This book describes new gel permeation chromatography/liquid chromatography applications and techniques that will provide polymer scientists and practitioners with insight into the development of new polymers and plastics and improvement of existing materials.

This book covers a range of topics of interest to those involved in the fractionation and characterization of polymeric substances. It deals with problems that are encountered in modern gel permeation chromatography with dual detection when calculating average molecular weights.

Widely employed for separating and detecting chemicals in solution, separation techniques are most often applied in tandem, subsequently referred to as hyphenated methods. Hyphenated and Alternative Methods of Detection in Chromatography details the development and application of mass spectral detection techniques coupled with gas phase and liquid phase chromatographies. With contributions from experts in a variety of fields, as evidenced by the range of topics, the book describes the advantages and disadvantages of various separation techniques and addresses methods for cutting-edge applications such as proteomics research. Specifically, this book covers: The development of the LC-NMR and its application in chromatographic science, particularly in relation to the analysis of natural and environmental samples and in the study of reaction monitoring, biosynthetic analysis, and structural elucidation The application of LC-ICP in biological samples for the speciation of organoarsenic and organoselenium compounds; metal complexes in microorganisms, plants, and foods of plant origin; human body fluids and tissues; and in the detection of chemical warfare agents Electrochemical detection in liquid chromatography, system optimization, and applications in the analysis of flavonoids The use of chemiluminescence for microcolumn and capillary methods of separation The process of employing multidimensional separation methods as a means of identifying components in complex samples A detailed reference for those starting out in the field, this book also suits those who are more experienced yet require assistance in new directions. It is an ideal reference for senior undergraduate and postgraduate students wishing to supplement their learning experience. Containing over 800 references, this book is an excellent source of information within the field of

On the job or in the field, when facing a problem with differential equations and boundary conditions, most likely you don't have time to read through several publications in search of a method that may or may not solve your problem. Organized for quick and easy access to practical solutions, Analytical and Approximate Methods in Transport Phenomena is a reference for the day-to-day problems encountered when working with variables in heat, mass, or momentum transfer. This text is organized differently from usual resources on applied mathematics for engineers. First, it introduces a new classification system of the problem based on just three numbers, so locating the appropriate solution method is quick and easy. Second, the author presents mathematical methods with applications in mind, introducing examples, as well as common or possible solutions, before presenting any mathematical theory or method. This allows you to identify the issue you need to resolve, then apply the appropriate method to the problem at hand. The book also includes practical discussions of the consequences and applications of various solutions. The book highlights mathematical methods as tools for solving practical problems, not as a primary objective. Its structure and focus on application, with just the right amount of mathematical rigor, makes it the most effective manual available for easily finding the analytical methods needed to solve transport problems.

Micro- and Nanostructured Multiphase Polymer Blend Systems: Phase Morphology and Interfaces focuses on the formation of phase morphology in polymer blends and copolymers and considers various types of blends including thermosets, thermoplastics, thermoplastic vulcanizates, and structured copolymers. The book carefully debates the processing, rheology, and crystallization aspects of the phase morphology of polymer blends. The text surveys theory, characterization, processing, and experimental aspects of phase morphology development and design of polymer blends. It examines the adhesion of polymer-polymer interfaces in immiscible polymer blends and the different ways by which nanostructures may be generated in thermosetting polymers. The book analyzes the polymerization process and the dynamic vulcanization of multicomponent polymer blends and the crystallization behavior occurring in blends with a confined morphology. It also discusses the structure-rheology relationship in compatibilized blends, the effects of elasticity on the structure development, and the rheological response in concentrated blends. Micro- and Nanostructured Multiphase Polymer Blend Systems examines the current state of the art, challenges, and future prospects in the field of polymer blends. The handpicked selection of topics and expert contributors makes this survey of phase morphology in polymer blends an outstanding resource for anyone involved in the field of polymer materials design.

This new edition features research from nearly 60 of the profession's most distinguished international authorities. Recognizing emerging developments in biopolymer systems research with fully updated and expanded chapters, the second edition discusses the biopolymer-based multilayer structures and their application in biosensors, the progress made in the understanding of protein behaviour at the air-water interface, experimental findings in ellipsometry and reflectometry, and recent developments concerning protein interfacial behaviour in microfabricated total analysis systems and microarrays. With over 3000 references, this is an essential reference for professionals and students in surface, pharmaceutical, colloid, polymer, and medicinal chemistry; chemical, formulation, and application engineering; and pharmacy.

This handbook presents the outlook for future production and consumption of MTBE and other oxygenates worldwide and studies new catalytic systems and modern methods for the synthesis and commercial production of methyl tertiary-butyl ether (MTBE) and related ethers. The scope of this sophisticated guide extends from process chemistry fundamentals and reaction kinetics to environmental remediation technologies and industry responses to conflicting calls for MTBE phase-out and higher-octane products. Well-illustrated with over 200 figures and tables, this authoritative Handbook details bioremediation, air stripping, and oxidation and adsorption processes for MTBE removal.

This book focuses on the fundamental principles and latest research findings in hydrogen energy fields including: hydrogen production, hydrogen storage, fuel cells, hydrogen safety, economics, and the impact on society. Further, the book introduces the latest development trends in practical applications, especially in commercial household fuel cells and commercial fuel cell vehicles in Japan. This book not only helps readers to further their basic knowledge, but also presents the state of the art of hydrogen-energy-related research and development. This work serves as an excellent reference for beginners such as graduate students, as well as a handbook and systematic summary of entire hydrogen-energy systems for scientists and engineers.

Waste Engine Oils presents a complete description of the field of engine used oils, widely collected in the networks of services-stations and garages. It describes the manufacture of base oils in refineries, and mentions the main additives playing an essential role in the quality of the marketed finished oils. The organization of the different systems of collecting in order to obtain a waste oil regenerable or used as fuel are explained.

This book covers the main operations of physical and chemical treatments required in waste oil regeneration by covering the fundamental principles techniques such as vacuum distillation, solvent deasphalting, and ultrafiltration. A wide part is dedicated to applications with the description of about twenty processes. In addition, the book describes several types of energetic valorizations which concern a quite important fraction of the collected oil volume.
* Comprehensive approach of the waste oil valorization
* Overview of chemical engineering operations applied to waste oil
* Objective view of the given information on a subject giving rise to competitiveness between the two routes of volorization

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal

This textbook provides both students and professionals alike with a transdisciplinary and comprehensive foundation to design responsible chemical products and processes that protect human health and the environment. It serves as a compact guide that brings together knowledge and tools from across multiple disciplines. Readers are introduced to a set of core topics with focus placed on basic technical methods and tools (including life cycle assessment, product and process risk assessment, and thermal safety concepts) as well as on important normative topics (including philosophical, societal, and business perspectives in addition to current environmental and safety legislation). Developed in collaboration with industry partners, this textbook also provides a workable, illustrative case study that guides readers through applying the fundamentals learned to the production and application of a real-world chemical product. Building upon the success of its first German edition published in 1998, this latest edition has been significantly updated and expanded to reflect developments over the past two decades. Its publication comes at a key time when the volume and pace of global chemical production is dramatically increasing, and the rise of social media and informed citizen scientists make the dialogue with stakeholders even more important and demanding. This textbook is a valuable resource for both the current and next generation of scientists and engineers that will be tasked with addressing the many challenges and opportunities that are appearing as a result. Covering a wide range of interconnected topics at a fundamental level applicable across scientific study programs and professions, this textbook fills a need not met by many of the other more specialized textbooks currently available.

Provides a solid grounding in the basic principles of the science of thermodynamics proceeding to practical, hands-on applications in large-scale industrial settings. Presents myriad applications for power plants, refrigeration and air conditioning systems, and turbomachinery. Features hundreds of helpful example problems and analytical exercises. Solutions manual is available to instructors.

This book investigates the main vegetable biomass types, their chemical characteristics and their potential to replace oil as raw material for the chemical industry, according to the principles of green chemistry. Authors from different scientific and technical backgrounds, from industry and academia, give an overview of the state of the art and ongoing developments. Aspects including bioeconomy, biorefineries, renewable chemistry and sustainability are also considered, given their relevance in this context. Furthermore, the book reviews green chemistry principles and their relation to biomass, while also exploring the main processes for converting biomass into bioproducts. The need to develop renewable feedstock for the chemical industry to replace oil has been identified as a major strategic challenge for the 21st century. In this context, the use of different types of vegetable biomass - starch, lignocellulosic, oleaginous, saccharide and algae - can be seen as a viable alternative to the use of non-renewable, more expensive raw materials. Furthermore, it offers a model for adding economic value to the agro industrial chains such as soybean, sugarcane, corn and forests, among others. This will in turn contribute to the sustainability of a wide range of chemicals, mainly organics and their transformation processes, which are widely used by modern society.

CONTENTS - 1. AGRICULTURAL EMULSIONS - 2. BITUMINOUS EMULSIONS - 3. CLEANERS - 4. COSMETICS - 5. EMULSION POLYMERIZATION - 6. FOAMS AND ANTIFOAMS - 7. GASOLINE EMULSIONS - 8. FOOD EMULSIONS - 9. LEATHER AND PAPER TREATMENT EMULSIONS - 10. MEDICAL EMULSIONS - 11. CUTTING OILS, SOLUBLE OILS, MISCIBLE OILS - 12. PAINT - 13. POLISHES - 14. RESIN AND RUBBER EMULSIONS - 15. TEXTILE EMULSIONS - APPENDIX - Conversion Tables - Viscosity Comparison Chart - Color Standards Comparator - Temperature Conversion Table - Rate of Flow Chart - List of Emulsifying Agents - Suppliers of Emulsifying Agents - INDEX - FOREWARD - The first volume of Practical Emulsions has attempted to convey a general impression of the science of the formulation and manufacture of emulsions. Salient points have been presented in as simple a manner as possible, while detailed examination of specific points of the theory has been left to those whose qualifications and interests better fit them for such tasks. In this volume, I have compiled basic formulations of many types of emulsion. This compilation is intended to provide graphic illustration of the breadth of emulsion technology. The formulations can also provide a starting point for the development of new and improved emulsion products and represent the types of product that can be made and their major constituents. These formulations are provided by manufacturers to illustrate the use of their products. The suitability of any product for marketing, or the determination of the patent position regarding any formulation, is the responsibility of the person who manufactures and/or sells the product. Many firms have generously provided formulation suggestions, and they merit my sincere appreciation for their help. Their contributions are acknowledged by appropriate references at the end of each chapter.

Scientists and engineers have made significant advances over the last two decades to achieve feasible, cost-efficient processes for the large-scale production of alternative, environmentally friendly sources of energy. Alcoholic Fuels describes the latest methods for producing fuels containing varying percentages of alcohol alongside the various applications they benefit, including combustion engines, fuel cells, and miniature power generators. Written by experts and innovators in the field,the chapters address the development and application of all alcoholic fuels, from production to end use. The first section of the book examines the production of methanol, ethanol, and butanol from several biomass sources, including corn, wood, and landfill waste. The second section explores blended fuels, such as E10, E85, and E-Diesel, and the third section focuses on applications of the different alcohol fuel types, including fuel cells, reformers, and generators. The book concludes with a discussion of the future production, use, and impact of alcohol-based fuels on society. Alcoholic Fuels provides a timely and practical source of information for chemists, engineers, and scientists working with alternative energy sources as well as managers, policymakers, and consumers considering the use and implementation of alcoholic fuels in automobiles and other energy conversion devices.

Featuring case studies and worked examples that illustrate key concepts in the text, this book contains guidelines for scaleup of laboratory and pilot plant results, methods to derive the correct reaction order, activation energy, or kinetic model from laboratory tests, and theories, correlations, and practical examples for 2- and 3-phase reaction systems, including bubble columns, slurry reactions, trickle-led reactors, and fluidized beds. A comprehensive reference, the book offers strategies to analyze and interpret kinetic data for homogeneous and heterogeneous reactions, practical design procedures, rate equations, and analytical models for improved reactor performance.

This volume provides up-to-date information on the developments in chromatographic methods and applications to provide readers with stimulating, critical, readable, and relevant reviews of this subject. It includes information on high-pressure liquid chromatography in pharmacology and toxicology.

This text offers authoritative contributions from nearly 200 leaders in the field and new methods to enhance catalytic reactions. "Catalysis of Organic Reactions" covers approaches for designing, modifying, and altering catalysts for improved function, performance, and stability, procedures to reduce by-product formation, and cost-effective alternatives for the hydrogenation of organic compounds. Studying the phase preference, concentration, characteristics, and recoverability of recently developed and commercial catalysts, this is an excellent guide for chemical engineers; organic, medicinal, catalytic, physical, industrial, process, inorganic, and organometallic chemists and biochemists, and surface and environmental scientists.

This book provides up-to-date information on a wide range of developments in the general and gas chromatographic methods and applications. It presents timely, cutting-edge reviews in the fields of bio-, analytical, organic, polymer, and pharmaceutical chemistry.

This book examines the metal/solution interface with the electrochemical quartz crystal microbalance, exploring electrostatic adsorption, metal deposition, and roughness. It explores the indirect laser-induced temperature-jump method for characterizing fast interfacial electron transfer.

The book concentrates on powder flow properties, their measurement and applications. These topics are explained starting from the interactions between individual particles up to the design of silos. A wide range of problems are discussed - such as flow obstructions, segregation, and vibrations. The goal is to provide a deeper understanding of the powder flow, and to show practical solutions.

Principles of Parenteral Solution Validation: A Practical Lifecycle Approach covers all aspects involved in the development and process validation of a parenteral product. By using a lifecycle approach, this book discusses the latest technology, compliance developments, and regulatory considerations and trends, from process design, to divesting. As part of the Expertise in Pharmaceutical Process Technology series edited by Michael Levin, this book incorporates numerous case studies and real-world examples that address timely problems and offer solutions to the daily challenges facing practitioners in this area.

This book consists of a series of 82 precise, easy-to-read articles by internationally renowned scientists and emphasizes the practical approach to HPLC with minimal theory, although the underlying principles for peptide and protein separations are clearly expressed. All of the major modes of microbore, ultrafast and analytical HPLC are discussed, including size-exclusion, ion-exchange, reversed-phase, hydrophobic interaction, and affinity and immunoaffinity chromatography. A section on preparative HPLC, including displacement techniques, is also presented. Problem-solving approaches to the separation of various classes of biologically active peptides and proteins are thoroughly explored, while the importance of peptide standards for monitoring column performance and for optimizing separation conditions is emphasized. Several articles focus on the choice of the correct detection method (electrochemical, UV, fluorescence), as well as the need for a proper knowledge of approaches to column and instrument maintenance and trouble-shooting. A section on predictive approaches deals with both computer simulation of peptide separations and peptide structure. The book also includes complementary techniques to HPLC, as well as other useful applications of HPLC. It enables both novice and experienced chromatographers to realize the full potential of this extremely powerful technique, in the process making an important contribution to scientific literature.

This classic and bestselling landmark publication, originally published in 1965, examines the dynamic mechanisms, fundamental principles, and physical properties of various chromatographic procedures. It offers methods to characterize, identify, and predict chromatographic phenomena - providing strategies to select the most appropriate separation tools and techniques for specific applications in chemistry, physics, biology, and forensic and environmental science. Written by a world-renowned pioneer in the field, Dynamics of Chromatography contains many worked equations and real-world examples in gas and liquid chromatography. It includes numerous schematic figures for visualization of key concepts, introduces the means to control migration rate differences and zone spreading, and presents a detailed random-walk model for clarification of column processes. It also analyzes flow, diffusion, and kinetic events, stresses the link between theory and practice, and summarizes mathematical quantities and parameters.

"Chemistry and Technology of Lubricants" describes the chemistry and technology of base oils, additives and applications of liquid lubricants. This Third Edition reflects how the chemistry and technology of lubricants has developed since the First Edition was published in 1992.

The acceleration of performance development in the past 35 years has been as significant as in the previous century: Refinery processes have become more precise in defining the physical and chemical properties of higher quality mineral base oils. New and existing additives have improved performance through enhanced understanding of their action. Specification and testing of lubricants has become more focused and rigorous.

"Chemistry and Technology of Lubricants" is directed principally at those working in the lubricants industry as well as individuals working within academia seeking a chemist's viewpoint of lubrication. It is also of value to engineers and technologists requiring a more fundamental understanding of the subject.