Prof. Baev presents in his book the development of the thermodynamic theory of specific intermolecular interactions for a wide spectrum of organic compounds: ethers, ketones, alcohols, carboxylic acids, and hydrocarbons. The fundamentals of an unconventional approach to the theory of H-bonding and specific interactions are formulated based on a concept of pentacoordinate carbon atoms. New types of hydrogen bonds and specific interactions are substantiated and on the basis of the developed methodology their energies are determined. The system of interconnected quantitative characteristics of the stability of specific intermolecular interactions is presented. The laws of their transformations are discussed and summarized. The new concept of the extra stabilizing effect of isomeric methyl groups on the structure and stability of organic molecules is introduced and the destabilization action on specific interactions is outlined.

This monograph is intended to provide a systematic presentation of theories concerning the adsorption of metal ions from aqueous solutions onto surfaces of natural and synthetic substances and to outline methods and procedures to estimate the extent and progress ofadsorption. As heavy metals and the problems associated with their transport and distribution are of serious concern to human health and the environment, the materials presented in this volume have both theoretical and practical significance. In writing this monograph, one ofour goals was to prepare a book useful to environmental workers and practicing engineers. For this reason, our presentation relies heavily on concepts commonly used in the environmental engineering literature. In fact, the volume was prepared for readers with a basic understanding of environmental engineering principles and some knowledge of adsorption processes. No prior familiarity with the ionic solute adsorption at solid-solution interfaces is assumed. Instead, introduction of the necessary background information was included. Generally speaking, metal ion adsorption may be studied in terms of three distinct but interrelated phenomena: surface ionization, complex formation, and the formation and presence of an electrostatic double layer adjacent to adsorbent surfaces. Analyses of these phenomena with various degrees of sophistication are xviii ADSORPTION OF METAL IONS FROM AQUEOUS SOLUTIONS presented, and their various combinations yield different models that describe metal ion adsorption.

As the availability of fossils fuels becomes more limited, the negative impact of their consumption becomes an increasingly relevant factor in our choices with regards to primary energy sources. The exponentially increasing demand for energy is reflected in the mass generation of by-products and waste flows which characterize current society's development and use of fossil sources. The potential for recoverable material and energy in these ever-increasing refuse flows is huge, even after the separation of hazardous constituent elements, allowing safe and sustainable further exploitation of an otherwise 'wasted' resource. Fuel Cells in the Waste-to-Energy Chain explores the concept of waste-to-energy through a 5 step process which reflects the stages during the transformation of refuse flows to a valuable commodity such as clean energy. By providing selected, integrated alternatives to the current centralized, wasteful, fossil-fuel based infrastructure, Fuel Cells in the Waste-to-Energy Chain explores how the concept of waste-to-energy can be constructed and developed into a realistic solution. The entire spectrum of current and future energy problems is illuminated through the explanation of the operational, integration and marketing implications of high efficiency technological solutions using the real context of developed regions such as Europe. Up-to-date reviews are provided on the status of technology and demonstration, implementation and marketing perspectives. The detailed technological information and insight gathered from over twenty years of experience in the field makes Fuel Cells in the Waste-to-Energy Chain a valuable resource for all engineers and researchers in the fields of energy supply systems and waste conversion, as well as providing a key reference for discussions by policy makers, marketing experts and industry developers working in energy supply and waste management.

This study focuses on the physical aspects of ultrasonic de-ashing and de-sulfurization, such as cavitation, streaming and their combined effects. Ambedkar Balraj proposes an ultrasound-assisted coal particle breakage mechanism and explores aqueous and solvent-based ultrasonic techniques for de-ashing and de-sulfurization. Ambedkar designs a Taguchi L-27 fractional-factorial matrix to assess the individual effects of key process variables. In this volume he also describes process optimization and scale-up strategies. The author provides a mechanism-based model for ultrasonic reagent-based coal de-sulfurization, proposes a flow diagram for ultrasonic methods of high-throughput coal-wash and discusses the benefits of ultrasonic coal-wash. Coal will continue to be a major fuel source for the foreseeable future and this study helps improve its use by minimising ash and sulfur impurities.

A systematic computer-aided approach provides a versatile setting for the control engineer to overcome the complications of controller design for highly nonlinear systems. Computer-aided Nonlinear Control System Design provides such an approach based on the use of describing functions. The text deals with a large class of nonlinear systems without restrictions on the system order, the number of inputs and/or outputs or the number, type or arrangement of nonlinear terms. The strongly software-oriented methods detailed facilitate fulfillment of tight performance requirements and help the designer to think in purely nonlinear terms, avoiding the expedient of linearization which can impose substantial and unrealistic model limitations and drive up the cost of the final product.

Design procedures are presented in a step-by-step algorithmic format each step being a functional unit with outputs that drive the other steps. This procedure may be easily implemented on a digital computer with example problems from mechatronic and aerospace design being used to demonstrate the techniques discussed. The author s commercial MATLAB(r)-based environment, available separately from insert URL here, can be used to create simulations showing the results of using the computer-aided control system design ideas characterized in the text.

Academic researchers and graduate students studying nonlinear control systems and control engineers dealing with nonlinear plant, particularly mechatronic or aerospace systems will find Computer-aided Nonlinear Control System Design to be of great practical assistance adding to their toolbox of techniques for dealing with system nonlinearities. A basic knowledge of calculus, nonlinear analysis and software engineering will enable the reader to get the best from this book."

Fluid-membrane material interfaces, morphologies of membrane surface and the sub-layer underneath the membrane surface, and fluid transport through the membrane governed by the above interface and morphology parameters, and driving forces involved in process operatio- all these three aspects together constitute the fundamental physico-chemical and engineering basis for the practical success of Membrane Separation Technology (MST) in all its applications. Quantitative data on the above interface and morphology parameters and applicable transport equations involving the above parameters, are needed for membrane design, specification of membranes, modules and systems, and prediction of their performance for any given separation application. Even though more than 40 years have elapsed since the emergence of the field of MST, there are very few books which deal with all the above three aspects of the subject in an integrated manner. This simply shows that the field of MST is still in its early stages of development and only a small fraction of its vast potential has been practically realized to-date. Still, what has already accomplished is extraordinary both in its scope, and in its impact, on scientific research and service to society at large.

Modern societies produce large amounts of waste of many different types. This presents a problem in terms of management or disposal to prevent harm to human health and the environment. Additionally it represents a loss of potentially useful resources. In the circular economy concept nothing would ever become waste because everything would be re-usable or its components recoverable. Ionic liquids provide a potential route for valorisation of different waste types, paving the way for a circular economy and a more sustainable world. Covering various types of waste, including municipal, industrial, electronic, and medical, while addressing patented and commercial applications, this book aims to deliver a comprehensive, but also critical, perspective on the application of ionic liquids towards waste valorisation. Waste Valorisation Using Ionic Liquids is a useful resource for academic and industrial players, in the fields of chemistry, chemical and environmental engineering, and biotechnology, as well as anyone working on waste management and resource recovery.

The recently published book by the author, "Engineering Heat Transfer", already dealt with exact computation of heat exchangers and tube banks. In design c- putationthisisaccomplishedviacorrectivefactors;thelattermakesitpossibleto compute the actual mean temperature difference by starting from the logarithmic onerelativeto?uidsinparallel?oworcounter?ow. As far as veri?cation computation is concerned, corrective factors were int- ducedtocomputeacertaincharacteristicfactorcorrectly,asisfundamentalforthis typeofcomputation. Basedontheabove,theauthordecidedtoinvestigatefurther,re?ne,andwiden thistopic:theoutcomeofthisworkhasresultedinthishandbook. Newtypesofexchangerswereexamined;thecalculationwasre?nedtoproduce practicallyexactvaluesforthefactors. Thescopeoftheinvestigationwasincreased by widening the range of the starting factors. Furthermore, a greater number of valuestobeincludedinthetableswasconsidered. Finally,afewcharacteristicsof certainvaluesofthecorrectivefactorswerehighlighted. The?rstsectionisanintroduction;itsummarizesthefundamentalcriteriaofheat transferandproceedstoillustratethebehaviorof?uidsinbothparallelandcounter ?ow. Italsoshowshowtocomputethemeanisobaricspeci?cheatforsome? uids; itillustratesthesigni?canceofdesigncomputationandveri?cationcomputation. In addition,itillustrateshowtoproceedwithheatexchangersandtubebankstocarry outbothdesignandveri?cationcomputationcorrectly. AppendixAthenincludes36tablesasareferencefordesigncomputation,The tablescontainthecorrectivefactorsrequiredtoobtaintheactualmeantemperature differencebystartingfromthemeanlogarithmictemperaturedifferencerelativeto ?uidsinparallel?oworcounter?ow. Finally, Appendix B includes 35 tables for veri?cation computation. As far as heatexchangers areconcerned, itshowsthevaluesoffactor ? whichisrequired forthistypeofcomputation. Thevaluesofthecorrectivefactorsforcoilsandtube banksarealsopresented. Milano,Italy DonatelloAnnaratone v Notation c=speci?cheat(J/kgK) d=diameter(m) E=ef?ciencyfactor h=enthalpy(kJ/kg) k=thermalconductivity(W/mK) M=mass?owrate(kg/s) m=massmoisturepercentage(%) q=heatpertimeunit(W) 2 S=surface(m ) ? t=temperature( C) 2 U=overallheattransfercoef?cient(W/m K) x=thickness(m) 2 ? =heattransfercoef?cient(W/m K) ? =characteristicfactor ? =characteristicfactor ? =ef?ciency ? =correctivefactor ? =correctivefactor ? =characteristicfactor ? ?t =temperaturedifference( C) vii viii Notation Superscripts =heating?uid =heated?uid Subscripts c=counter?ow e=exchanger i=inside l=logarithmic m=mean o=outside p=constantpressure(isobaric),parallel?ow w=wall 1=inlet(forheatingorheated?uid) 2=outlet(forheatingorheated?uid) Contents 1 Introduction to Computation ...1 1. 1 GeneralConsiderations ...1 1. 2 MeanIsobaricSpeci?cHeat ...3 1. 2. 1 WaterandSuperheatedSteam ...4 1. 2. 2 AirandOtherGases...4 2 Design Computation...7 2. 1 Introduction ...7 2. 2 FluidsinParallelFloworinCounterFlow ...8 2. 3 TheMeanDifferenceinTemperatureinReality ...12 2. 3. 1 FluidsinCrossFlow...14 2. 3. 2 HeatExchangers...15 2. 3. 3 Coils...19 2. 3. 4 TubeBankswithVariousPassagesoftheExternalFluid . 21 3 Veri?cation Computation ...25 3. 1 Introduction ...25 3. 2 FluidsinParallelFloworinCounterFlow ...25 3. 3 Factor?inRealCases...33 3. 3. 1 FluidswithCrossFlow ...

Industrial Process Identification and Control Design is devoted to advanced identification and control methods for the operation of continuous-time processes both with and without time delay, in industrial and chemical engineering practice. The simple and practical step- or relay-feedback test is employed when applying the proposed identification techniques, which are classified in terms of common industrial process type: open-loop stable; integrating; and unstable, respectively. Correspondingly, control system design and tuning models that follow are presented for single-input-single-output processes. Furthermore, new two-degree-of-freedom control strategies and cascade control system design methods are explored with reference to independently-improving, set-point tracking and load disturbance rejection. Decoupling, multi-loop, and decentralized control techniques for the operation of multiple-input-multiple-output processes are also detailed. Perfect tracking of a desire output trajectory is realized using iterative learning control in uncertain industrial batch processes. All the proposed methods are presented in an easy-to-follow style, illustrated by examples and practical applications. This book will be valuable for researchers in system identification and control theory, and will also be of interest to graduate control students from process, chemical, and electrical engineering backgrounds and to practising control engineers in the process industry.

Careful selection of the right lubricant(s) is required to keep a machine running smoothly. Lubrication Fundamentals, Third Edition, Revised and Expanded describes the need and design for the many specialized oils and greases used to lubricate machine elements and builds on the tribology and lubrication basics discussed in previous editions. Utilizing knowledge from leading experts in the field, the third edition covers new lubrication requirements, crude oil composition and selection, base stock manufacture, lubricant formulation and evaluation, machinery and lubrication fundamentals, and environmental stewardship. The book combines lubrication theory with practical knowledge, and provides many useful illustrations to highlight key industrial, commercial, marine, aviation, and automotive lubricant applications and concepts. All previous edition chapters have been updated to include new technologies, applications, and specifications that have been introduced in the past 15 years. What's New in the Third Edition: Adds three new chapters on the growing renewable energy application of wind turbines, the impact of lubricants on energy efficiency, and best practice guidelines on establishing an in-service lubricant analysis program Updates API, SAE, and ACEA engine oil specifications, descriptions of new engine oil tests, impact of engine and fuel technology trends on engine oil Includes the latest environmental lubricant tests, definitions, and labelling programs Compiles expert information from ExxonMobil publications and the foremost international equipment builders and industry associations Covers key influences impacting lubricant formulations and technology Offers data on global energy demand and interesting statistics such as the worldwide population of nuclear reactors, wind turbines, and output of hydraulic turbines Presents new sections on the history of synthetic lubricants and hazardous chemical labeling for lubricants Whether used as a training guide for industry novices, a textbook for students to understand lubrication principles, or a technical reference for experienced lubrication and tribology professionals, Lubrication Fundamentals, Third Edition, Revised and Expanded is a "must read" for maintenance professionals, lubricant formulators and marketers, chemists, and lubrication, surface, chemical, mechanical, and automotive engineers.

This book represents a first considered attempt to study the factors that conditioned industrial chemistry for war in 1914-18. Taking a comparative perspective, it reflects on the experience of France, Germany, Austria, Russia, Britain, Italy and Russia, and points to significant similarities and differences. It looks at changing patterns in the organisation of industry, and at the emerging symbiosis between science, industry and the military.

Industrial Inorganic Chemistry adds to the previously published graduate level textbooks on Industrial Chemistry by Mark A. Benvenuto. It focuses specifically on inorganic processes, from the largest industrial process for the production of major inorganic chemicals and metals, down to and including smaller niche processes that have become extremely important in maintaining the current quality of life. The book provides a survey on the production of essential elements and compounds, such as sulfuric acid, calcium carbonate, fertilizers as well as numerous metals and alloys. In addition to the fundamental scientific principles each chapter includes discussions on the environmental impacts: mining of raw materials, creation of by-products, pollution, and waste generation, all of which have become key factors for the potential implementation of greener methods. The author also highlights ways in which industry has begun to make industrial inorganic processes more environmentally benign. Examines major inorganic chemistry processes, their effect on every-day life and current efforts to improve processes or adapt "green" chemical production. Provides didactic links between theoretical lecture contents and current, largescale chemical processes. Valuable for students of Inorganic Chemistry, Industrial Chemistry, Chemical Engineering and Materials Sciences.

Successful industrial heterogeneous catalysts fulfill several key require ments: in addition to high catalytic activity for the desired reaction, with high selectivity where appropriate, they also have an acceptable commercial life and are rugged enough for transportation and charging into plant reactors. Additional requirements include the need to come online smoothly in a short time and reproducible manufacturing procedures that involve convenient processes at acceptable cost. The development of heterogeneous catalysts that meet these (often mutually exclusive) demands is far from straightforward, and in addition much of the actual manufacturing tech nology is kept secret for commercial reasons-thus there is no modern text that deals with the whole of this important subject. Principles of Catalyst Development, which deals comprehensively with the design, development, and manufacture of practical heterogeneous catalysts, is therefore especially valuable in meeting the long-standing needs of both industrialists and academics. As one who has worked extensively on a variety of catalyst development problems in both industry and academia, James T. Richardson is well placed to write an authoritative book covering both the theory and the practice of catalyst development. Much of the material contained in this book had its origin in a series of widely acclaimed lectures, attended mainly by industrial researchers, given over many years in the United States and Europe. All those in industry who work with catalysts, both beginners and those of considerable experience, should find this volume an essential guide."

By drawing together the current theoretical and experimental understanding of the phenomena of delayed hydride cracking (DHC) in zirconium alloys, The Effect of Hydrogen and Hydrides on the Integrity of Zirconium Alloy Components: Delayed Hydride Cracking provides a detailed explanation focusing on the properties of hydrogen and hydrides in these alloys. Whilst the emphasis lies on zirconium alloys, the combination of both the empirical and mechanistic approaches creates a solid understanding that can also be applied to other hydride forming metals. This up-to-date reference focuses on documented research surrounding DHC, including current methodologies for design and assessment of the results of periodic in-service inspections of pressure tubes in nuclear reactors. Emphasis is placed on showing how our understanding of DHC is supported by progress in general understanding of such broad fields as the study of hysteresis associated with first order phase transformations, phase relationships in coherent crystalline metallic solids, the physics of point and line defects, diffusion of substitutional and interstitial atoms in crystalline solids, and continuum fracture and solid mechanics. Furthermore, an account of current methodologies is given illustrating how such understanding of hydrogen, hydrides and DHC in zirconium alloys underpins these methodologies for assessments of real life cases in the Canadian nuclear industry. The all-encompassing approach makes The Effect of Hydrogen and Hydrides on the Integrity of Zirconium Alloy Component: Delayed Hydride Cracking an ideal reference source for students, researchers and industry professionals alike.

Polysiloxanes are the most studied inorganic and semi-inorganic polymers because of their many medical and commercial uses. The Si-O backbone endows polysiloxanes with intriguing properties: the strength of the Si-O bond imparts considerable thermal stability, and the nature of the bonding imparts low surface free energy. Prostheses, artificial organs, objects for facial reconstruction, vitreous substitutes in the eyes, and tubing take advantage of the stability and pliability of polysiloxanes. Artificial skin, contact lenses, and drug delivery systems utilize their high permeability. Such biomedical applications have led to biocompatability studies on the interactions of polysiloxanes with proteins, and there has been interest in modifying these materials to improve their suitability for general biomedical application. Polysiloxanes examines novel aspects of polysiloxane science and engineering, including properties, work in progress, and important unsolved problems. The volume, with ten comprehensive chapters, examines the history, preparatin and analysis, synthesis, characterization, and applications of these polymeric materials.

Methods of nuclear magnetic resonance (NMR) are increasingly applied in engineering sciences. The book summarizes research in the field of chemical and process engineering performed at the Karlsruhe Institute of Technology (KIT). Fundamentals of the methods are exposed for readers with an engineering background. Applications cover the fields of mechanical process engineering (filtration, solid-liquid separation, powder mixing, rheometry), chemical process engineering (trickle-bed reactor, ceramic sponges), bioprocess engineering (biofilm growth), and food process engineering (microwave heating, emulsions). Magnetic Resonance Imaging (MRI) as well as low-field NMR are covered with notes on hardware. Emphasis is placed on quantitative data analysis and image processing.

This book presents a design-driven investigation into smart materials developed by chemists, physicists, materials and chemical engineers, and applied by designers to consumer products. Introducing a class of smart materials, that change colors, the book presents their characteristics, advantages, potentialities and difficulties of applications of this to help understanding what they are, how they work, how they are applied. The books also present a number of case studies: products, projects, concepts and experiments using smart materials, thus mapping out new design territories for these innovative materials. These case studies involve different fields of design, including product, interior, fashion and communication design. Within the context of rising sustainable and human-centered design agendas, the series will demonstrate the role and influence of these new materials and technologies on design, and discuss how they can implement and redefine our objects and spaces to encourage more resilient environments.

This book is about two special topics in rheological fluid mechanics: the elasticity of liquids and asymptotic theories of constitutive models. The major emphasis of the book is on the mathematical and physical consequences of the elasticity of liquids; seventeen of twenty chapters are devoted to this. Constitutive models which are instantaneously elastic can lead to some hyperbolicity in the dynamics of flow, waves of vorticity into rest (known as shear waves), to shock waves of vorticity or velocity, to steady flows of transonic type or to short wave instabilities which lead to ill-posed problems. Other kinds of models, with small Newtonian viscosities, give rise to perturbed instantaneous elasticity, associated with smoothing of discontinuities as in gas dynamics. There is no doubt that liquids will respond like elastic solids to impulses which are very rapid compared to the time it takes for the molecular order associated with short range forces in the liquid, to relax. After this, all liquids look viscous with signals propagating by diffusion rather than by waves. For small molecules this time of relaxation is estimated as lQ-13 to 10-10 seconds depending on the fluids. Waves associated with such liquids move with speeds of 1 QS cm/s, or even faster. For engineering applications the instantaneous elasticity of these fluids is of little interest; the practical dynamics is governed by diffusion, .say, by the Navier-Stokes equations. On the other hand, there are other liquids which are known to have much longer times of relaxation."

Flow Control Methods and Devices in Micrometer Scale Channels, by Shuichi Shoji and Kentaro Kawai. Micromixing Within Microfluidic Devices, by Lorenzo Capretto, Wei Cheng, Martyn Hill and Xunli Zhang. Basic Technologies for Droplet Microfluidics, by Shaojiang Zeng, Xin Liu, Hua Xie and Bingcheng Lin. Electrorheological Fluid and Its Applications in Microfluidics, by Limu Wang, Xiuqing Gong and Weijia Wen. Biosensors in Microfluidic Chips, by Jongmin Noh, Hee Chan Kim and Taek Dong Chung. A Nanomembrane-Based Nucleic Acid Sensing Platform for Portable Diagnostics, by Satyajyoti Senapati, Sagnik Basuray, Zdenek Slouka, Li-Jing Cheng and Hsueh-Chia Chang. Optical Detection Systems on Microfluidic Chips, by Hongwei Gai, Yongjun Li and Edward S. Yeung. Integrated Microfluidic Systems for DNA Analysis, by Samuel K. Njoroge, Hui-Wen Chen, Ma gorzata A. Witek and Steven A. Soper. Integrated Multifunctional Microfluidics for Automated Proteome Analyses, by John K. Osiri, Hamed Shadpour, Ma gorzata A. Witek and Steven A. Soper. Cells in Microfluidics, by Chi Zhang and Danny van Noort. Microfluidic Platform for the Study of Caenorhabditis elegans, by Weiwei Shi, Hui Wen, Bingcheng Lin and Jianhua Qin."

This volume includes 20 contributions of the 12th meeting on Analytical Ultracentrifugation from March 1-2, 2001 in Duisburg, Germany. Various fields of ultracentrifugation are covered concerning research problems in biochemistry, biophysical chemistry and macromolecular chemistry as well as interacting systems. New investigations concerning the sedimentation theory are presented. The phase transition of gels is dealt with, as is the sedimentation-diffusion equilibrium of gels. One section contains the hydrodynamics of biopolymers.

Today, ergot alkaloids have found widespread clinical use and more than 50 formulations contain natural or semisynthetic ergot alkaloids. They are used in the treatment of uterine atonia, postpartum bleeding, migraine, orthostatic circulatory disturbances, senile cerebral insufficiency, hypertension, hyp- prolactinemia, acromegaly, and Parkinsonism. Recently, new therapeutic - plications have emerged, e.g., against schizophrenia and for therapeutic usage based on newly discovered antibacterial and cytostatic effects, immunomodu- tory and hypolipemic activity.The broad physiological effects of ergot alkaloids are based mostly on their interactions with neurotransmitter receptors on the cells. The presence of "hidden structures'' resembling some important neu- humoral mediators (e.g., noradrenaline, serotonin, dopamine) in the molecules of ergot alkaloids could explain their interactions with these receptors 1]. Ergot alkaloids are produced by the filamentous fungi of the genus, Claviceps (e.g., Claviceps purpurea - Ergot, Mutterkorn). On the industrial scale these alkaloids were produced mostly by parasitic cultivation (field production of the ergot) till the end of the 1970s. Today this uneconomic method has been - placed by submerged fermentation. Even after a century of research on ergot alkaloids the search still continues for new, more potent and more selective ergot alkaloid derivatives.