This book summarizes the authors' extensive experience and interdisciplinary approach to demonstrate how acquiring and integrating data using a variety of analytical equipment can provide better insights into unconventional shale reservoir rocks and their constituent components. It focuses on a wide range of properties of unconventional shale reservoirs, discussing the use of conventional and new analytical methods for detailed measurements of mechanical properties of both organic and inorganic constituent elements as well as of the geochemical characteristics of organic components and their origins. It also addresses the investigation of porosity, pore size and type from several perspectives to help us to define unconventional shale formation. All of these analyses are treated individually, but brought together to present the rock sample on a macro scale. This book is of interest to researchers and graduate students from various disciplines, such as petroleum, civil, and mechanical engineering, as well as from geoscience, geology, geochemistry and geophysics. The methods and approaches can be further extended to biology and medicine.

Single-Use Technology (SUT) is the first comprehensive publication of practical considerations for each stage of the implementation process of SUT, and covers the selection, specification, design and qualification of systems to meet end-user requirements. Having become readily available for all processing operations within the biopharmaceutical industry, SUT has the potential to reduce capital costs, improve plant throughput and reduce the risk of cross-contamination. However, there are no clear guidelines to aid the end-user on implementation of these technologies into a validated, good manufacturing practice (GMP) environment. This book presents approaches for the implementation within various end-user facilities and systems, SUT within regulatory frameworks (ICH Q8, Q9, Q10 and GMP), standardisation and assessment strategies, specifation of user requirements and SUT design, risk assessment and evaluation as well as qualification for different SUT types.

Distillation Theory and Its Application to Optimal Design of Separation Units presents a clear, multidimensional geometric representation of distillation theory that is valid for all distillation column types, splits, and mixtures. This representation answers such fundamental questions as: - What are the feasible separation products for a given mixture? - What minimum power is required to separate a given mixture? - What minimum number of trays is necessary to separate a given mixture at a fixed power input? Concepts are reinforced by chapter exercises using free DistillDesigner software, which provides quick and reliable solutions to problems of flowsheet synthesis and to optimal design calculations. This software allows refinement and confirmation of the algorithms of optimal design. This book is intended for students and specialists in the design and operation of separation units in the chemical, pharmaceutical, food, wood, petrochemical, oil-refining, and natural gas industries and for software designers.

Written by Laurence Britton, who has over 20 years' experience in the fields of static ignition and process fire and explosion hazards research, this resource addresses an area not extensively covered in process safety standards or literature: understanding and reducing potential hazards associated with static electricity. The book covers the nature of static electricity, characteristics and effective energies of different static resources, techniques for evaluating static electricity hazards, general bonding, grounding, and other techniques used to control static or prevent ignition, gases and liquids, powders and hybrid mixtures.

Drawing on over 45 years of hands-on experience, the author provides in-depth knowledge of water-blown cellular polymers, from their chemistry to formulation and process methodology. This book describes the manufacture of standard and specialty foams using new and emerging technologies. The author gives advice on the challenges foam producers commonly face with regard to formulations and makes recommendations for machinery and equipment.

Rubber materials serve a variety of purposes in our everyday life. This book gives a complete survey of the life cycle of rubber materials starting from the basics and covering everything to recycling of rubber. The important aspects for researchers and engineers in rubber industry such as vulcanization, thermoplastic elastomers, additives and fillers and rubber bonding is covered in one chapter each.

Chemical Analysis provides non invasive and micro-analytical techniques for the investigation of cultural heritage materials. The tools and techniques, discussed by experts in the field, are of universal, sensitive and multi-component nature.

Filling a longstanding gap for graduate courses in the field, Chemical Reaction Engineering: Beyond the Fundamentals covers basic concepts as well as complexities of chemical reaction engineering, including novel techniques for process intensification. The book is divided into three parts: Fundamentals Revisited, Building on Fundamentals, and Beyond the Fundamentals. Part I: Fundamentals Revisited reviews the salient features of an undergraduate course, introducing concepts essential to reactor design, such as mixing, unsteady-state operations, multiple steady states, and complex reactions. Part II: Building on Fundamentals is devoted to "skill building," particularly in the area of catalysis and catalytic reactions. It covers chemical thermodynamics, emphasizing the thermodynamics of adsorption and complex reactions; the fundamentals of chemical kinetics, with special emphasis on microkinetic analysis; and heat and mass transfer effects in catalysis, including transport between phases, transfer across interfaces, and effects of external heat and mass transfer. It also contains a chapter that provides readers with tools for making accurate kinetic measurements and analyzing the data obtained. Part III: Beyond the Fundamentals presents material not commonly covered in textbooks, addressing aspects of reactors involving more than one phase. It discusses solid catalyzed fluid-phase reactions in fixed-bed and fluidized-bed reactors, gas-solid noncatalytic reactions, reactions involving at least one liquid phase (gas-liquid and liquid-liquid), and multiphase reactions. This section also describes membrane-assisted reactor engineering, combo reactors, homogeneous catalysis, and phase-transfer catalysis. The final chapter provides a perspective on future trends in reaction engineering.

PEO Unsaturated Macromonomers ................... 21 PEO Saturated Macromonomers ..................... 24 PEO Block and Graft Copolymers .................... 25 Dispersion Polymerization of PEO Macromonomers ......... 27 Copolymerization of PEO Macromonomers with Styrene ...... 27 Copolymerization of PEO Macromonomers with Alkyl Acrylates and Methacrylates .................... 33 Emulsion Polymerization of PEO Macromonomers ......... 34 Homopolymerization of PEO Macromonomers ............ 34 Copolymerization of PEO Macromonomers with Styrene ...... 39 Copolymerization of PEO Macromonomers with Other Comonomers ............................ 45 Polymerization of PEO Macromonomers in Other Disperse Systems .......................... 48 Conclusion ................................. 50 References ................................. 52 List of Abbreviations and Symbols A acrylic group second virial coefficient A2 AA acrylic acid AVA 4,4'-azobis(4-cyanovaleric acide) AIBN 2,2'-azobiisobutyronitrile B A butyl acrylate BzMA benzyl methacrylate BMA butyl methacrylate CAC critical association concentration concentration of monomer in water cw concentration of polymer micelle concentration CMC critical CFC critical flocculation concentration CFT critical flocculation temperature chain length (CL) Radical Polymerization of Polyoxyethylene Macromonomers in Disperse Systems 3 methyl Cl t-butyl tC4 chain transfer constant to stabilizer cs chain transfer to solvent css chain transfer constant for transfer to polymeric stabilizer CSP D particle diameter DLS dynamic light scattering volume median diameter D50 final particle diameter " f DBP dibenzoyl peroxide number average degree of polymerization DPn diffusion coefficient of the radical in water " w overall activation energy EO activation energy for propagation E activation energy for termination E t activation energy for decomposition of initiator Ed EO ethylene oxide unit f initiator efficiency monomer feed composition fw graft available G a graft required G r HLB hydrofile-lipophile balance

This edited volume deals with the attempts made by the scientists and practitioners to address contemporary issues in geoenvironmental engineering such as characterization of dredged sediments, geomaterials and waste, valorization of waste, sustainability in waste management and some other geoenvironmental issues that are becoming quite relevant in today's world especially in view of the high urbanization rates, advancement in technologies, and changes in consumption behavior of people. In this regard, wastes generated through the daily activities of individuals and organizations pose many challenges in their management. The volume is based on the best contributions to the 2nd GeoMEast International Congress and Exhibition on Sustainable Civil Infrastructures, Egypt 2018 - The official international congress of the Soil-Structure Interaction Group in Egypt (SSIGE).

Research into "smart rubbers", i.e. elastomeric materials that respond to external stimuli, has increased dramatically recently, predominantly due to the growing need for improved materials for new applications. This book aims to provide an overview over the field of smart rubber research. Examples of the various components involved in smart rubbers are highlighted and discussed. Different types of stimuli and numerous applications are explained.

There is a growing need in the chemical industry for trained specialists who have not only a solid chemical knowledge, but also a basic understanding of the underlying management processes; this book specifically addresses this need. Business Chemistry: How to Build Thriving Businesses in the Chemical Industry presents a solution-oriented approach to the key topics of strategic and innovation management, business model innovation, cross-functional integration of R&D, marketing functions and operations management, specifically designed to address core managerial issues relevant for chemists. The book is divided into three sections as follows: Part One: Strategy and Management looks at the principles of strategy, qualitative and quantitative methods in strategic management, and managing business co-operation. Part Two: Innovation and Entrepreneurship addresses the principles of research, technology and innovation; the tools, people and processes required for innovation management; recognizing, managing and developing new business opportunities, and opportunities for corporate entrepreneurship. Part Three: Operations and Marketing discusses the day to day operations management in research-intensive industries; the principles of marketing; supplier-integration; managing efficiency and customer needs. Each chapter presents possible solutions for management problems supported by the latest academic research, practical examples from the chemical industry, and case studies supported by industry experts Business Chemistry: How to Build Thriving Businesses in the Chemical Industry offers chemists and other natural scientists employed in research-intensive industries the possibility to develop essential management skills carefully crafted to their respective industry. It also provides students interested in business management and entrepreneurship in the chemical industry, with a clear understanding of essential management skills and capabilities.

This book examines the background of fourth-generation biofuel production, use of genetically modified microalgae for production of fourth-generation biofuels; cultivation and harvesting of genetically modified microalgae; residue from biofuel extraction; health and environmental concerns of fourth-generation biofuels; regulations on cultivation and processing of the genetically modified algae; carbon dioxide sequestration; water footprint and current status and key challenges. The topic caters to academic researchers and industrial experts, who work in the field of biofuels as source of alternative fuel to achieve environmental and economic sustainability.

This book outlines the most recent progress in the development of technologies for carbon dioxide utilization into renewable synthetic fuels and platform chemicals via chemical and biological routes. Various processes are discussed, including thermocatalytic, electrocatalytic, photocatalytic, and biological conversion. This SpringerBrief consists of four chapters, each chapter outlining fundamentals and catalytic mechanisms, and discussing main design considerations and major technological challenges, providing also a brief outline of the most recent progress. The book is useful for a broad community of academic and industrial researchers in the fields of chemical reaction engineering, electro- and photo-chemistry, and biochemical engineering, with specific emphasizes on heterogeneous catalysis, reactor design and process development.

Presents a rigorous development of thermodynamic laws of phase equilibria beginning with fundamental principles, accompanied by a short description of the mathematics vital to a clear understanding of basic concepts as well as the practical methods used to calculate phase equilibria. Offers excellent explanations of well-established thermodynamic tools and novel, state-of-the-art techniques representing real fluid behavior. Models covered are relevant to the modeling of nonelectrolyte mixtures over wide ranges of pressure, temperature, composition and molecular diversity.

This book provides informative, useful, and stimulating reading on the topic of organic sonochemistry - the core of ultrasound-based applications. Given the increasing interest in new and improved technologies, allied to their green and sustainable character (not always a valid premise), there is a great attraction for organic chemists to apply these protocols in synthesis and process chemistry. Unfortunately, as with other enabling technologies, many researchers new to the field have received a simple and dishonest message: just switch on! Therefore a significant portion of sonochemical syntheses lack reproducibility (surprisingly cavitation control and/or ultrasonic parameters are omitted) and the actual role of sonication remains uncertain. While this book does not provide a detailed description of fundamentals, the introductory remarks highlight the importance of cavitational effects and their experimental control. It presents a number of concepts of sonochemical reactivity and empirical rules with pertinent examples, often from classical and recent literature. It then focuses on scenarios of current interest where organic chemistry, and synthesis in particular, may benefit from sonication in terms of both chemical and mechanical activation. The "sustainable corner" of this field is largely exemplified through concepts like atom economy, renewable sources, wasteless syntheses, and benign solvents as reaction media. This book is useful for both researchers and graduate students, especially those familiar with the field of sonochemistry and applications of ultrasound in general. However, it is also of interest to a broader audience as it discusses the fundamentals, techniques, and experimental skills necessary for scientists wishing to initiate the use of ultrasound in their domain of expertise.

The book gives a systematic introduction to green chemistry principles and technologies in inorganic and organic chemistry, polymer sciences and pharmaceutical industry. It also discusses the use of biomass and marine resources for synthesis as well as renewable energy utilization and the concepts and evaluation of recycling economy and eco-industrial parks.

This brief summarizes the most commonly used sulfur dioxide surrogates and also shows the diverse reactivities to highlight the advances made in the development of synthetic methods through the insertion of sulfur dioxide. Depending on the nature of the transformation, these reactions are classified into four types: (i) pericyclic reactions; (ii) nucleophilic addition with organometallic reagents; (iii) transition metal catalysis; and (iv) free radical reactions. Highlighting recent advances in the insertion of sulfur dioxide, providing detailed descriptions of the experimental procedures for these valuable reactions, and discussing the remaining challenges in this field, the brief offers an appealing and highly useful guide for a wide readership in organic chemistry and medicinal chemistry from both academia and industry.

Biohydrogen: For Future Engine Fuel Demands covers the production, purification, storage, pipeline transport, usage, and safety of biohydrogen. Hydrogen promises to be the most significant fuel source of the future, due to its global availability and the fact that water is its only by-product. Biofuels such as bioethanol, biodiesel, bio-oil, and biohydrogen are produced using technologies for thermochemically and biologically converting biomass. Hydrogen fuel production technologies can make use of either non-renewable sources, or renewable sources such as wind, solar, and biorenewable resources.

Biohydrogen: For Future Engine Fuel Demands reviews all of the modern biomass-based transportation fuels, including bioethanol, biodiesel, biogas, biohydrogen, and fuel cells. The book also discusses issues of biohydrogen economy, policy and environmental impact. Biohydrogen looks set to be the fuel of choice in the future, replacing both fossil fuels and biorenewable liquid fuels.

This book offers the state of the art on the progress and accomplishments of 25 years of research at the Associate Laboratory LSRE-LCM - Laboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials on lignin conversion to value-added products and their downstream separation. The first valorisation pathway presented for lignin is its partial depolymerisation by oxidation for the production of low molecular weight phenolic compounds, such as vanillin and syringaldehyde, and the second one is the lignin application as macromonomer for polyurethane synthesis. In this book, the authors present the integration of these two valorisation pathways as an exclusive vision of LSRE-LCM resulting from hands-on experience on reaction and separation processes: the integrated process for lignin valorisation. In this perspective, the lignin is oxidized to simultaneously produce syringaldehyde and vanillin, and the obtained by-products to produce a polyol for lignin-based polyurethanes, completing the lignin value chain. On the perspective of pulp mill-related biorefineries, a valorisation route for eucalyptus bark is also presented, focusing on LSRE-LCM experience on extraction and separation of bioactive polyphenols, giving some insights about further integration of extracted bark on biorefining operations.

A membrane is considered the heart of every separation process because it is developed as a nanostructured/nanofunctionalized thin barrier that controls the exchange between two phases, not only by external forces and under the effect of fluid properties, but also through the intrinsic characteristics of the membrane material itself. This book compiles cutting-edge research in membrane science, nanomaterials, and nanotechnologies, mainly from interdisciplinary research groups at the Institute on Membrane Technology, National Research Council (ITM-CNR), Italy, working on membrane design, membrane process engineering, and selected materials and practices for enhanced transport mass, charge, and energy. It covers topics on the design of new nanostructured membranes with improved properties, together with the identification of efficient transport-property relationships. It shares and strengthens the knowledge of making membrane technology a much more powerful and eco-friendly route, enabling one to provide prospective solutions and benefits for numerous fields of applications where traditional separation technologies suffer from many deficiencies. It is a great reference for researchers and investigators; graduate, PhD, and postgraduate students; and end users interested in membrane science and technology, nanomaterials, eco-friendly separation, chemistry, biology, and process engineering.

Focusing on current and future uses of microbes as production organisms, this practice-oriented textbook complements traditional texts on microbiology and biotechnology. The editors have brought together leading researchers and professionals from the entire field of industrial microbiology and together they adopt a modern approach to a well-known subject. Following a brief introduction to the technology of microbial processes, the twelve most important application areas for microbial technology are described, from crude bulk chemicals to such highly refined biomolecules as enzymes and antibodies, to the use of microbes in the leaching of minerals and for the treatment of municipal and industrial waste. In line with their application-oriented topic, the authors focus on the "translation" of basic research into industrial processes and cite numerous successful examples. The result is a first-hand account of the state of the industry and the future potential for microbes in industrial processes. Interested students of biotechnology, bioengineering, microbiology and related disciplines will find this a highly useful and much consulted companion, while instructors can use the case studies and examples to add value to their teaching.

This book provides an overview of fuel cell technology and, in particular, of Solid Oxide Electrolysis Cells (SOFCs). Each chapter highlights the effects of different synthesis parameters and/or adopted sintering method, clarifying both advantages and disadvantages pointed out by different experimental campaigns. The book focuses on Doped-Ceria Electrolytes, presenting an engineered production process of GDC/SDC electrolytes by using a combination of wet chemical synthesis and/or alternative sintering techniques, capable of enhancing electrolytes microstructural features and electrical properties at reduced temperature and time. The author proposes useful guidelines to produce dense and high-preforming ceria-based electrolytes for IT-SOFCs.

This book examines the development and utilization of alternative fuels in order to reduce or control the environmental impact of internal combustion engine exhaust gases. Discussing alternative fuels such as dual fuel techniques, rubber seed/palm oil biodiesel, syngas dual-fuelling, water-in-diesel emulsions and gasification of date palm seeds, it is a valuable resource for researchers in the field of engine development and on alternative fuels.