Introduction to Sol-Gel Processing introduces undergraduate and graduate students to the field of colloids applied to materials processing, better known as sol-gel processing. It is written for Engineering or Science students in the fields of Chemical Engineering, Materials Processing, Ceramics Engineering, Colloid Science and Mineral Chemistry.
Introduction to Sol-Gel Processing does not intend to be exhaustive on the research done in this field. However the most important facts about the most recent developments, including mixed organic-inorganic sol-gels known as hybrid materials and the use of surfactants and micelles, are addressed. More precisely, the book focuses on gathering the main theories related to sol-gel processing in a comprehensive manner, so as to provide the most important scientific basis to students.
Introduction to Sol-Gel Processing is organized in such a way that each chapter corresponds to one of the main steps in a chronological order of application of sol-gel techniques to the synthesis of materials. The book first presents elementary solvent chemistry, in particular the partial charge model theory. Next, theories on the nucleation and growth of particles and on the steric or electrostatic stabilization (also known as D.L.V.O. theory) of colloidal suspensions, are gathered in a chapter on colloidal particles. Another chapter is devoted to the theories on gelation. Gels, their structure and properties at large such as their swelling, shrinkage or drying behavior, also constitute an important chapter. After drying, gels become almost traditional ceramic materials and they are often submitted to thermal treatments during which they can phase-transform andsinter. Two chapters offer an opportunity to gather the main theories related to these two fields. Finally, the main applications are reviewed according to the domains of application, particularly for coatings, filtering membranes, and catalysts.

This volume provides the reader with the most up-to-date and relevant knowledge on the reactivity of metals located in zeolite materials, either in framework or extra-framework positions, and the way it is connected with the nature of the chemical environment provided by the host. Since the first report of the isomorphous substitution of titanium in the framework of zeolites giving rise to materials with unusual catalytic properties, the incorporation of many other metals have been investigated with the aim for developing catalysts with improved performance in different reactions. The continuous expansion of the field, both in the variety of metals and zeolite structures, has been accompanied by an increasing focus on the relationship between the reactivity of metal centers and their unique chemical environment. The concepts covered in this volume are of interest to people working in the field of inorganic and physical chemistry, catalysis and chemical engineering, but also for those more interested in theoretical approaches to chemical reactivity. In particular the volume is useful to postgraduate students conducting research in the design, synthesis and catalytic performance of metal-containing zeolites in both academic and application contexts.

This is a book about mathematical modelling. It focuses on the modelling of the preparation of materials. Materials are important, of course, in an economic sense: the "goods" of goods-and-services are made of materials. This provides a strong incentive to produce good materials and to improve existing materials. Mathematical modelling can help in this regard. Without a doubt, modelling a materials processing operation is not strictly necessary. Materials synthesis and fabrication processes certainly existed before the invention of mathematics and computers, and well before the combined use of mathematics and computers. Modelling can, however, be of assistance--if done properly--and if used properly. The mathematical modelling described in this book is, at its root, a rather formal, structured way of thinking about materials synthesis and fabrication processes. It requires looking at a process as a whole. It requires considering everything that is or might be important. It requires translating the details of a given physical process into one or more mathematical equations. It requires knowing how to simplify the equations without over-simplifying them.

This practical guide describes the basic computational methodologies for catalysis and materials science at an introductory level, presenting the methods with relevant applications, such as spectroscopic properties, chemical reactivity and transport properties of catalytically interesting materials. Edited and authored by internationally recognized scientists, the text provides examples that may be considered and followed as state-of-the art.

- Microporous Organic Polymers: Design, Synthesis, and Function By J.-X. Jiang and A. I. Cooper - Hydrogen, Methane and Carbon Dioxide Adsorption in Metal-Organic Framework Materials By X. Lin, N. R. Champness, and M. Schroeder -Doping of Metal-Organic Frameworks with Functional Guest Molecules and Nanoparticles By F. Schroeder and R. A. Fischer -Chiral Metal-Organic Porous Materials: Synthetic Strategies and Applications in Chiral Separation and Catalysis By K. Kim, M. Banerjee, M. Yoon, and S. Das -Controlled Polymerization by Incarceration of Monomers in Nanochannels By T. Uemura and S. Kitagawa -Designing Metal-Organic Frameworks for Catalytic Applications L. Ma and W. Lin -Magnetic and Porous Molecule-Based Materials By N. Roques, V. Mugnaini, and J. Veciana

This book analyzes hydrocarbon generation and accumulation within space-limited source rocks. The authors draw conclusions based on the principles of basin formation, hydrocarbon generation and accumulation, coupled with the practice of terrigenous basins in eastern China. Hydrocarbon generation and expulsion have been quantitatively assessed in space-limited source rock systems. This book explores new hydrocarbon generation and expulsion models to reflect real geological situations more accurately. The theory and practice proposed in this book challenge the traditional theory of kerogen thermal degradation and hydrocarbon generation.

This book provides readers with the most current knowledge on hazardous waste management practices. It addresses the rapidly changing advances in waste stream characterization and the discovery of new chemicals - which have led to new hazardous wastes, technological innovation, stringent environmental regulations, changes in transport and dispersion modelling of hazardous pollutants, and new waste management techniques. Hazardous Waste Management: Advances in Chemical and Industrial Waste Treatment and Technologies is an invaluable reference for waste management and treatment professionals, chemical engineers and technicians, medical professionals, and environmental regulators, as well as students taking courses on hazardous waste management, environmental engineering, and environmental science.

Most conventional cryogenic refrigerators and liquefiers operate with pure fluids, the major exception being natural gas liquefiers that use mixed refrigerant processes. The fundamental aspects of mixed refrigerant processes, though very innovative, have not received the due attention in open literature in view of commercial interests. Hundreds of patents exist on different aspects of mixed refrigerant processes. However, it is difficult to piece together the existing information to choose an appropriate process and an optimum composition or a given application. The aim of the book is to teach (a.) the need for refrigerant mixtures, (b.) the type of mixtures that can be used for different refrigeration and liquefaction applications, (c.) the different processes that can be used and (d.) the methods to be adopted for choosing the components of a mixture and their concentration for different applications.

This book shows the promising future and essential issues on the storage of the supercritical gases, including hydrogen, methane and carbon dioxide, by adsorption with controlling the gas-solid interaction by use of designed nanoporous materials. It explains the reason why the storage of these gases with adsorption is difficult from the fundamentals in terms of gas-solid interaction. It consists of 14 chapters which describe fundamentals, application, key nanoporous materials (nanoporous carbon, metal organic frame works, zeolites) and their storage performance for hydrogen, methane, and carbon dioxide. Thus, this book appeals to a wide readership of the academic and industrial researchers and it can also be used in the classroom for graduate students focusing on clean energy technology, green chemistry, energy conversion and storage, chemical engineering, nanomaterials science and technology, surface and interface science, adsorption science and technology, carbon science and technology, metal organic framework science, zeolite science, nanoporous materials science, nanotechnology, environmental protection, and gas sensors.

Design, construct and utilize fuel systems using this comprehensive reference work. Combustion Engineering Issues for Solid Fuel Systems combines modeling, policy/regulation and fuel properties with cutting edge breakthroughs in solid fuel combustion for electricity generation and industrial applications. This book moves beyond theory to provide readers with real-life experiences and tips for addressing the various technical, operational and regulatory issues that are associated with the use of fuels. With the latest information on CFD modeling and emission control technologies, Combustion Engineering Issues for Solid Fuel Systems is the book practicing engineers as well as managers and policy makers have been waiting for.
Provides the latest information on CFD modeling and emission control technologies
Comprehensive coverage of combustion systems and fuel types
Addresses policy and regulatory concerns at a technical level
Tackles various technical and operational issues"

This book collates the latest trends and technological advancements in bioremediation, especially for its monitoring and assessment. Divided into 18 chapters, the book summarizes basic concepts of waste management and bioremediation, describes advancements of the existing technologies, and highlights the role of modern instrumentation and analytical methods, for environmental clean-up and sustainability. The chapters cover topics such as the role of microbial fuel cells in waste management, microbial biosensors for real-time monitoring of bioremediation processes, genetically modified microorganisms for bioremediation, application of immobilized enzyme reactors, spectroscopic techniques, and in-silico approaches in bioremediation monitoring and assessment. The book will be advantageous not only to researchers and scholars interested in bioremediation and sustainability but also to professionals and policymakers.

This book provides a systematic and comprehensive introduction to the technical principles, materials, processes, and equipment of the electron beam wire deposition technology (EBWD), while focusing on the research results of the author's scientific research team engaged in this technology in China. It mainly introduces the conceptual connotation, principle, and characteristics of the EBWD technology, its position and function in the additive manufacturing technology system, the direction and trend of technological development at home and abroad, the fundamentals and application results of the EBWD technology, including technical principles, equipment technology, special materials, manufacturing technology, quality testing, and application practices. So this book can serve as a reference book for teachers, students, and scientific researchers in scientific research institutions who are engaged in relevant studies.

Methanol - The Chemical and Energy Feedstock of the Future offers a visionary yet unbiased view of methanol technology. Based on the groundbreaking 1986 publication "Methanol" by Friedrich Asinger, this book includes contributions by more than 40 experts from industry and academia. The authors and editors provide a comprehensive exposition of methanol chemistry and technology which is useful for a wide variety of scientists working in chemistry and energy related industries as well as academic researchers and even decision-makers and organisations concerned with the future of chemical and energy feedstocks.

The main objective of this volume is to demonstrate the importance of the fundamental aspects of interfacial phenomena in various industrial applications. The text provides the reader with the knowledge that is essential for the composition of the complex multi-phase systems used in the above mentioned areas of application. It should enable the physical and formulation chemist as well as the chemical engineer in designing the formulation on the basis of a rational approach. It will also enable the formulation scientist to better understanding the factors responsible for producing a stable product with optimum application conditions. The book should also be very useful for teaching the subject of formulation at academic institutions.

This book is a compilation of selected papers from the Fourth International Technical Symposium on Deepwater Oil and Gas Engineering & The Third International Youth Forum on Gas Hydrate, held in Qingdao, China in December 2021. The work focuses on the advancement of techniques for the deepwater oil and gas exploitation and natural gas hydrate exploitation. The book introduces new ideas for exploring deepwater oil and gas hydrate in a safe and efficient way. Advances of the natural gas hydrate pilot production in South China Sea, in oil and gas flow assurance and emerging technologies based on clathrate hydrate will be presented. It is a valuable resource for both practitioners and academics working in the field of deepwater oil and gas engineering.

This book discusses financial, managerial and engineering aspects associated with project engineering. The book is a text/reference book on courses related to project engineering for undergraduate students of Chemical Engineering programmes. The author has utilized her decade-long professional experience with reputed project consultancy organizations and her academic experience in writing this book. The background of project engineering is described with special emphasis on its interdisciplinary nature. Project management techniques are discussed with the help of worked-out examples. It includes multiple choice questions and information regarding relevant courses in different institutes. The book is useful for undergraduate degree and diploma students as well as for fresh graduate engineering trainees in various process consulting organizations.

This book presents the fundamentals of the reservoir and interfacial engineering. The book systematically starts with the basics of primary, secondary and tertiary (enhanced) oil recovery and emphasizes on the theory of microbial-enhanced oil recovery (MEOR) and its potential toward recovery of oil in place. Different approaches of MEOR such as in-situ, ex-situ, and integration of chemical- and microbial-enhanced oil recovery (EOR) are discussed in detail. This book highlights the link between the effectiveness of MEOR and the local reservoir conditions, crude oil characteristics, and indigenous microbial community. The latest implementations of MEOR across the globe are highlighted as case studies to outline the potential as well as the scope of MEOR. Given the topics covered, this book will be useful for professionals and researchers working in the areas of petroleum science and engineering, chemical engineering, biotechnology, bioengineering, and other related fields.

This is the only book that covers containment, specifically for the process industries. This Guide covers the range of containment equipment from simple air-flow control devices to enclosures that restrict exposures to well below a microgram per cubic meter averaged over a working day. The selection of a particular containment system for a particular transfer operation can be difficult because of the wide choice available. This Guide provides a structured approach to the selection process.
Covers the legislation for containment guidelines in the US, UK, and Europe
Provides an exhaustive list of containment equipment, including chapters on maintenance and reliability
Shows the engineer how to develop a containment strategy for his/her plant

This book review series presents current trends in modern biotechnology. The aim is to cover all aspects of this interdisciplinary technology where knowledge, methods and expertise are required from chemistry, biochemistry, microbiology, genetics, chemical engineering and computer science. Volumes are organized topically and provide a comprehensive discussion of developments in the respective field over the past 3-5 years. The series also discusses new discoveries and applications. Special volumes are dedicated to selected topics which focus on new biotechnological products and new processes for their synthesis and purification. In general, special volumes are edited by well-known guest editors. The series editor and publisher will however always be pleased to receive suggestions and supplementary information. Manuscripts are accepted in English.

This book offers a comprehensive review of the latest developments, challenges and trends in C1-based (one-carbon based) bioproduction, and it presents an authoritative account of one-carbon compounds as promising alternative microbial feedstocks. The book starts with a perspective on the future of C1 compounds as alternative feedstocks for microbial growth, and their vital role in the establishment of a sustainable circular carbon economy, followed by several chapters in which expert contributors discuss about the recent strategies and address key challenges regarding one or more C1 feedstocks. The book covers topics such as acetogenic production from C1 feedstocks, aerobic carboxydotrophic bacteria potential in industrial biotechnology, bioconversion of methane to value-added compounds, combination of electrochemistry and biology to convert C1 compounds, and bioprocesses based on C1-mixotrophy. Particular attention is given to the current metabolic engineering, systems biology, and synthetic biology strategies applied in this field.

Contents - PART 1 - The Unique Position of the Carbon Atom in Chemistry - 1. The Nature of Organic Chemistry - 2. The Organic Chemist Looks at a Molecule - 3. Valence - 4. New Ideas on Valence - 5. The Unique Position of Carbon among the Elements - 6. The O C T E T in Chemistry - 7. The D U E T in Chemistry - 8. North and South Poles - PART 2 - The Architecture of Carbon Compounds - 9. Methane and the Structure Theory - 10. Carbon Chains - 11. Carbon Rings - 12. Morphology of Chain and Ring Compounds - 13. Double and Triple Bonds - 14. Energy and Molecular Structure - 15. PI Electrons - 16. Bond Energies and Resonance - 17. How Molecules React - 18. Why Molecules React - 19. The Benzene Ring - 20. Nuclear Reactions - 21. The Geography of the Benzene Ring - 22. Stereochemistry and Isomerism - PART 3 - The Classification of Carbon Compounds - 23. The Common Methods of Classification in Organic Chemistry - 24. Halogen Compounds and Free Radicals - 25. Alcohols, Phenols, and Ethers - 26. Aldehydes and Ketones - 27. Carboxylic Acids - 28. Mixed Oxygen Compounds - 29. Nitrogen Compounds - 30. Compounds with Sulphur, Phosphorus, and Other Elements - PART 4 - Special Topics in Organic Chemistry - 31. Structures of Complex Compounds - 32. Aromatic Character in Heterocycles and Condensed Cycles - 33. Proteins - 34. Carbohydrates - 35. Chemistry in Plant and Animal Life - 36. Dyes - 37. Isotopic Chemistry - 38. Giant Molecules - Supplementary Reading - Index - Preface - When Dr. Frank C. Whitmore was president of the American Chemical Society in 1938 and made the customary tour of local ACS sections, he used that occasion to spread the gospel of the electron theory of valence. At one of his lectures the author of this book sat in the audience among a mixed group of chemists consisting of technicians, students, and college graduates. The lack of familiarity of organic chemists with the electron was so obvious that it aroused in the author an urge to write an elementary introduction to organic chemistry in which the role of the electron would be emphasized. This book is especially intended to serve two groups of readers: those engaged in work of a chemical nature who are not able to take a classroom course in organic chemistry, and those in a college course who find they have a need for a supplementary book to help clarify the approach to modern organic chemistry. In other words, the book was conceived as an integrated introduction to both electron-valence theory and organic chemistry at a level suitable for self-study. The first edition of this book appeared in 1943 during World War II. A second edition, much enlarged, was published in 1955. For this third edition the book has been extensively rewritten, and more than enough material has been added so that it can serve as a textbook for a one-year college course. The novel arrangement of the subject matter in the earlier editions has been maintained. A teacher who prefers to lecture largely from his own notes should find no difficulty incorporating his material into the simple plan on which this book is based.

This new edition features research from nearly 60 of the profession's most distinguished international authorities. Recognizing emerging developments in biopolymer systems research with fully updated and expanded chapters, the second edition discusses the biopolymer-based multilayer structures and their application in biosensors, the progress made in the understanding of protein behaviour at the air-water interface, experimental findings in ellipsometry and reflectometry, and recent developments concerning protein interfacial behaviour in microfabricated total analysis systems and microarrays. With over 3000 references, this is an essential reference for professionals and students in surface, pharmaceutical, colloid, polymer, and medicinal chemistry; chemical, formulation, and application engineering; and pharmacy.

Studies in catalyst deactivation play a major role in the identification of the real catalytic system, in particular, the structure and texture of the solid, which is often in a metastable state, as it is operated in the industrial reactor. These studies also allow the identification of the experimental conditions which preserve this active and selective state. This is crucial for a real understanding of catalysts and catalysis. Another area of catalytic science concerns reactions kinetics, which, if properly determined, are of paramount importance in the elucidation of mechanisms. The behavior of the kinetics during aging and deactivation and an accurate modeling of the evolution of activity and selectivity are essential information for the process performance. These are just two typical examples, but quite generally, the science of catalyst deactivation is going to be more oriented to fundamental issues.

This third edition is a comprehensive and extended study about the best known approaches for preparing the main types of glycosides, covering the classic and more recent glycosylation reactions used for preparing simple and challenging glycosides currently used as potent antiviral and antineoplastic drugs, or fluorogenic substrates used for enzymatic detection in cell biology. Besides, this new edition provides more examples of the glycosidic methodologies followed for preparing complex glycoconjugates such as glycoproteins and glycosphingolipids and gangliosides used as adjuvants or as synthetic vaccines candidates. Also, additional mechanistic evidence is presented for better understanding of the glycosylation reaction, trying to identify the variables mainly depending on protecting and leaving groups, as well as catalyst and reaction condition which altogether directs the anomeric stereo control. A chapter on the glycoside hydrolysis is included in view of the increasing interest in the use of biomass as a natural and renewable source for obtaining important intermediates or products used in food or valuable materials. The author includes information in the characterization of glycosides section with the aim of giving additional tools for the structural assignment through NMR, X-Ray and mass spectra techniques.