given for the recovery of different metabolites as well as for the calculation of the extraction processes necessary for equipment design. Besides solvent extraction, novel separation techniques with liquid membrane, microemulsion and reversed micelles are also presented. This book will introduce the biochemical engineer and process engineer to the recovery of products from complex cultivation broths by modern techniques of solvent extraction and help them with process design.

Flow Control Methods and Devices in Micrometer Scale Channels, by Shuichi Shoji and Kentaro Kawai. Micromixing Within Microfluidic Devices, by Lorenzo Capretto, Wei Cheng, Martyn Hill and Xunli Zhang. Basic Technologies for Droplet Microfluidics, by Shaojiang Zeng, Xin Liu, Hua Xie and Bingcheng Lin. Electrorheological Fluid and Its Applications in Microfluidics, by Limu Wang, Xiuqing Gong and Weijia Wen. Biosensors in Microfluidic Chips, by Jongmin Noh, Hee Chan Kim and Taek Dong Chung. A Nanomembrane-Based Nucleic Acid Sensing Platform for Portable Diagnostics, by Satyajyoti Senapati, Sagnik Basuray, Zdenek Slouka, Li-Jing Cheng and Hsueh-Chia Chang. Optical Detection Systems on Microfluidic Chips, by Hongwei Gai, Yongjun Li and Edward S. Yeung. Integrated Microfluidic Systems for DNA Analysis, by Samuel K. Njoroge, Hui-Wen Chen, Ma gorzata A. Witek and Steven A. Soper. Integrated Multifunctional Microfluidics for Automated Proteome Analyses, by John K. Osiri, Hamed Shadpour, Ma gorzata A. Witek and Steven A. Soper. Cells in Microfluidics, by Chi Zhang and Danny van Noort. Microfluidic Platform for the Study of Caenorhabditis elegans, by Weiwei Shi, Hui Wen, Bingcheng Lin and Jianhua Qin."

Membrane Reactors for Hydrogen Production Processes deals with technological and economic aspects of hydrogen selective membranes application in hydrogen production chemical processes. Membrane Reactors for Hydrogen Production Processes starts with an overview of membrane integration in the chemical reaction environment, formulating the thermodynamics and kinetics of membrane reactors and assessing the performance of different process architectures. Then, the state of the art of hydrogen selective membranes, membrane manufacturing processes and the mathematical modeling of membrane reactors are discussed. A review of the most useful applications from an industrial point of view is given. These applications include: natural gas steam reforming, autothermal reforming, water gas shift reaction, decomposition of hydrogen sulphide, and alkanes dehydrogenation. The final part is dedicated to the description of a pilot plant where the novel configuration was implemented at a semi-industrial scale. Plant engineers, researchers and postgraduate students will find Membrane Reactors for Hydrogen Production Processes a comprehensive guide to the state of the art of membrane reactor technology.

This book provides insights into the development and usage of coal in chemical engineering. The reactivity of coal in processes such as pyrolysis, gasification, liquefaction, combustion and swelling is related to its structural properties. Using experimental findings and theoretical analysis, the book comprehensively answers three crucial issues that are fundamental to the optimization of coal chemical conversions: What is the structure of coal? How does the underlying structure determine the reactivity of different types of coal? How does the structure of coal alter during coal conversion? This book will be of interest to both individual readers and institutions involved in teaching and research into chemical engineering and energy conversion technologies. It is aimed at advanced- level undergraduate students. The text is suitable for readers with a basic knowledge of chemistry, such as first-year undergraduate general science students. Higher-level students with an in-depth understanding of the chemistry of coal will also benefit from the book. It will provide a useful reference resource for students and university-level teachers, as well as practicing engineers.

As a result of the advancements in algorithms and the huge increase in speed of computers over the past decade, electronic structure calculations have evolved into a valuable tool for characterizing surface species and for elucidating the pathways for their formation and reactivity. It is also now possible to calculate, including electric field effects, STM images for surface structures. To date the calculation of such images has been dominated by density functional methods, primarily because the computational cost of - curate wave-function based calculations using either realistic cluster or slab models would be prohibitive. DFT calculations have proven especially valuable for elucidating chemical processes on silicon and other semiconductor surfaces. However, it is also clear that some of the systems to which DFT methods have been applied have large non-dynamical correlation effects, which may not be properly handled by the current generation of Kohn-Sham-based density functionals. For example, our CASSCF calculations on the Si(001)/acetylene system reveal that at some geometries there is extensive 86 configuration mixing. This, in turn, could signal problems for DFT cal- lations on these systems. Some of these problem systems can be addressed using ONIOM or other "layering" methods, treating the primary region of interest with a CASMP2 or other multireference-based method, and treating the secondary region by a lower level of electronic structure theory or by use of a molecular mechanics method. ACKNOWLEDGEMENTS We wish to thank H. Jonsson, C. Sosa, D. Sorescu, P. Nachtigall, and T. -C."

Reviews all known antifoam mechanisms, and discusses the appropriate practical approaches for solving foam control problems in a variety of industrial contexts. These range from crude oil production to detergent formulation.

This book presents comprehensive information on the relay auto-tuning method for unstable systems in process control industries, and introduces a new, refined Ziegler-Nichols method for designing controllers for unstable systems. The relay auto-tuning method is intended to assist graduate students in chemical, electrical, electronics and instrumentation engineering who are engaged in advanced process control. The book's main focus is on developing a controller tuning method for scalar and multivariable systems, particularly for unstable processes. It proposes a much simpler technique, avoiding the shortcomings of the popular relay-tuning method. The effects of higher-order harmonics are incorporated, owing to the shape of output waveforms. In turn, the book demonstrates the applicability and effectiveness of the Ziegler-Nichols method through simulations on a number of linear and non-linear unstable systems, confirming that it delivers better performance and robust stability in the presence of uncertainty. The proposed method can also be easily implemented across industries with the help of various auto-tuners available on the market. Offering a professional and modern perspective on profitably and efficiently automating controller tuning, the book will be of interest to graduate students, researchers, and industry professionals alike.

CONTENTS - PART I. ATOMS, MOLECULES AND CHEMICAL BONDING - I. Atom: Wave Nature and Configuration - II. Electron Clouds, Covalent and Ionic Radii - III. Molecular Orbitals - IV. Valence Bond Theory of Chemical Bonding - V. Hybridization - VI. Chemical Bonding and its Molecular Orbital Theory - VII. Coupling of Angular Momenta and Magnetic Moments - VIII. Transitional Elements - IX. Complexes, Ligands and Molecular Orbital Field Theory - PART II. NON-TRANSITIONAL ELEMENTS - X. Inert Gases of the Zero Group - Rare Elements of the Alkali Group - XI. Lithium - XII. Rubidium, Caesium and Francium - Rare Elements of the Alkaline Earth Group - XIII. Beryllium - XIV. Radium and Radon - Rare Elements of Boron-Aluminium Group - XV. Gallium - XVI. Indium - XVII. Thallium - Rare Elements of Carbon Group - XVIII. Germanium - Rare Elements of Oxygen-Sulphur Group - XIX. Selenium - XX. Tellurium and Polonium - XXI. Element 85, Alabamine or Astatine of Halogen Group - PART III. TRANSITIONAL ELEMENTS - XXII. Scandium - XXIII. Lathanide Series or Rare Earths - Rare Elements of the Titanium Sub-Group - XXIV. Titanium - XXV. Zirconium - XXVI. Hafnium - XXVII. Thorium - Rare Elements of the Vanadium Sub-Group - XXVIII. Vanadium - XXIX. Columbium or Niobium - XXX. Tantalum - Rare Elements of the Chromium Sub-Group - XXXI. Molybdenum - XXXII. Tungsten or Wolfram - XXXIII. Uranium - Rare Elements of the Manganese Sub-Group - XXXIV. Rhenium and Technetium - Platinum Metals - XXXV. Ruthenium - XXXVI. Rhodium - XXXVII. Palladium - XXX VIII. Osmium - XXXIX. Iridium - XL. Platinum - XLI. Actinium and Protoactinium - XLII. Trans-Uranium Elements - Rare Earth Homologues in the Actinide Series - Index -

Green Chemistry is an inventive science based on fundamental research towards the development of new sustainable chemical processes. There is a great need to create a new type of chemistry focused on a new production system, in order to prepare the younger generation to get a greener future.

The globalization pushes the chemistry community to adopt ethical issues. In this prospect Green Chemistry can achieve the approval of the society by teaching students to be confident in science and at the same time by convincing people that it is possible to attain technological development with respect and care for the environment we live in. This is why it is of foremost importance that education and fundamental research remain strictly connected, so that democracy and development can grow and progress side by side.

This book has been prepared to extend the knowledge of Green Chemistry not disregarding, however, the industrial interest. It is the result of the effort to put together and share the expertise of leading practitioners in the field of Green Chemistry.

The Interuniversity Consortium 'Chemistry for the Environment' is a non-profit organisation established in 1993 in Italy. At present it includes 31 member universities and 80 research units.

This book focuses on structural characterisation techniques for porous materials. Covering a range of techniques, including gas sorption, mercury porosimetry, thermoporometry, NMR and imaging methods, this practical guide presents the basic theory behind each characterisation technique, and discusses the practicalities of the experimental and data analysis approaches needed for complex industrial samples. The book shows readers how to approach characterising a particular sort of material for the first time and then how to develop a strategy for more in-depth analysis. It also demonstrates how to determine the best techniques for solving particular problems, and describes methods of obtaining the required information, as well as the limitations of various methods. It particularly highlights a scientific approach involving parameter validation and simple acquisition. Featuring examples taken from case studies of real-world industrial materials, this book is intended for industrial practitioners and researchers. It provides a manual of potential techniques and answers questions concerning porous materials that arise in areas such as the catalyst industry, the oil and gas sector, batteries, fuel cells, tissue engineering scaffolds and drug delivery devices.

The porous structure of molecular sieves, combined with their chemical composition, makes them uniquely suitable for use as catalysts or catalytic supports. As such, the materials are used in a wide range of chemical reactions, and as components of formulated products. The shape selectivity of the materials further enhances their chemical usefulness, and exploitation of their unique absorption properties holds the key to improving their catalytic properties. To that end, great efforts are being made to find new of different molecular sieves, with altered or tailored structures or chemical composition. The synthesis and characterisation of molecular sieve materials is a considerable challenge, testing both the chemist's understanding and practical skills. In a thorough overhaul of the very successful first edition of this book, the author guides the reader in the basics of sieve structure, synthesis and characterisation, and points the way to the development of new or improved sieve materials. By covering both the principles and practical aspects of sieve synthesis and characterisation, professional chemists, particularly those involved in industrial research and development, will find this book an essential guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate students, will find this book an invaluable guide to this exciting and important area of chemistry.

CONTENTS - INTRODUCTION - 1. BASIC CONSIDERATIONS - Solutions-Suspensions-Emulsions-Surface Activity - 2. PROPERTIES OF EMULSIONS - Particle size and arrangement ; Rheology ; Micelle Theory ; Stability and Interfacial Phenomena ; Causes of Unstable Emulsions - 3. INGREDIENTS AND ADDITIVES - Surfactants-Emulsifying Agents ; Wetting Agents ; Foamers ; Protective Colloids ; Preservatives - 4. ANALYSIS AND TESTING OF EMULSIONS - Type of Emulsion ; Density ; Viscosity ; Surface Tension ; Particle Size ; Water ; PH-Color OdorCorrosion ; Stability ; Performance ; Analytical Procedures ; ASTM Specifications - 5. TECHNIQUES OF EMULSIFICATION - English Method-Continental Method - 6. EMULSIFYING EQUIPMENT - Low-Shear-High-Shear-Rotor-Stator ; Pressurized Fluid ; Vibrational Devices ; Laboratory Equipment - 7. EMULSION PLANTS AND PRODUCTION MACHINERY - Over-all Plan ; Modes of Operation ; Power Requirements ; Mixing Tanks ; Pumps ; Conveyors ; Materials of Construction ; Instrumentation ; Packaging - 8. SELECTED TOPICS - Formulation of Emulsions-HLB-Biodegradability - Regulations - BIBLIOGRAPHY - LIST OF EMULSIFYING AGENTS - SUPPLIERS OF EMULSIFYING AGENTS - GLOSSARY - INDEX - Introduction - Emulsions, though not new, are finding new and wider applications daily. One of the first references to emulsions was recorded by Galen (131-c.201), the Greek physician. Beginning with that early reference to the emulsifying power of beeswax, the art and science of emulsification has flourished. Emulsions are prepared and used for a variety of reasons. As oil paint cannot be applied to a damp surface, it is emulsified in water. The oil paint, then, in the form of an emulsion, can be applied to a damp surface. Therefore, the emulsion can change the application characteristics of a material. Water is a desirable, cheap diluent, and an emulsion is an easy method of using water to dilute materials that are not soluble in water. In addition, the fire hazard of flammable water-insoluble materials can be decreased through emulsification. The odor and taste of water-insoluble materials can be reduced by the use of an emulsion. Cod-liver oil, for example, loses much of its fishy, oily taste when it is emulsified. The kinetics of many reactions are enhanced through the use of emulsion polymerization techniques. On the other hand, emulsions are difficult to manufacture. A small deviation in temperature or mixing speed or small amounts of impurities can prevent the formation of a stable emulsion. Emulsions are sensitive in varying degrees to heat, cold, and age. The production of good, stable emulsions, therefore, is the combination of science and art. It is the purpose of this book to describe the art and technique of emulsification.

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science.The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience.Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.Review articles for the individual volumes are invited by the volume editors.Readership: research chemists at universities or in industry, graduate students

A growing proportion of the world's population is dependent on Seawater Desalination as a source of fresh water for both potable and civil use. One of the main drawbacks of conventional desalination technologies is the substantial energy requirement, which is facing cost increases in the global energy market. "Seawater Desalination" presents an overview of conventional and non-conventional technologies, with a particular focus on the coupling of renewable energies with desalination processes.

The first section of this book presents, in a technical but reader-friendly way, an overview of currently-used desalination processes, from thermal to membrane processes, highlighting the relevant technical features, advantages and disadvantages, and development potential. It also gives a rapid insight into the economic aspects of fresh water production from seawater.

The second section of the book presents novel processes which use Renewable Energies for fresh water production. From the first solar still evaporators, which artificially reproduced the natural cycle of water, technology has progressed to develop complex systems to harness energy from the sun, wind, tides, waves, etc. and then to use this energy to power conventional or novel desalination processes. Most of these processes are still at a preliminary stage of development, but some are already being cited as examples in remote areas, where they are proving to be valuable in solving the problems of water scarcity.

A rapid growth in these technologies is foreseen in the coming years. This book provides a unique foundation, within the context of present and future sustainability, for professionals, technicians, managers, and private and public institutions operating in the area of fresh water supply.

Over the last 15 years, there has been renewed interest in supercritical fluids owing to their unique properties and relatively low environmental impact. Greatest attention has been given to the extraction and separation of organic compounds. Supercritical fluids have also been successfully used for particle production, as reaction media, and for the destruction of toxic waste. Supercritical carbon dioxide has been the most widely used supercritical fluid, mainly because it is cheap, relatively nontoxic, and has convenient critical values. Supercritical fluids have also been used on analytical and preparative scales for many biological and other applications. Many papers have been published on the use of supercritical fluids. However, few have acted as a detailed instruction manual for those wanting to use the techniques for the first time. We anticipate that this Methods in Biotechnology volume, Supercritical Fluid Methods and Protocols will s- isfy the need for such a book. Every chapter has been written by experienced workers and should, if closely followed, enable workers with some or no previous experience of supercritical fluids to conduct experiments successfully at the first attempt.