This book is intended to give readers an appreciation of what the future holds, as cutting-edge technologies in synthetic biology and pathway engineering and advanced bioprocessing development pave the way for providing goods and services to benefit humankind that are based on the synergy of two biomasses - i.e. of what a renewable feedstock could yield and an infinite microbial biomass could provide in terms of enzymes and biocatalysts. This 13-chapter book, with an introductory treatise on the guiding principles of green chemistry and engineering metrics, brings together a broad range of research and innovation agendas and perspectives from industries, academia and government laboratories using renewable feedstocks that include macroalgae and lignins. In addition, social-economic aspects and the pillars of competitiveness in regional cluster development are explored as we transition from fossil-fuel-based economies to a circular bioeconomy, with chemurgy and green chemistry being implicit to the innovation movement. The bulk of the book covers specific applications including the bioproduction of amino sugars, dicarboxylic acids, omega-3 fatty acids, starch and fermentable sugars from lignocellulosic materials, and phenolics as building blocks for polymer synthesis. Enzymatic systems for accessing chiral and special-purpose chemicals, as well as the development of specialized enzymes from macroalgae for biofuel and biochemical production are also addressed. Research gaps, hurdles to overcome in various biological processes, and present achievements in the production of biofuels and biochemicals from lignocellulosic materials are discussed. Going beyond the conventional expectation of discussing the production of drop-in chemicals, the book instead emphasizes how the potential of new chemicals and materials can be harnessed through innovative thinking and research. As such, it provides an invaluable reference source for researchers and graduate students interested in Chemurgy and Green Chemistry, as well as for practitioners in the field of industrial biotechnology and biobased industry. Peter C.K. Lau is a Distinguished Professor at Tianjin Institute of Industrial Biotechnology of the Chinese Academy of Sciences, and an Adjunct Professor at the Departments of Chemistry and Microbiology & Immunology, McGill University, Canada.

Biomimetics is an innovative paradigm shift based on biodiversity for sustainability. Biodiversity is not only the result of evolutionary adaption but also the optimized solution of an epic combinatorial chemistry for sustainability, because the diversity has been acquired by biological processes and technology, including production processes, operating principles, and control systems, all of which differ from human technology. In the recent decades, biomimetics has gained a great deal of industrial interest because of its unique solutions for engineering problems. In this book, researchers have contributed cutting-edge results from the viewpoint of two types of industrial applications of biomimetics. The first type starts with engineering tasks to solve an engineering problem using biomimetics, while the other starts with the knowledge of biology and its application to engineering fields. This book discusses both approaches. Edited by Profs. Masatsugu Shimomura and Akihiro Miyauchi, two prominent nanotechnology researchers, this book will appeal to advanced undergraduate- and graduate-level students of biology, chemistry, physics, and engineering and to researchers working in the areas of mechanics, optical devices, glue materials, sensor devices, and SEM observation of living matter.

This is the first book to deal with the innovative technologies in the field of textiles and clothing sustainability. It details a number of sustainable and innovative technologies and highlights their implications in the clothing sector. There are currently various measures to achieve sustainability in the textiles and the clothing industry, including innovations in the manufacturing stage, which is the crux of this book.

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

This volume presents essential information on chemical reagents commonly used in flotation processes. It comprehensively summarizes the properties, preparation and applications of collectors, frothers, depressants and flocculants. It also discusses the microanalysis of flotation reagents and adsorption measurement. The book offers a valuable resource for all university researchers and students, as wells as R&D engineers in minerals processing and extractive metallurgy who wish to explore innovative reagents and technologies that lead to more energy efficient and environmentally sustainable solutions.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.

This reference offers an overview of the bulk and surface properties of perovskite-like structures, and provides the latest discussions on the applications of these materials and processes. It also introduces ceramic methods for the processing of perovskite-derived high Tc cuprates.;Examining every available procedure for synthesizing high-surface-area perovskite oxides, this book: delineates processing techniques for preparing perovskite-derived high-critical-temperature superconductors; illustrates the relevance of physiochemical methods to investigate bulk and surface structures of perovskite compounds; explicates the importance of surface composition in the context of catalytic behaviour; summarizes methods of changing stoichiometry; shows how to design perovskite oxides for a given purpose; reviews key solid-state properties; and presents the major applications.

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.

This book discusses the mechanisms of electric conductivity in various ionic liquid systems (protic, aprotic as well as polymerized ionic liquids). It hence covers the electric properties of ionic liquids and their macromolecular counterpanes, some of the most promising materials for the development of safe electrolytes in modern electrochemical energy devices such as batteries, super-capacitors, fuel cells and dye-sensitized solar cells. Chapter contributions by the experts in the field discuss important findings obtained using broadband dielectric spectroscopy (BDS) and other complementary techniques. The book is an excellent introduction for readers who are new to the field of dielectric properties of ionic conductors, and a helpful guide for every scientist who wants to investigate the interplay between molecular structure and dynamics in ionic conductors by means of dielectric spectroscopy.

This book outlines the most recent progress in the development of technologies for carbon dioxide utilization into renewable synthetic fuels and platform chemicals via chemical and biological routes. Various processes are discussed, including thermocatalytic, electrocatalytic, photocatalytic, and biological conversion. This SpringerBrief consists of four chapters, each chapter outlining fundamentals and catalytic mechanisms, and discussing main design considerations and major technological challenges, providing also a brief outline of the most recent progress. The book is useful for a broad community of academic and industrial researchers in the fields of chemical reaction engineering, electro- and photo-chemistry, and biochemical engineering, with specific emphasizes on heterogeneous catalysis, reactor design and process development.

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

This text seeks to provide a comprehensive technical foundation and practical examples for casting process modelling technology. It highlights fundamental theory for solidification and useful applications for industrial production. It also details shape and ingot castings, semi-solid metalworking, and spray forming.

Membranes are an energy efficient separation technology that are now the basis for many water treatment and food processing applications. However, there is the potential to improve the operating performance of these separations and to extend the application of membranes to energy production, gas separations, organic solvent-based separations, and biomedical applications through novel membrane materials. This book contains 20 chapters written by leading academic researchers on membrane fabrication and modification techniques and provides a comprehensive overview on the recent developments of membrane technology. Membranes can be manufactured from a range of materials including polymeric compounds, and ceramic materials, and both these materials are considered in the book. There are 5 chapters on water and wastewater membranes that cover the fabrication of thin film (TFC) composite membranes for nanofiltration(NF)/reverse osmosis (RO)/forward osmosis (FO) applications, stimuli responsive membranes, electrospun membranes, porous ceramic membranes, and polymeric ultrafiltration (UF) manufacture and modification. There are another 6 chapters on gas separation that consider carbon membranes, zeolite membranes, silica template and metal oxide silica membranes, TFC membranes, silica membranes, and metal organic framework (MOF) membranes. Zeolite membranes are also considered for organic solvent applications, as are solvent-resistant membranes manufactured by phase inversion, ceramic-supported composite membranes, and ceramic NF membranes. The emerging areas of membranes for energy and biomedical applications have 3 and 2 chapters, respectively. Energy applications consider ion exchange membranes for use in fuel cells, membranes for electrodialysis, and membranes for use in microbial fuel cells. For biomedical applications the chapters focus on hemodialysis membranes and redox responsive membranes.

Presents a rigorous development of thermodynamic laws of phase equilibria beginning with fundamental principles, accompanied by a short description of the mathematics vital to a clear understanding of basic concepts as well as the practical methods used to calculate phase equilibria. Offers excellent explanations of well-established thermodynamic tools and novel, state-of-the-art techniques representing real fluid behavior. Models covered are relevant to the modeling of nonelectrolyte mixtures over wide ranges of pressure, temperature, composition and molecular diversity.

The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field. All chapters from Topics in Heterocyclic Chemistry are published Online First with an individual DOI. In references, Topics in Heterocyclic Chemistry is abbreviated as Top Heterocycl Chem and cited as a journal

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal

Vincent Bulone et al.: Cellulose sources and new understanding of synthesis in plants Thomas Heinze et al.:Cellulose structure and properties Thomas Rosenau, Antje Potthast, Ute Henniges et al.: Recent developments in cellulose aging (degradation / yellowing / chromophore formation) Sunkyu Park et al.:Cellulose crystallinity Lina Zhang et al.:Gelation and dissolution behavior of cellulose Yoshiyuki Nishio et al.:Cellulose and derivatives in liquid crystals Alessandro Gandini, Naceur Belgacem et al.:The surface and in-depth modification of cellulose fibers Emily D. Cranston et al.:Interfacial properties of cellulose Herbert Sixta, Michael Hummel et al.Cellulose Fibers Regenerated from Cellulose Solutions in Ionic Liquids Qi Zhou et al.:Cellulose-based biocomposites Orlando Rojas et al.:Films of cellulose nanocrystals and nanofibrils Pedro Fardim et al.:Functional cellulose particles Wadood Hamad et al.:Cellulose Composites

This book offers a comprehensive introduction to polymer rheology with a focus on the viscoelastic characterization of polymeric materials. It contains various numerical algorithms for the processing of viscoelastic data, from basic principles to advanced examples which are hard to find in the existing literature. The book takes a multidisciplinary approach to the study of the viscoelasticity of polymers, and is self-contained, including the essential mathematics, continuum mechanics, polymer science and statistical mechanics needed to understand the theories of polymer viscoelasticity. It covers recent achievements in polymer rheology, such as theoretical and experimental aspects of large amplitude oscillatory shear (LAOS), and numerical methods for linear viscoelasticity, as well as new insights into the interpretation of experimental data. Although the book is balanced between the theoretical and experimental aspects of polymer rheology, the author's particular interest in the theoretical side will not remain hidden. Aimed at readers familiar with the mathematics and physics of engineering at an undergraduate level, the multidisciplinary approach employed enables researchers with various scientific backgrounds to expand their knowledge of polymer rheology in a systematic way.

In the past decades, the scan rate range of calorimeters has been extended tremendously at the high end, from approximately 10 up to 10 000 000 DegreesC/s and more. The combination of various calorimeters and the newly-developed Fast Scanning Calorimeters (FSC) now span 11 orders of magnitude, by which many processes can be mimicked according to the time scale(s) of chemical and physical transitions occurring during cooling, heating and isothermal stays in case heat is exchanged. This not only opens new areas of research on polymers, metals, pharmaceuticals and all kinds of substances with respect to glass transition, crystallization and melting phenomena, it also enables in-depth study of metastability and reorganization of samples on an 1 to 1000 ng scale. In addition, FSC will become a crucial tool for understanding and optimization of processing methods at high speeds like injection molding. The book resembles the state-of-the art in Thermal Analysis & Calorimetry and is an excellent starting point for both experts and newcomers in the field.

This book reviews the fundamental aspects of quinoxaline chemistry: synthesis, reactions, mechanisms, structure, properties, and uses. The first four chapters present a survey of the developments in quinoxaline chemistry since the publication of the monograph on "Condensed Pyrazines" by Cheeseman and Cookson in 1979. These chapters give comprehensive coverage of all the methods of the synthesis of quinoxalines and the important quinoxaline-containing ring systems such as thiazolo[3,4-a]-, pyrrolo[1,2-a]-, and imidazo[1,5-a]quinoxalines. Chapter five describes many new methods for the construction of quinoxaline macrocycles, which are important in applications such as optical devices and materials. The final chapter reviews all previously known rearrangements of heterocyclic systems that lead to benzimidazole derivatives. Mamedov critically analyses these transformations to reveal a novel acid-catalyzed rearrangement of quinoxalinones giving 2-heteroarylbenzimidazoles and 1-heteroarylbenzimidazolones in the presence of nucleophilic reactants (MAMEDOV Heterocycle Rearrangement). This book is of interest to researchers in the fields of heterocyclic and synthetic organic chemistry.

This book is a comprehensive collaboration on intelligent polymers and coatings for industrial applications by worldwide researchers and specialists. The authors cover the basis and fundamental aspects of intelligent polymers and coatings, challenges, and potential mechanisms and properties. They include recent and emerging industrial applications in medical, smart textile design, oil and gas, electronic, aerospace, and automobile industries as well as other applications including microsystems, sensors, and actuators, among others. The authors discuss the potential for future research in these areas for improvement and growth of marketable applications of intelligent polymers and coatings.

This Springer Laboratory volume is a practical guide for scientists and students dealing with the measurement of mechanical properties of polymers at the nanoscale through AFM force-distance curves. In the first part of the book the reader will find a theoretical introduction about atomic force microscopy, focused on force-distance curves, and mechanical properties of polymers. The discussion of several practical issues concerning the acquisition and the interpretation of force-distance curves will help scientists starting to employ this technique. The second part of the book deals with the practical measurement of mechanical properties of polymers by means of AFM force-distance curves. Several "hands-on" examples are illustrated in a very detailed manner, with particular attention to the sample preparation, data analysis, and typical artefacts. This section gives a complete overview about the qualitative characterization and quantitative determination of the mechanical properties of homogeneous polymer samples, polymer brushes, polymer thin films, confined polymer samples, model blends and microstructured polymer blends through AFM force-distance curves. The book also introduces to new approaches and measurement techniques, like creep compliance and force modulation measurements, pointing out approximations, limitations and issues requiring further confirmation.

This book discusses the latest developments in narrow fabrics from research institutions, machinery building companies and producers of such products, presented during the International Week of Narrow Fabrics in March 2016 in Moenchengladbach, Germany. It also demonstrates different applications of braided and woven fabrics. Braided and woven narrow products are produced using completely different techniques, but have a lot of similarities in their applications - they are used as belts, ropes and tubes in areas ranging from medical textiles, cables, technical and home applications to large-scale transport belts and long tubes for transporting oil from the bottom of the ocean.

This is a practical guidebook about cyclopropanes that thoroughly surveys derivatives and transformations, synthetic methods, and experimental efficiency as a gateway for further research and development in the field. Provides comprehensive lists and synthetically-oriented synopses of cyclopropane chemistry review references along with publication data on applications in the syntheses of natural and related biologically active compounds Acts as a resource to help readers better understand cyclopropane applications for the efficient realization of synthetically important organic transformations and popular experimental procedures Includes new developments and up-to-date information that will lead to original methodologies for complex organic synthesis Stresses universality, flexibility, and experimental efficiency of a strategy based on preparing cyclopropane derivatives and performing ring cleavage reactions with inexpensive reagents Focuses on the synthetic potential of cyclopropane applications, for example the synthesis of natural compounds and other target-oriented syntheses via cyclopropane intermediaries, as well on their planning by retrosynthetic analysis

This book describes industrial applications of polyolefins from the researchers' perspective. Polyolefins constitute today arguably the most important class of polymers and polymeric materials for widespread industrial applications. This book summarizes the present state of the art. Starting from fundamental aspects, such as the polymerization techniques to synthesize polyolefins, the book introduces the topic. Basic knowledge about polyolefin composites and blends is explained, before applications aspects in different industry sectors are discussed. The spectrum comprises a wide range of applications and industry sectors, such as the packaging and food industry, the textile industry, automotive and buildings, and even biomedical applications. Topics, which are addressed in the various chapters, comprise synthesis and processing of the materials; their classification; mechanical, physical and technical requirements and properties; their characterization; and many more. In the end of the book, even the disposal, degradation and recycling of polyolefins are addressed, and light is shed on their commercial significance and economic value. In this way, the book follows the entire 'lifetime' of polyolefin compounds and materials: from their synthesis and processing, over applications, to the recycling and reuse of disposed or degraded polyolefin substrates.