Elucidating Organic Reaction Mechanisms using photo-CIDNP Spectroscopy, by Martin Goez. Parahydrogen Induced Polarization by Homogeneous Catalysis: Theory and Applications, by Kerstin Münnemann et al. Improving NMR and MRI Sensitivity with Parahydrogen, by R. Mewis & Simon Duckett. The Solid-state Photo-CIDNP Effect, by Jörg Matysik et al. Parahydrogen-induced Polarization in Heterogeneous Catalytic Processes, by Igor Koptyug et al. Dynamic Nuclear Polarization Enhanced NMR Spectroscopy, by U. Akbey & H. Oschkinat. Photo-CIDNP NMR Spectroscopy of Amino Acids and Proteins, by Lars T. Kuhn.

This book is written for scientists involved in the calibration of viscometers. A detailed description for stepping up procedures to establish the viscosity scale and obtaining sets of master viscometers is given in the book. Uncertainty considerations for standard oils of known viscosity are presented. The modern viscometers based on principles of tuning fork, ultrasonic, PZT, plate waves, Love waves, micro-cantilever and vibration of optical fiber are discussed to inspire the reader to further research and to generate improved versions. The primary standard for viscosity is pure water. Measurements of its viscosity with accuracy/uncertainty achieved are described. The principles of rotational and oscillation viscometers are explained to enhance the knowledge in calibration work. Devices used for specific materials and viscosity in non SI units are discussed with respect to the need to correlate viscosity values obtained by various devices. The description of commercial viscometers meets the needs of the user.

An instructive reference that will help control researchers and engineers, interested in a variety of industrial processes, to take advantage of a powerful tuning method for the ever-popular PID control paradigm. This monograph presents explicit PID tuning rules for linear control loops regardless of process complexity. It shows the reader how such loops achieve zero steady-position, velocity, and acceleration errors and are thus able to track fast reference signals. The theoretical development takes place in the frequency domain by introducing a general-transfer-function-known process model and by exploiting the principle of the magnitude optimum criterion. It is paralleled by the presentation of real industrial control loops used in electric motor drives. The application of the proposed tuning rules to a large class of processes shows that irrespective of the complexity of the controlled process the shape of the step and frequency response of the control loop exhibits a specific performance. This specific performance, along with the PID explicit solution, formulates the basis for developing an automatic tuning method for the PID controller parameters which is a problem often met in many industry applications-temperature, pH, and humidity control, ratio control in product blending, and boiler-drum level control, for example. The process of the model is considered unknown and controller parameters are tuned automatically such that the aforementioned performance is achieved. The potential both for the explicit tuning rules and the automatic tuning method is demonstrated using several examples for benchmark process models recurring frequently in many industry applications.

Alistair Lennox's thesis reports on the reactivity of organotrifluoroborates, which are becoming increasingly important reagents in synthesis. The thesis is divided into three sections. The first section describes a method for preparing organotrifluoroborates. The second section reports on a mechanistic investigation into the main application of RBF3K reagents as coupling partners in Suzuki-Miyaura coupling, phenomena identified as arising from organotrifluoroborate hydrolysis and fluoride release. The final section reports on a detailed investigation into the hydrolysis mechanism, a prerequisite for their Suzuki-Miyaura coupling, and how it may be predicted and controlled. This research has uncovered many interesting and useful details and shows how problems associated with Suzuki-Miyaura coupling can best be addressed. There has already been wide industrial uptake of the new procedures and insights. The broad nature and clear and succinct style will make the thesis a valuable resource for anyone working in synthesis, organometallic chemistry, or in homogeneous catalysis.

Transformation and Utilization of Carbon Dioxide shows the various organic, polymeric and inorganic compounds which result from the transformation of carbon dioxide through chemical, photocatalytic, electrochemical, inorganic and biological processes. The book consists of twelve chapters demonstrating interesting examples of these reactions, depending on the types of reaction and catalyst. It also includes two chapters dealing with the utilization of carbon dioxide as a reaction promoter and presents a wide range of examples of chemistry and chemical engineering with carbon dioxide. Transformation and Utilization of Carbon Dioxide is a collective work of reviews illustrative of recent advances in the transformation and utilization of carbon dioxide. This book is interesting and useful to a wide readership in the various fields of chemical science and engineering. Bhalchandra Bhanage is a professor of industrial and engineering chemistry at Institute of Chemical Technology, India. Masahiko Arai is a professor of chemical engineering at Hokkaido University, Japan.

The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field.

The two volumes of Handbook of Gas Sensor Materials provide a detailed and comprehensive account of materials for gas sensors, including the properties and relative advantages of various materials. Since these sensors can be applied for the automation of myriad industrial processes, as well as for everyday monitoring of such activities as public safety, engine performance, medical therapeutics, and in many other situations, this handbook is of great value. Gas sensor designers will find a treasure trove of material in these two books.

Providing a critical and extensive compilation of the downstream processes of natural gas that involve the principle of gas processing , transmission and distribution, gas flow and network analysis, instrumentation and measurement systems and its utilisation, this book also serves to enrich readers understanding of the business and management aspects of natural gas and highlights some of the recent research and innovations in the field. Featuring extensive coverage of the design and pipeline failures and safety challenges in terms of fire and explosions relating to the downstream of natural gas technology, the book covers the needs of practising engineers from different disciplines, who may include project and operations managers, planning and design engineers as well as undergraduate and postgraduate students in the field of gas, petroleum and chemical engineering. This book also includes several case studies to illustrate the analysis of the downstream process in the gas and oil industry. Of interest to researchers is the field of flame and mitigation of explosion: the fundamental processes involved are also discussed, including outlines of contemporary and possible future research and challenges in the different fields.

The use of isoconversional kinetic methods for analysis of thermogravimetric and calorimetric data on thermally stimulated processes is quickly growing in popularity. The purpose of this book is to create the first comprehensive resource on the theory and applications of isoconversional methodology. The book introduces the reader to the kinetics of physical and chemical condensed phase processes that occur as a result of changing temperature and discusses how isoconversional analysis can provide important kinetic insights into them. The book will help the readers to develop a better understanding of the methodology, and promote its efficient usage and successful development.

Biomimetics is an innovative paradigm shift based on biodiversity for sustainability. Biodiversity is not only the result of evolutionary adaption but also the optimized solution of an epic combinatorial chemistry for sustainability, because the diversity has been acquired by biological processes and technology, including production processes, operating principles, and control systems, all of which differ from human technology. In the recent decades, biomimetics has gained a great deal of industrial interest because of its unique solutions for engineering problems. In this book, researchers have contributed cutting-edge results from the viewpoint of two types of industrial applications of biomimetics. The first type starts with engineering tasks to solve an engineering problem using biomimetics, while the other starts with the knowledge of biology and its application to engineering fields. This book discusses both approaches. Edited by Profs. Masatsugu Shimomura and Akihiro Miyauchi, two prominent nanotechnology researchers, this book will appeal to advanced undergraduate- and graduate-level students of biology, chemistry, physics, and engineering and to researchers working in the areas of mechanics, optical devices, glue materials, sensor devices, and SEM observation of living matter.

Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

This book focuses on the triboemission of low-energy electrons from the freshly generated surface. These electrons play the most crucial role in the chemical reactions at the tribological interface. New models and TIP (thermodymanics of irreversible processes) describe in detail the behavior of emitted electrons which lower the activation energy of the chemical reactions. This book also highlights tribocatalysis phenomena as examples of the lowering of the activation energy. A book titled Tribocatalysis has never been published before this.

The Role of Metals and Ligands in Organic Hydroformylation, by Luca Gonsalvi, Antonella Guerriero, Eric Monflier, Frédéric Hapiot, Maurizio Peruzzini. Hydroformylation in Aqueous Biphasic Media Assisted by Molecular Receptors, by Frédéric Hapiot, Hervé Bricout, Sébastien Tilloy, Eric Monflier. Asymmetric Hydroformylation, by Bernabé F. Perandones, Cyril Godard, Carmen Claver. Domino Reactions Triggered by Hydroformylation, by Elena Petricci, Elena Cini. Rhodium-Catalyzed Hydroformylation in Fused Azapolycycles Synthesis, by Roberta Settambolo. Hydroformylation in Natural Product Synthesis, by Roderick W. Bates, Sivarajan Kasinathan.

This Brief describes the influence of the different organic chelating agents on the topography, physical properties and phases of SPPS-deposited spinel ferrite splats. The author describes how by using the SPPS process, the coating is produced directly from a solution precursor and how all physical and chemical reactions such as evaporation, decomposition, crystallization and coating formation occur in a single step. The author details not only the innovative approach to liquid feeding, but also focuses on its effects on the spinel ferrite system. The results of experimentation as well as detailed explanations of the experiments are included.

Alexey Ivanov investigates the application of a silicon anodization process as a three-dimensional structuring technique, where silicon is transformed into porous silicon as a sacrificial layer or directly dissolved in electropolishing regime. The work contains a detailed state of the art, experimental studies and modeling of the process for basic shape controlling techniques. Limitations of the developed FEM model with secondary current distribution are discussed.

Over the past twenty years, Catalysis by Heteropolyacids (HPAs) has received wide attention and led to new and promising developments both at academic and industrial level. In particular, heterogeneous catalysis is particularly attractive because it generally satisfies most of green chemistry's requirements. By emphasizing the development of third generation catalysts, this volume presents trends and opportunities in academic and industrial research. The book appeals to postgraduates, researchers, and chemists working in the field of environmentally benign catalysts as well as catalytic processes.

The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field.

Metaheuristics exhibit desirable properties like simplicity, easy parallelizability and ready applicability to different types of optimization problems such as real parameter optimization, combinatorial optimization and mixed integer optimization. They are thus beginning to play a key role in different industrially important process engineering applications, among them the synthesis of heat and mass exchange equipment, synthesis of distillation columns and static and dynamic optimization of chemical and bioreactors. This book explains cutting-edge research techniques in related computational intelligence domains and their applications in real-world process engineering. It will be of interest to industrial practitioners and research academics.

This book presents a new electric arc furnace process and discusses potential for developing a steelmaking aggregate of the new generation, namely the Fuel Arc Furnace based on existing shaft furnaces. It also reviews the history of developing various types of furnaces with the scrap preheating and flat bath advantages of these furnaces, identifying their disadvantages and presenting methods of eliminating them.

Industrial Organic Chemistry examines all major industrial manufacturing technologies and reaction types with a focus on organic chemistry in general and petroleum refining in particular. The author takes a systematic approach to introducing the most important classes of organic compounds, from the C1 fraction through to polyaromatics and polymers. The author introduces biological sources for key compounds such as fuel and plastics and compares these bio-based organic materials to the corresponding petroleum-based chemicals. In addition to the chemistry behind processes in the petroleum, pharma, food and agrochemical industries, this book also discusses related topics such as process selectivity, waste management, and product purification.

This book highlights major achievements made in the last five years concerning sustainable C(sp3)-H bond functionalization and offers a promising and emerging tool-kit for organic synthesis. The book is divided into three chapters demonstrating key advances in C(sp3)-H bond functionalization. Chapter 1 reviews transition-metal-catalyzed C(sp3)-H bond functionalization using different directing groups, while Chapter 2 addresses the new methods of transition-metal-catalyzed and metal-free C(sp3)-H bond functionalization without directing groups, in addition to briefly highlighting redox-neutral C(sp3)-H bond functionalization. In closing, Chapter 3 examines visible-light photoredox catalysis, an emerging and highly sustainable C(sp3)-H bond functionalization strategy. The book offers an intriguing and useful reference guide for a broad readership working and/or interested in the fields of organic, organometallic, and green chemistry.

Technical gases are used in almost every field of industry, science and medicine and also as a means of control by government authorities and institutions and are regarded as indispensable means of assistance. In this complete handbook of purified gases the physical foundations of purified gases and mixtures as well as their manufacturing, purification, analysis, storage, handling and transport are presented in a comprehensive way. This important reference work is accompanied with a large number of Data Sheets dedicated to the most important purified gases.

This volume describes the most recent findings on the structure of ILs interpreted through cutting-edge experimental and theoretical methods. Research in the field of ionic liquids (ILs) keeps a fast and steady pace. Since these new-generation molten salts first appeared in the chemistry and physics landscape, a large number of new compounds has been synthesized. Most of them display unexpected behaviour and possess stunning properties. The coverage in this book ranges from the mesoscopic structure of ILs to their interaction with proteins. The reader will learn how diffraction techniques (small and large angle X-Ray and neutron scattering, powder methods), X-Ray absorption spectroscopies (EXAFS/XANES), optical methods (IR, RAMAN), NMR and calorimetric methods can help the study of ILs, both as neat liquids and in mixtures with other compounds. It will enable the reader to choose the best method to suit their experimental needs. A detailed survey of theoretical methods, both quantum-chemical and classical, and of their predictive power will accompany the exposition of experimental ones. This book is a must read for postgraduate students, for post-docs, and for researchers who are interested in understanding the structural properties of ILs.

This book covers the fundamental requirements for air, soil and water pollution control in oil and gas refineries, chemical plants, oil terminals, petrochemical plants, and related facilities. In this concise volume, Dr. Bahadori elucidates design and operational considerations relevant to critical systems such as the waste water treatment units, solid waste disposal, and waste water sewer treatment  as well as engineering/technological methods related to soil and air pollutions control. Engineers and technical managers in a range of industries will benefit from detail on a diverse list of topics.

This monograph presents design methodologies for (robust) fractional control systems. It shows the reader how to take advantage of the superior flexibility of fractional control systems compared with integer-order systems in achieving more challenging control requirements. There is a high degree of current interest in fractional systems and fractional control arising from both academia and industry and readers from both milieux are catered to in the text. Different design approaches having in common a trade-off between robustness and performance of the control system are considered explicitly. The text generalizes methodologies, techniques and theoretical results that have been successfully applied in classical (integer) control to the fractional case. The first part of Advances in Robust Fractional Control is the more industrially oriented. It focuses on the design of fractional controllers for integer processes. In particular, it considers fractional-order proportional-integral-derivative controllers, because integer-order PID regulators are, undoubtedly, the controllers most frequently adopted in industry. The second part of the book deals with a more general approach to fractional control systems, extending techniques (such as H-infinity optimal control and optimal input-output inversion based control) originally devised for classical integer-order control. Advances in Robust Fractional Control will be a useful reference for the large number of academic researchers in fractional control, for their industrial counterparts and for graduate students who want to learn more about this subject.