In the past decades, the scan rate range of calorimeters has been extended tremendously at the high end, from approximately 10 up to 10 000 000 DegreesC/s and more. The combination of various calorimeters and the newly-developed Fast Scanning Calorimeters (FSC) now span 11 orders of magnitude, by which many processes can be mimicked according to the time scale(s) of chemical and physical transitions occurring during cooling, heating and isothermal stays in case heat is exchanged. This not only opens new areas of research on polymers, metals, pharmaceuticals and all kinds of substances with respect to glass transition, crystallization and melting phenomena, it also enables in-depth study of metastability and reorganization of samples on an 1 to 1000 ng scale. In addition, FSC will become a crucial tool for understanding and optimization of processing methods at high speeds like injection molding. The book resembles the state-of-the art in Thermal Analysis & Calorimetry and is an excellent starting point for both experts and newcomers in the field.

This book reviews the fundamental aspects of quinoxaline chemistry: synthesis, reactions, mechanisms, structure, properties, and uses. The first four chapters present a survey of the developments in quinoxaline chemistry since the publication of the monograph on "Condensed Pyrazines" by Cheeseman and Cookson in 1979. These chapters give comprehensive coverage of all the methods of the synthesis of quinoxalines and the important quinoxaline-containing ring systems such as thiazolo[3,4-a]-, pyrrolo[1,2-a]-, and imidazo[1,5-a]quinoxalines. Chapter five describes many new methods for the construction of quinoxaline macrocycles, which are important in applications such as optical devices and materials. The final chapter reviews all previously known rearrangements of heterocyclic systems that lead to benzimidazole derivatives. Mamedov critically analyses these transformations to reveal a novel acid-catalyzed rearrangement of quinoxalinones giving 2-heteroarylbenzimidazoles and 1-heteroarylbenzimidazolones in the presence of nucleophilic reactants (MAMEDOV Heterocycle Rearrangement). This book is of interest to researchers in the fields of heterocyclic and synthetic organic chemistry.

The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field.

This book focuses on the fundamental principles and recent progress in the field of electrical and thermal properties of polymer nanocomposites. The physical and chemical natures determining the electrical and thermal properties of polymer nanocomposites are discussed in detail. The authors describe the range of traditional and emerging polymer nanocomposites from nanoparticle and polymer composites to novel nanostructure based polymer nanocomposites. They include novel properties and potential applications, such as high-k, low-k, high thermal conductivity, antistatic, high voltage insulation, electric stress control, and thermal energy conversion among others.

This book provides comprehensive, state-of-the art coverage of photorefractive organic compounds, a class of material with the ability to change their index of refraction upon illumination. The change is both dynamic and reversible. Dynamic because no external processing is required for the index modulation to be revealed, and reversible because the index change can be modified or suppressed by altering the illumination pattern. These properties make photorefractive materials very attractive candidates for many applications such as image restoration, correlation, beam conjugation, non-destructive testing, data storage, imaging through scattering media, holographic imaging and display. The field of photorefractive organic material is also closely related to organic photovoltaic and light emitting diode (OLED), which makes new discoveries in one field applicable to others.

This second edition is a short and comprehensive study on the best known approaches for preparing the main types of glycosides. It covers synthetic pathways of challenging glycosides known as antiviral or antineoplastic drugs, and synthetic substrates used for enzymatic detection, including those used for detection of gene markers in plant biotechnology. The author pays special attention to the structural characterization of glycosides and provides the basic tools for the structural assignment through NMR, X-Ray and mass spectra techniques. The book also covers strategies for preparation of antiviral and antineoplastic drugs included in a drug design course.

This volume presents essential information on chemical reagents commonly used in flotation processes. It comprehensively summarizes the properties, preparation and applications of collectors, frothers, depressants and flocculants. It also discusses the microanalysis of flotation reagents and adsorption measurement. The book offers a valuable resource for all university researchers and students, as wells as R&D engineers in minerals processing and extractive metallurgy who wish to explore innovative reagents and technologies that lead to more energy efficient and environmentally sustainable solutions.

This book reviews and characterises promising single-compound solvents, solvent blends and advanced solvent systems suitable for CO2 capture applications using gas-liquid absorption. Focusing on energy efficient solvents with minimal adverse environmental impact, the contributions included analyse the major technological advantages, as well as research and development challenges of promising solvents and solvent systems in various sustainable CO2 capture applications. It provides a valuable source of information for undergraduate and postgraduate students, as well as for chemical engineers and energy specialists.

A unique feature of this book is its focus on nanotechnological solutions for the production of bioenergy and biofuels. Coverage includes topics such as nanobiotechnology, microalgae, biofuel cells, biomass pretreatment, and biomass conversion. An international team of experts also addresses the need to precisely characterize nanoparticles and the role of catalysts. The range of topics addressed, together with a chapter on risk management, make this book a highly useful resource for a broad readership including physicists, chemists, microbiologists, biotechnologists, food technologists, agricultural engineers, and nanotechnologists.

This book presents selected high-quality research papers submitted to ICNF 2017, the 3rd International Conference on Natural Fibers, which was held in Braga, Portugal, on 21-23 June 2017. It discusses the latest research and developments in the field and covers a wide range of topics related to various aspects of natural-fiber composites, such as production and processing of raw materials, surface modification and functionalization, advanced fibrous structures for composites, nano fibers, experimental characterization, modeling and analysis, design and product development, applications, market potential, and environmental impacts. The book presents the latest research work addressing different approaches and techniques to improve processing, performance, functionalities and cost-effectiveness of natural-fibers composites, in order to increase their applications in different industrial sectors such as automobiles, transportation, construction, and sport. & nbsp;

This book analyzes hydrocarbon generation and accumulation within space-limited source rocks. The authors draw conclusions based on the principles of basin formation, hydrocarbon generation and accumulation, coupled with the practice of terrigenous basins in eastern China. Hydrocarbon generation and expulsion have been quantitatively assessed in space-limited source rock systems. This book explores new hydrocarbon generation and expulsion models to reflect real geological situations more accurately. The theory and practice proposed in this book challenge the traditional theory of kerogen thermal degradation and hydrocarbon generation.

This book is a state of the art treatise on what has been done so far on measuring sustainability for decision making. Contributions will appeal to engineers and scientists engaged in technology development, assessment, and verification. Researchers working on engineering sustainability are likely to get ideas for further research in quantifying sustainability for industrial systems. Concepts described can be applied across all scales, from process technology to global sustainability; and challenges and limitations are also addressed. Readers will discover important insights about simulation-based approaches to process design and quantitative measurement techniques of sustainability for business and technology systems. Most of the examples and case studies are from chemical enterprises but the methodologies presented could be applicable to any system for which quantitative data for indicators are available, and the choice of the set of indicators of sustainability are comprehensive.

This monograph deals with the interrelationship between chemistry and physics, and especially the role played by quantum chemistry as a theory in between these two disciplines. The author uses structuralist approach to explore the overlap between the two sciences, looking at their theoretical and ontological borrowings as well as their continuity. The starting point of this book is that there is at least a form of unity between chemistry and physics, where the reduction relation is conceived as a special case of this unity. However, matters are never concluded so simply within philosophy of chemistry, as significant problems exist around a number of core chemical ideas. Specifically, one cannot take the obvious success of quantum theories as outright support for a reductive relationship. Instead, in the context of a suitably adapted Nagelian framework for reduction, modern chemistry's relationship to physics is constitutive. The results provided by quantum chemistry, in partic ular, have significant consequences for chemical ontology. This book is ideal for students, scholars and academics from the field of Philosophy of Science, and particularly for those with an interest in Philosophy of Chemistry and Physics.

This comprehensive work explores interfacial instability and pattern formation in dynamic systems away from the equilibrium state in solidification and crystal growth. Further, this significantly expanded 2nd edition introduces and reviews the progress made during the last two decades. In particular, it describes the most prominent pattern formation phenomena commonly observed in material processing and crystal growth in the framework of the previously established interfacial wave theory, including free dendritic growth from undercooled melt, cellular growth and eutectic growth in directional solidification, as well as viscous fingering in Hele-Shaw flow. It elucidates the key problems, systematically derives their mathematical solutions by pursuing a unified, asymptotic approach, and finally carefully examines these results by comparing them with the available experimental results. The asymptotic approach described here will be useful for the investigation of pattern formation phenomena occurring in a much broader class of inhomogeneous dynamical systems. In addition, the results on global stability and selection mechanisms of pattern formation will be of particular interest to researchers working on material processing and crystal growth. The stability mechanisms of a curved front and the pattern formation have been fundamental subjects in the areas of condensed-matter physics, materials science, crystal growth, and fluid mechanics for some time now. This book offers a stimulating and insightful introduction for all physicists, engineers and applied mathematicians working in the fields of soft condensed-matter physics, materials science, mechanical and chemical engineering, fluid dynamics, and nonlinear sciences.

This book provides an overview of hydrogen production from renewable resources such as ethanol using plasma or plasma-catalytic technologies. Further, it presents a balanced and comprehensive treatment of the core principles, novel plasma reactors and diagnostics, as well as state-of-the-art plasma energy applications. It brings together technological advances and research on plasma generators and their application in hydrogen production, including plasma-assisted alcohol reforming technology, plasma-catalytic alcohol reforming technology, the alcohol reforming mechanism, models of alcohol reforming for hydrogen production, the energy balance of hydrogen production from ethanol, and a comparison of alcohol reforming assisted by different plasma treatment systems. As such, it offers a valuable reference guide for scientists, engineers and graduate students in the fields of energy and environment, plasma physics and chemistry.

This book presents a design-driven investigation into smart materials developed by chemists, physicists, materials and chemical engineers, and applied by designers to consumer products, buildings, interfaces, or textiles. Introducing a class of smart materials (referred to as stimuli-responsive, morphing or kinetic materials) that move and change their shape in response to stimuli, the book presents their characteristics, advantages, potentials, as well as the difficulties involved in their application. The book also presents a large number of case studies on products, projects, concepts, and experiments employing smart materials, thus mapping out new design territories for these innovative materials. The case studies involve different fields of design, including product, interior, fashion, and communication design. Reflecting the growing demand for sustainable and human-centered design agendas, the book explores and reveals the role and influence of these new materials and technologies on design and human experience, and discusses how they can be used to redefine our objects and spaces so as to promote more resilient environments. The book offers an intriguing and valuable resource for design professionals, engineers, scientists and students alike.

This is the first book to deal with the innovative technologies in the field of textiles and clothing sustainability. It details a number of sustainable and innovative technologies and highlights their implications in the clothing sector. There are currently various measures to achieve sustainability in the textiles and the clothing industry, including innovations in the manufacturing stage, which is the crux of this book.

This book highlights the manufacturing and applications of acoustic textiles in various industries. It also includes examples from different industries in which acoustic textiles can be used to absorb noise and help reduce the impact of noise at the workplace. Given the importance of noise reduction in the working environment in several industries, the book offers a valuable guide for companies, educators and researchers involved with acoustic materials.

This book, provides a general introduction to the ideas and methods of statistical mechanics with the principal aim of meeting the needs of Master's students in chemical, mechanical, and materials science engineering. Extensive introductory information is presented on many general physics topics in which students in engineering are inadequately trained, ranging from the Hamiltonian formulation of classical mechanics to basic quantum mechanics, electromagnetic fields in matter, intermolecular forces, and transport phenomena. Since engineers should be able to apply physical concepts, the book also focuses on the practical applications of statistical physics to material science and to cutting-edge technologies, with brief but informative sections on, for example, interfacial properties, disperse systems, nucleation, magnetic materials, superfluidity, and ultralow temperature technologies. The book adopts a graded approach to learning, the opening four basic-level chapters being followed by advanced "starred" sections in which special topics are discussed. Its relatively informal style, including the use of musical metaphors to guide the reader through the text, will aid self-learning.

This book details all current techniques for converting bulk polymers into nano-size materials. The authors highlight various physical and chemical approaches for preparation of nano-size polymers. They describe the properties of these materials and their extensive potential commercial applications.

This book focuses on the fundamental principles and latest research findings in hydrogen energy fields including: hydrogen production, hydrogen storage, fuel cells, hydrogen safety, economics, and the impact on society. Further, the book introduces the latest development trends in practical applications, especially in commercial household fuel cells and commercial fuel cell vehicles in Japan. This book not only helps readers to further their basic knowledge, but also presents the state of the art of hydrogen-energy-related research and development. This work serves as an excellent reference for beginners such as graduate students, as well as a handbook and systematic summary of entire hydrogen-energy systems for scientists and engineers.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal

The book offers a comprehensive report on the design and optimization of a thermochemical heat storage system for use in buildings. It combines theoretical and experimental work, with a special emphasis on model-based methods. It describes the numerical modeling of the heat exchanger, which allows recovery of about two thirds of the waste heat from both solar and thermal energy. The book also provides readers with a snapshot of current research on thermochemical storage systems, and an in-depth review of the most important concepts and methods in thermal management modeling. It represents a valuable resource for students, engineers and researchers interested in thermal energy storage processes, as well as for those dealing with modeling and 3D simulations in the field of energy and process engineering.

This thesis describes the inception, design, and implementation of stereoselective desymmetrization reactions in the total synthesis of the natural products pactamycin and paspaline. In the case of pactamycin, the author develops a novel asymmetric Mannich reaction and symmetry-breaking reduction strategy to enable facile construction of the complex core architecture in fifteen steps using commercially available materials - the shortest synthesis to date. He subsequently demonstrates the flexibility of this approach in SAR investigations by highlighting the preparation of twenty-five unique pactamycin structural congeners. For paspaline, the author develops a biocatalytic desymmetrization strategy that allows the highly controlled synthesis of core stereochemistry and provides a platform for the development of new conceptual disconnections in the synthesis of "steroid-like" natural products. This thesis offers a valuable resource for students embarking on a PhD in total synthesis.

This book addresses the linear and nonlinear two-phase stability of the one-dimensional Two-Fluid Model (TFM) material waves and the numerical methods used to solve it. The TFM fluid dynamic stability is a problem that remains open since its inception more than forty years ago. The difficulty is formidable because it involves the combined challenges of two-phase topological structure and turbulence, both nonlinear phenomena. The one dimensional approach permits the separation of the former from the latter.The authors first analyze the kinematic and Kelvin-Helmholtz instabilities with the simplified one-dimensional Fixed-Flux Model (FFM). They then analyze the density wave instability with the well-known Drift-Flux Model. They demonstrate that the Fixed-Flux and Drift-Flux assumptions are two complementary TFM simplifications that address two-phase local and global linear instabilities separately. Furthermore, they demonstrate with a well-posed FFM and a DFM two cases of nonlinear two-phase behavior that are chaotic and Lyapunov stable. On the practical side, they also assess the regularization of an ill-posed one-dimensional TFM industrial code. Furthermore, the one-dimensional stability analyses are applied to obtain well-posed CFD TFMs that are either stable (RANS) or Lyapunov stable (URANS), with the focus on numerical convergence.