A discussion of fundamental characteristics, theories and applications for liquid-liquid colloidal dispersions. It profiles experimental and traditional measurement techniques in a variety of emulsified systems, including rheology, nuclear magnetic resonance, dielectric spectroscopy, microcalorimetry, video enhanced microscopy, and conductivity.

This expert volume provides specialized coverage of the current state of the art in carbon gels. Carbon gels represent a promising class of materials with high added value applications and many assets, like the ability to accurately tailor their structure, porosity, and surface composition and easily dope them with numerous species. The ability to obtain them in custom shapes, such as powder, beads, monoliths, or impregnated scaffolds opens the way towards numerous applications, including catalysis, adsorption, and electrochemical energy storage, among others. Nevertheless, it remains a crucial question as to which design synthesis and manufacturing processes are viable from an economic and environmental point of view. The book represents the perspectives of renowned specialists in the field, specially invited to conduct a one-day workshop devoted to carbon gels as part of the 19th International Sol-Gel Conference, SOL-GEL 2017, held on September 3rd, 2017 in Liege, Belgium. Addressing properties and synthesis through applications and industry outlook, this book represents essential reading for advanced graduate students through practicing researchers interested in these exciting materials.

This book discusses biomethane and the processes and applications downstream from biogas production. Biogas is a result of anaerobic digestion of agricultural or general household waste, such as manure, plants or food waste, and as such is considered a renewable energy source. Biomethane is a gas that results from any process that improves the quality of biogas by reducing the levels of carbon dioxide, hydrogen sulfide, moisture and other contaminant gases. Chemically, biomethane is the same as methane, and its name refers to the method of production rather than the content. Biomethane plants are generally found in locations with a low population density that are close to farms or food processing plants. In situations where there is no natural gas pipeline nearby, biomethane downstream applications can include storage, transportation, home heating, industrial use and distribution through small-scale local gas grids. This book discusses each of these applications and lists some of the design criteria as well as various issues relating to them.

The chemical industry processes a high proportion of its products in powder form, thus making the efficient, effective and safe handling and processing of powders of prime importance. Powders and Solids: Developments in Handling and Processing Technologies brings the reader right up-to-date with both newly-introduced commercial practices and results of recent fundamental research on the behaviour of model powders. Case studies are also included. Commencing with an overview of developments in the health and safety aspects of handling powders, the book then goes on to look at the new technologies being applied to powders and powder handling, followed by aspects of measurement and control in powder handling. It will be essential reading for all industrial practitioners, particularly those in the pharmaceutical industry, as well as all engineers working either in industry or research on processes involving solid and powder handling.

This volume documents developments in the study of catalysis relating to organic synthesis and its application in industrial processes. It surveys a wide range of homo- and heterogeneous catalysis for industrial and pharmaceutical chemicals. It covers enantioselective hydrogenation, catalyzed hydrogens and oxidation, carbonylation, hydroaminomethylation, and more.

From the reviews of the First Edition: "The book has admirably met its stated goal. The whole gamut of surface and colloid science has been presented in a comprehensive manner without any undue oversimplification. The author should be congratulated for his clarity." —Advanced Materials Now in its second edition, this work remains the single most useful introduction available to the complex area of surface and colloids science. Industry expert Drew Myers walks readers through concepts, theories, and applications—keeping the mathematics to a minimum and presenting real-world case studies to illustrate key technological and biological processes. He substantially reorganizes and updates the material to reflect the current state of knowledge in the field, offering new chapters on absorption and biological systems in addition to the important areas of colloid stability, emulsions and foams, monolayer films, surfactants, and wetting. This revision also boasts an improved index, more than 200 new line drawings, general and specific chapter bibliographies, and end-of-chapter problems. Geared to scientists, technologists, and students dealing with colloidal and surface systems and their numerous industrial applications, the book imparts an understanding of the fundamental aspects of surfaces, interfaces, and colloids, which is essential for effective solutions in diverse areas of chemistry, physics, biology, medicine, engineering, and material sciences.

In this book, Samohyl and Pekar offer a consistent and general non-equilibrium thermodynamic description for a model of chemically reacting mixtures. This type of model is frequently encountered in practice and up until now, chemically reacting systems (out of equilibrium) have rarely been described in books on non-equilibrium thermodynamics. Readers of this book benefit from the systematic development of the theory; this starts with general principles, going through the applications to single component fluid systems, and finishing with the theory of mixtures, including chemical reactions. The authors describe the simplest mixture model - the linear fluid - and highlight many practical and thermodynamically consistent equations for describing transport properties and reaction kinetics for this model. Further on in the book, the authors also describe more complex models. Samohyl and Pekar take special care to clearly explain all methodology and starting axioms and they also describe in detail applied assumptions and simplifications. This book is suitable for graduate students in chemistry, materials science and chemical engineering as well as professionals working in these and related areas.

This new reference presents the most recent information on new and potential food hydrocolloids originated from agricultural products, including o yellow mustard gum o flaxseed gum o cereals (wheat, barley, oat, and corn)o psyllium fenugreek o soybean. Polysaccharide Gums from Agricultural Products: Processing, Structures and Functionality addresses the basic chemistry, extracting processes, molecular structure, and, most importantly, the functional properties and potential applications of new polysaccharide gums.

The complete control system engineering solution for continuous and batch manufacturing plants.

This book presents a complete methodology of control system design for continuous and batch manufacturing in such diverse areas as pulp and paper, petrochemical, chemical, food, pharmaceutical, and biochemical production. Geared to practicing engineers faced with designing increasingly more sophisticated control systems in response to present-day economic and regulatory pressures, Plantwide Process Control focuses on the engineering portion of a plant automation improvement project. It features a full control design information package (Control Requirements Definition or CRD), and guides readers through all steps of the automation process—from the initial concept to design, simulation, testing, implementation, and operation. This unique and practical resource:

• Integrates continuous, batch, and discrete control techniques.
• Shows how to use the methodology with any automation project—existing or new, simple or complex, large or small.
• Relates recent ISO and ISA standards to the discipline of control engineering.
• Illustrates the methodology with a pulp-and-paper mill case study.
• Incorporates numerous other examples, from single-loop controllers to multivariable controllers.

Fuel cells are widely regarded as the future of the power and transportation industries. Intensive research in this area now requires new methods of fuel cell operation modeling and cell design. Typical mathematical models are based on the physical process description of fuel cells and require a detailed knowledge of the microscopic properties that govern both chemical and electrochemical reactions. Advanced Methods of Solid Oxide Fuel Cell Modeling proposes the alternative methodology of generalized artificial neural networks (ANN) solid oxide fuel cell (SOFC) modeling. Advanced Methods of Solid Oxide Fuel Cell Modeling provides a comprehensive description of modern fuel cell theory and a guide to the mathematical modeling of SOFCs, with particular emphasis on the use of ANNs. Up to now, most of the equations involved in SOFC models have required the addition of numerous factors that are difficult to determine. The artificial neural network (ANN) can be applied to simulate an object's behavior without an algorithmic solution, merely by utilizing available experimental data. The ANN methodology discussed in Advanced Methods of Solid Oxide Fuel Cell Modeling can be used by both researchers and professionals to optimize SOFC design. Readers will have access to detailed material on universal fuel cell modeling and design process optimization, and will also be able to discover comprehensive information on fuel cells and artificial intelligence theory.

This is the first in-depth presentation in book form of current analytical methods for optimal design, selection and evaluation of instrumentation for process plants. The presentation is clear, concise and systematic-providing process engineers with a valuable tool for improving quality, costs, safety, loss prevention, and production accounting.

From Chapter 1 Introduction
"Instrumentation is needed in process plants to obtain data that are essential to perform several activities. Among the most important are control, the assessment of the quality of products, production accounting… and the detection of failures related to safety. In addition, certain parameters than cannot be measured directly, such as heat exchanger, fouling or column deficiencies, are of interest. Finally, new techniques, such as on-line optimization, require the construction of reliable computer models for which the estimation of process parameters is essential.

"This book concentrates on the tasks of determining the optimal set of measured variables and selecting the accuracy and reliability of the corresponding instruments. The goal is to obtain sufficiency accurate and reliable estimates of variables of interest while filtering bad data due to possible instrument malfunction. An additional goal is to observe and diagnose single and multiple process faults."

From the Preface
"There is a vast amount of literature devoted to the selection and good maintenance of instruments. This literature covers the selection of the right instrument for a particular range and system, but only after the desired accuracy and reliability of measurement have been established. Little has been written on how to systematically determine the right accuracy and reliability needed when selecting an instrument, much less how much redundancy is needed for a particular system. The key variables that needed estimation come from control requirements, as well as monitoring needs for safety, quality control and production accounting. These are the starting points of the design methodology. This book concentrates on determining the optimal accuracy and reliability of instruments and their location. To determine this, certain desired properties of the system of instruments are used as constraints while the cost is minimized. These properties, among others are variable observability, system reliability and precision of certain variables.

"This book is not a textbook. Rather it is intended to be an organized collection of the most relevant work in this area…. It has been written with the intention of making it readable by engineers with some background in linear algebra, mathematical optimization and graph theory. It is organized so that the complexity of the sensor network design is addressed step by step."

The information in this new book serves the needs of chemical and other process engineers involved in instrumentation and control, maintenance, plant operations, process design, process development, quality control, safety, and loss prevention.

Illustrations and Tables
The text is supplemented with more than 100 flow charts, diagrams and other schematics that illustrate procedures, systems and instrumentation. More than 70 tables provide useful reference data.
The Author
Dr. Miguel J. Bagajewicz brings to this new book his extensive experience in design, data management, teaching and writing in the area of process engineering. He received his M.S. and Ph.D. in Chemical Engineering from the California Institute of Technology. He is presently Associate Professor, School of Chemical Engineering and Materials Science, and Director, Center for Engineering Optimization at the University of Oklahoma. He is the author or co-author of more than 100 journal articles, conference presentations, and reports, and the author of articles on data reconciliation and sensor location in the Instrument Engineers' Handbook, fourth edition. He is a member of the American Institute of Chemical Engineers (AIChE), and on the executive committee of the Central Oklahoma Chapter.

When a pharmaceutical company decides to build a Quality System, it has to face the fact that there aren't any guideline that define exactly how such a system has to be built. With terms such as quality system, quality assurance, and quality management used interchangeably, even defining the system's objectives is a problem. This book provides a practical guide to building a quality system. Beginning with explanations of key terms and concepts, it covers ISO 9000 and GMP and how to combine them, and includes a matrix showing their similarities and differences. Implementation reviews illustrate how Quality (Management) Systems have been installed successfully in pharmaceutical companies. Also covered are the individual components of a Quality System; auditing, validation, and supplier qualification systems; and Hazard Analysis Critical Control Points (HACCP).

The petrochemical industry is a scientific and engineering field that encompasses the production of a wide range of chemicals and polymers. The purpose of this book is not only to provide a follow-on to form the later chapters of the highly successful Chemistry and Technology of Petroleum 5th Edition but also provides a simplified approach to a very diverse chemical subject dealing with the chemistry and technology of various petroleum and petrochemical process. Following from the introductory chapters, this book provides the readers with a valuable source of information containing insights into petrochemical reactions and products, process technology, and polymer synthesis. Provides readers with a valuable source of information containing insights into petrochemical reactions and products, process technology, and polymer synthesis Introduces the reader to the various petrochemical intermediates are generally produced by chemical conversion of primary petrochemicals to form more complicated derivative products The reactions and processes involved in transforming petroleum-based hydrocarbons into the chemicals that form the basis of the multi-billion dollar petrochemical industry are reviewed and described The book includes information on new process developments for the production of raw materials and intermediates for petrochemicals Includes a description of the origin of the raw materials for the petrochemicals industry - including an overview of the coal chemicals industry

Synthesizing research from a wide variety of sources, this work offers a convenient guide to a clean, safe, inexpensive, non-toxic, non-polluting solvent that performs better than most conventional solvents. Natural Extracts Using Supercritical Carbon Dioxide reviews recent development in the technology and its applications to the food, flavor, fragrance, and pharmaceutical industries. It outlines the many advantages the method has over traditional methods like steam distillation, solvent extraction, and molecular distillation and it supports the popular trend toward the use of natural products in these industries.

Waste minimisation has a number of aims which include enhancing the intrinsic selectivity of any given process, providing a means of recovering reagents in a form which allows easy regeneration and the replacement of stoichiometric processes with catalytic ones. Solids, as catalysts or as supports for other reagents, offer potential for benefit in all these areas. This monograph provides an overview of the properties of the more useful solid catalysts and supported reagents, and highlights their most valuable applications in the preparation of organic chemicals in liquid phase reactions. Clean Synthesis Using Porous Inorganic Solid Catalysts and Supported Reagents is concerned with the use of solid catalysts in the clean synthesis of organic chemicals. The emphasis is on chemical processes of importance to the manufacture/preparation of fine and speciality chemicals, chemical intermediates and pharmaceutical intermediates, especially where catalysis is not currently used or where current catalysts are homogeneous, leading to difficult separation procedures and unacceptable levels of waste. This book focuses on solid catalysts based on inorganic supports and covers the emerging area of chemically modified mesoporous solid catalysts.

The Definitive, Learner-Friendly Guide to Chemical Engineering Separations--Extensively Updated, Including a New Chapter on Melt Crystallization Efficient separation processes are crucial to addressing many societal problems, from developing new medicines to improving energy efficiency and reducing emissions. Separation Process Engineering, Fifth Edition, is the most comprehensive, accessible guide to modern separation processes and the fundamentals of mass transfer. In this completely updated edition, Phillip C. Wankat teaches each key concept through detailed, realistic examples using actual data--with up-to-date simulation practice, spreadsheet-based exercises, and references. Wankat thoroughly covers each separation process, including flash, column, and batch distillation; exact calculations and shortcut methods for multicomponent distillation; staged and packed column design; absorption; stripping; and more. His extensive discussions of mass transfer and diffusion enable faculty to teach separations and mass transfer in a single course. And detailed material on liquid-liquid extraction, adsorption, chromatography, and ion exchange prepares students for advanced work. New and updated content includes melt crystallization, steam distillation, residue curve analysis, batch washing, the Shanks system for percolation leaching, eutectic systems, forward osmosis, microfiltration, and hybrid separations. A full chapter discusses economics and energy conservation, including updated equipment costs. Over 300 new and updated homework problems are presented, all extensively tested in undergraduate courses at Purdue University. New chapter on melt crystallization: solid-liquid phase equilibrium, suspension, static and falling film layer approaches, and 34 questions and problems New binary VLE equations and updated content on simultaneous solutions New coverage of safety and fire hazards New material on steam distillation, simple multi-component batch distillation, and residue curve analysis Expanded discussion of tray efficiencies, packed column design, and energy reduction in distillation New coverage of two hybrid extraction with distillation, and the Kremser equation in fractional extraction Added sections on deicing with eutectic systems, eutectic freeze concentration, and scale-up New sections on forward osmosis and microfiltration Expanded advanced content on adsorption and ion exchange including updated instructions for eight detailed Aspen Chromatography labs Discussion of membrane separations, including gas permeation, reverse osmosis, ultrafiltration, pervaporation, and applications Thirteen up-to-date Aspen Plus process simulation labs, adaptable to any simulator This guide reflects an up-to-date understanding of how modern students learn: designed, organized, and written to be exceptionally clear and easy to use. It presents detailed examples in a clear, standard format, using real data to solve actual engineering problems, preparing students for their future careers.

There have been several attempts to write the history of Britain's chemical industry as a whole, and countless others concentrating on individual companies. Some have looked at the technical aspects of the industry, whilst others have addressed economic issues. Few have, however, attempted to analyse the effects of the chemical industry on society in general. The current environmental crisis can only be fully understood in the light of its history. This is the first such book to look critically at the whole development of industrial chemistry in the UK in the context of its effects on the environment. No one from industry, government or academia can afford to be unaware of the historical roots of our present dilemma. Industrial chemists can take heart from the realization that their predecessors were remarkably aware of the problems and often found satisfactory solutions. Industrial chemistry has traditionally been seen as the great 'polluter'. Without any attempts at 'whitewash' this book puts the record straight. From academic chemist to industrialist to politician, Chemistry, Society and Environment: A New History of the British Chemical Industry will be of relevance to all those concerned with the social and environmental impact of the chemical industry.

This book presents part of the proceedings of the Manufacturing and Materials track of the iM3F 2020 conference held in Malaysia. This collection of articles deliberates on the key challenges and trends related to manufacturing as well as materials engineering and technology in setting the stage for the world in embracing the fourth industrial revolution. It presents recent findings with regards to manufacturing and materials that are pertinent towards the realizations and ultimately the embodiment of Industry 4.0, with contributions from both industry and academia.

This long-awaited, revised and updated reference/text combines a thorough description of the origin and application of fundamental chemical kinetics through an assessment of realistic reactor problems with an expanded discussion of kinetics and its relation to chemical thermodynamics. Provides exercises of gradiating difficulty that range from simple applications of equations and concepts developed in the text to open-ended situations drawing on creative thinking Adds a host of worked-out illustrations and a notation list after each chapter, reinforcing important concepts Retaining the careful organization and logical progression of ideas that characterized the first edition, the Second Edition of Reaction Kinetics and Reactor Design clarifies chain and polymerization reactions in greater depth contains new material on microbial and enzyme kinetics and adsorption-desorption theory streamlines the presentation of the derivations arising from the kinetic theory of gases addresses transport effect in catalytic reactions explains gas-solid noncatalytic reactions covers the development of two-phase reactor theory based on plug flow, mixing cell, and dispersion models introduces theory and design of fluid slurry and trickle beds examines catalyst deactivation phenomena, ion exchange, and chromatographic reactors and more Including over 1450 equations for developing rational chemical reactor designs and analysis models, the Second Edition of Reaction Kinetics and Reactor Design is an excellent reference for chemical, mechanical, petroleum, plant, process, civil, and design engineers, and an ideal text for upper-level undergraduate and graduate students in these disciplines.

"Serves as a comprehensive introduction to the preparation, uses, and physical chemistry of silicone surfactants--focusing on silicone polyoxyalkylene copolymers that are surface active in both aqueous and nonaqueous systems. Covers applications in the manufacture of polyurethane foam, coatings, wetting agents, fabric finishes, and polymer surface modifiers."

This book covers the principles of cryopreservation as they relate the preservation of viable cells and cell materials being developed for biopharmaceutical applications. Topics include: the principles of freezing and thawing cells, physiochemical phenomena, process and system design options, method selection considerations, preservation procedures, cryoprotectant additives, freeze-drying human live virus vaccines, and transport system selection criteria. Contributions from well-known experts such as Steven S. Lee, Thomas C. Pringle, William H. Siegel, Richard Wisniewski, and Fangdong Yin make this the single most important study available.

Editors: V.B. Fainerman, G. Loglio, E.H. Lucassen-Reynders, R. Miller and P. Petrov

This monograph provides a comprehensive introduction into the fast developing research field of dynamic processes at liquid/gas and liquid/liquid interfaces to postgraduate students, scientists and engineers interested in the fundamentals of non-equilibrium interfacial properties. It also addresses to some extent application fields, such as foams and emulsions. Theory and experiments on dynamic adsorption layers are considered systematically and discussed with respect to processes at interfaces.
It is both an introduction for beginners in the present field as well as a systematic preparation of a vast range of the current scientific investigations generalised, together with accumulated knowledge for those already being an insider. It is the first extensive review available on the subject of dynamics of adsorption and gives a general summary of the current state of adsorption kinetics theory and experiments. The book also reviews recent progress in new-designed set-ups and improved and generalised known methods for studying interfacial relaxations.

New process technology strategies are required to cope with the future. Fossil feedstocks are losing ground in favour of renewable feedstocks and secondary resources. Conventional processing routes using thermal "sledgehammer" techniques are replaced by highly selective (bio)catalytic conversions. The future process engineer is neither allowed to think in terms of unit operations, nor to take for granted the conventional practice of continuous steady state processing. Hybrid systems and transient operations are more and more frequently encountered. The continuing impressive progress being made in process modelling and control will revolutionize the process industries. In the new generation of chemical production processes the keyword is precision. Precision, in terms of selectivity and of efficiency, is required to maximize the utilisation of materials and energy. Moreover, enhanced precision is needed to exploit the quality of materials and energy to the full extent. Only by reducing the squandering of materials, energy and quality will a harmonious relationship be established between the process industries, the economy, and the environment. Process integration, as well as an integrated effort by the disciplines involved in process technology, will be of crucial importance in attaining the goals of precision process technology. These emerging strategies involve an active exchange of tools and ideas between a variety of disciplines, not only in plant design and operation, but even more in the early stages of process development and design. By looking from various angles at what the future has in store for the process industries, this volume systematically lifts the corners of the veil and may help to establish a new tradition of precision in process technology.

Simple, but beautifully versatile. Perhaps not a description many would choose for hydrogen peroxide, but an accurate one none the less, and this unique book explains the reasons behind the description. Beginning with an historical overview, and guidelines for the safe handling of peroxygens, Applications of Hydrogen Peroxide and Derivatives goes on to cover key activation mechanisms, organic functional group oxidations and the use of hydrogen peroxide with heterogeneous catalysts. The clean-up of environmental pollutants; chemical purification; and extraction of metals from their ores are also discussed in detail, using actual examples from industry. The versatility of this reagent may well prove to be a key to integrated pollution control in the future. This book should therefore be read by academics and industrialists at all levels, to encourage wider applications of the use of hydrogen peroxide in laboratories.

This book presents the chemical properties of lignocellulosic fibers, knowledge of which is essential for innovation and sustainable development of their transformation. Thermochemical transformation of wood and other lignocellulosics is presented to highlight its volatile, liquid and solid products and their novel applications. Forest biorefinery is described to emphasize the new products from lignocellulosic constituents, both structural (cellulose, hemicelluloses and lignins) and those extraneous to cell walls-extractives. New developments in cellulose technology related to nanocellulose are discussed in relation to new applications. Industrial lignins are presented in detail, both in terms of extraction procedures from spent liquors and structural characterization of the isolated lignins. Application of lignocellulosic biopolymers in new composite materials, or in biomaterials for medicinal purposes, and in solid wood preservation, are described. The example of an industrial biorefinery installed in southwestern France more than 40 years ago is presented.