This book presents a short introduction to the historical background to the field, the state of the art and a brief survey of the available instrumentation and the processing techniques used. The following major areas of interest in synthetic, organic and medicinal chemistry are elaborated on: transition-metal catalyzed reactions, organocatalytic transformations, heterocyclic synthesis, and photochemical reactions. Finally, selected applications in industry are also discussed. With its ample presentation of examples from recent literature, this is an essential and reliable source of information for both experienced researchers and postgraduate newcomers to the field.

This book is a comprehensive collaboration on intelligent polymers and coatings for industrial applications by worldwide researchers and specialists. The authors cover the basis and fundamental aspects of intelligent polymers and coatings, challenges, and potential mechanisms and properties. They include recent and emerging industrial applications in medical, smart textile design, oil and gas, electronic, aerospace, and automobile industries as well as other applications including microsystems, sensors, and actuators, among others. The authors discuss the potential for future research in these areas for improvement and growth of marketable applications of intelligent polymers and coatings.

This thesis presents a combination of material synthesis and characterization with process modeling. In it, the CO2 adsorption properties of hydrotalcites are enhanced through the production of novel supported hybrids (carbon nanotubes and graphene oxide) and the promotion with alkali metals. Hydrogen is regarded as a sustainable energy carrier, since the end users produce no carbon emissions. However, given that most of the hydrogen produced worldwide comes from fossil fuels, its potential as a carbon-free alternative depends on the ability to capture the carbon dioxide released during manufacture. Sorption-enhanced hydrogen production, in which CO2 is removed as it is formed, can make a major contribution to achieving this. The challenge is to find solid adsorbents with sufficient CO2 capacity that can work in the right temperature window over repeated adsorption-desorption cycles. The book presents a highly detailed characterization of the materials, together with an accurate measurement of their adsorption properties under dry conditions and in the presence of steam. It demonstrates that even small quantities of graphene oxide provide superior thermal stability to hydrotalcites due to their compatible layered structure, making them well suited as volume-efficient adsorbents for CO2. Lastly, it identifies suitable catalysts for the overall sorption-enhanced water gas shift process.

In the past decades, the scan rate range of calorimeters has been extended tremendously at the high end, from approximately 10 up to 10 000 000 DegreesC/s and more. The combination of various calorimeters and the newly-developed Fast Scanning Calorimeters (FSC) now span 11 orders of magnitude, by which many processes can be mimicked according to the time scale(s) of chemical and physical transitions occurring during cooling, heating and isothermal stays in case heat is exchanged. This not only opens new areas of research on polymers, metals, pharmaceuticals and all kinds of substances with respect to glass transition, crystallization and melting phenomena, it also enables in-depth study of metastability and reorganization of samples on an 1 to 1000 ng scale. In addition, FSC will become a crucial tool for understanding and optimization of processing methods at high speeds like injection molding. The book resembles the state-of-the art in Thermal Analysis & Calorimetry and is an excellent starting point for both experts and newcomers in the field.

This book reviews the fundamental aspects of quinoxaline chemistry: synthesis, reactions, mechanisms, structure, properties, and uses. The first four chapters present a survey of the developments in quinoxaline chemistry since the publication of the monograph on "Condensed Pyrazines" by Cheeseman and Cookson in 1979. These chapters give comprehensive coverage of all the methods of the synthesis of quinoxalines and the important quinoxaline-containing ring systems such as thiazolo[3,4-a]-, pyrrolo[1,2-a]-, and imidazo[1,5-a]quinoxalines. Chapter five describes many new methods for the construction of quinoxaline macrocycles, which are important in applications such as optical devices and materials. The final chapter reviews all previously known rearrangements of heterocyclic systems that lead to benzimidazole derivatives. Mamedov critically analyses these transformations to reveal a novel acid-catalyzed rearrangement of quinoxalinones giving 2-heteroarylbenzimidazoles and 1-heteroarylbenzimidazolones in the presence of nucleophilic reactants (MAMEDOV Heterocycle Rearrangement). This book is of interest to researchers in the fields of heterocyclic and synthetic organic chemistry.

The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field.

This book focuses on the fundamental principles and recent progress in the field of electrical and thermal properties of polymer nanocomposites. The physical and chemical natures determining the electrical and thermal properties of polymer nanocomposites are discussed in detail. The authors describe the range of traditional and emerging polymer nanocomposites from nanoparticle and polymer composites to novel nanostructure based polymer nanocomposites. They include novel properties and potential applications, such as high-k, low-k, high thermal conductivity, antistatic, high voltage insulation, electric stress control, and thermal energy conversion among others.

This book provides comprehensive, state-of-the art coverage of photorefractive organic compounds, a class of material with the ability to change their index of refraction upon illumination. The change is both dynamic and reversible. Dynamic because no external processing is required for the index modulation to be revealed, and reversible because the index change can be modified or suppressed by altering the illumination pattern. These properties make photorefractive materials very attractive candidates for many applications such as image restoration, correlation, beam conjugation, non-destructive testing, data storage, imaging through scattering media, holographic imaging and display. The field of photorefractive organic material is also closely related to organic photovoltaic and light emitting diode (OLED), which makes new discoveries in one field applicable to others.

This second edition is a short and comprehensive study on the best known approaches for preparing the main types of glycosides. It covers synthetic pathways of challenging glycosides known as antiviral or antineoplastic drugs, and synthetic substrates used for enzymatic detection, including those used for detection of gene markers in plant biotechnology. The author pays special attention to the structural characterization of glycosides and provides the basic tools for the structural assignment through NMR, X-Ray and mass spectra techniques. The book also covers strategies for preparation of antiviral and antineoplastic drugs included in a drug design course.

This volume presents essential information on chemical reagents commonly used in flotation processes. It comprehensively summarizes the properties, preparation and applications of collectors, frothers, depressants and flocculants. It also discusses the microanalysis of flotation reagents and adsorption measurement. The book offers a valuable resource for all university researchers and students, as wells as R&D engineers in minerals processing and extractive metallurgy who wish to explore innovative reagents and technologies that lead to more energy efficient and environmentally sustainable solutions.

This book reviews and characterises promising single-compound solvents, solvent blends and advanced solvent systems suitable for CO2 capture applications using gas-liquid absorption. Focusing on energy efficient solvents with minimal adverse environmental impact, the contributions included analyse the major technological advantages, as well as research and development challenges of promising solvents and solvent systems in various sustainable CO2 capture applications. It provides a valuable source of information for undergraduate and postgraduate students, as well as for chemical engineers and energy specialists.

A unique feature of this book is its focus on nanotechnological solutions for the production of bioenergy and biofuels. Coverage includes topics such as nanobiotechnology, microalgae, biofuel cells, biomass pretreatment, and biomass conversion. An international team of experts also addresses the need to precisely characterize nanoparticles and the role of catalysts. The range of topics addressed, together with a chapter on risk management, make this book a highly useful resource for a broad readership including physicists, chemists, microbiologists, biotechnologists, food technologists, agricultural engineers, and nanotechnologists.

This book presents selected high-quality research papers submitted to ICNF 2017, the 3rd International Conference on Natural Fibers, which was held in Braga, Portugal, on 21-23 June 2017. It discusses the latest research and developments in the field and covers a wide range of topics related to various aspects of natural-fiber composites, such as production and processing of raw materials, surface modification and functionalization, advanced fibrous structures for composites, nano fibers, experimental characterization, modeling and analysis, design and product development, applications, market potential, and environmental impacts. The book presents the latest research work addressing different approaches and techniques to improve processing, performance, functionalities and cost-effectiveness of natural-fibers composites, in order to increase their applications in different industrial sectors such as automobiles, transportation, construction, and sport. & nbsp;

This book analyzes hydrocarbon generation and accumulation within space-limited source rocks. The authors draw conclusions based on the principles of basin formation, hydrocarbon generation and accumulation, coupled with the practice of terrigenous basins in eastern China. Hydrocarbon generation and expulsion have been quantitatively assessed in space-limited source rock systems. This book explores new hydrocarbon generation and expulsion models to reflect real geological situations more accurately. The theory and practice proposed in this book challenge the traditional theory of kerogen thermal degradation and hydrocarbon generation.

This book is a state of the art treatise on what has been done so far on measuring sustainability for decision making. Contributions will appeal to engineers and scientists engaged in technology development, assessment, and verification. Researchers working on engineering sustainability are likely to get ideas for further research in quantifying sustainability for industrial systems. Concepts described can be applied across all scales, from process technology to global sustainability; and challenges and limitations are also addressed. Readers will discover important insights about simulation-based approaches to process design and quantitative measurement techniques of sustainability for business and technology systems. Most of the examples and case studies are from chemical enterprises but the methodologies presented could be applicable to any system for which quantitative data for indicators are available, and the choice of the set of indicators of sustainability are comprehensive.

Written by Laurence Britton, who has over 20 years' experience in the fields of static ignition and process fire and explosion hazards research, this resource addresses an area not extensively covered in process safety standards or literature: understanding and reducing potential hazards associated with static electricity. The book covers the nature of static electricity, characteristics and effective energies of different static resources, techniques for evaluating static electricity hazards, general bonding, grounding, and other techniques used to control static or prevent ignition, gases and liquids, powders and hybrid mixtures.

This monograph deals with the interrelationship between chemistry and physics, and especially the role played by quantum chemistry as a theory in between these two disciplines. The author uses structuralist approach to explore the overlap between the two sciences, looking at their theoretical and ontological borrowings as well as their continuity. The starting point of this book is that there is at least a form of unity between chemistry and physics, where the reduction relation is conceived as a special case of this unity. However, matters are never concluded so simply within philosophy of chemistry, as significant problems exist around a number of core chemical ideas. Specifically, one cannot take the obvious success of quantum theories as outright support for a reductive relationship. Instead, in the context of a suitably adapted Nagelian framework for reduction, modern chemistry's relationship to physics is constitutive. The results provided by quantum chemistry, in partic ular, have significant consequences for chemical ontology. This book is ideal for students, scholars and academics from the field of Philosophy of Science, and particularly for those with an interest in Philosophy of Chemistry and Physics.

This comprehensive work explores interfacial instability and pattern formation in dynamic systems away from the equilibrium state in solidification and crystal growth. Further, this significantly expanded 2nd edition introduces and reviews the progress made during the last two decades. In particular, it describes the most prominent pattern formation phenomena commonly observed in material processing and crystal growth in the framework of the previously established interfacial wave theory, including free dendritic growth from undercooled melt, cellular growth and eutectic growth in directional solidification, as well as viscous fingering in Hele-Shaw flow. It elucidates the key problems, systematically derives their mathematical solutions by pursuing a unified, asymptotic approach, and finally carefully examines these results by comparing them with the available experimental results. The asymptotic approach described here will be useful for the investigation of pattern formation phenomena occurring in a much broader class of inhomogeneous dynamical systems. In addition, the results on global stability and selection mechanisms of pattern formation will be of particular interest to researchers working on material processing and crystal growth. The stability mechanisms of a curved front and the pattern formation have been fundamental subjects in the areas of condensed-matter physics, materials science, crystal growth, and fluid mechanics for some time now. This book offers a stimulating and insightful introduction for all physicists, engineers and applied mathematicians working in the fields of soft condensed-matter physics, materials science, mechanical and chemical engineering, fluid dynamics, and nonlinear sciences.

This book provides an overview of hydrogen production from renewable resources such as ethanol using plasma or plasma-catalytic technologies. Further, it presents a balanced and comprehensive treatment of the core principles, novel plasma reactors and diagnostics, as well as state-of-the-art plasma energy applications. It brings together technological advances and research on plasma generators and their application in hydrogen production, including plasma-assisted alcohol reforming technology, plasma-catalytic alcohol reforming technology, the alcohol reforming mechanism, models of alcohol reforming for hydrogen production, the energy balance of hydrogen production from ethanol, and a comparison of alcohol reforming assisted by different plasma treatment systems. As such, it offers a valuable reference guide for scientists, engineers and graduate students in the fields of energy and environment, plasma physics and chemistry.

This book presents a design-driven investigation into smart materials developed by chemists, physicists, materials and chemical engineers, and applied by designers to consumer products, buildings, interfaces, or textiles. Introducing a class of smart materials (referred to as stimuli-responsive, morphing or kinetic materials) that move and change their shape in response to stimuli, the book presents their characteristics, advantages, potentials, as well as the difficulties involved in their application. The book also presents a large number of case studies on products, projects, concepts, and experiments employing smart materials, thus mapping out new design territories for these innovative materials. The case studies involve different fields of design, including product, interior, fashion, and communication design. Reflecting the growing demand for sustainable and human-centered design agendas, the book explores and reveals the role and influence of these new materials and technologies on design and human experience, and discusses how they can be used to redefine our objects and spaces so as to promote more resilient environments. The book offers an intriguing and valuable resource for design professionals, engineers, scientists and students alike.

This is the first book to deal with the innovative technologies in the field of textiles and clothing sustainability. It details a number of sustainable and innovative technologies and highlights their implications in the clothing sector. There are currently various measures to achieve sustainability in the textiles and the clothing industry, including innovations in the manufacturing stage, which is the crux of this book.

This book highlights the manufacturing and applications of acoustic textiles in various industries. It also includes examples from different industries in which acoustic textiles can be used to absorb noise and help reduce the impact of noise at the workplace. Given the importance of noise reduction in the working environment in several industries, the book offers a valuable guide for companies, educators and researchers involved with acoustic materials.

This book, provides a general introduction to the ideas and methods of statistical mechanics with the principal aim of meeting the needs of Master's students in chemical, mechanical, and materials science engineering. Extensive introductory information is presented on many general physics topics in which students in engineering are inadequately trained, ranging from the Hamiltonian formulation of classical mechanics to basic quantum mechanics, electromagnetic fields in matter, intermolecular forces, and transport phenomena. Since engineers should be able to apply physical concepts, the book also focuses on the practical applications of statistical physics to material science and to cutting-edge technologies, with brief but informative sections on, for example, interfacial properties, disperse systems, nucleation, magnetic materials, superfluidity, and ultralow temperature technologies. The book adopts a graded approach to learning, the opening four basic-level chapters being followed by advanced "starred" sections in which special topics are discussed. Its relatively informal style, including the use of musical metaphors to guide the reader through the text, will aid self-learning.

This book details all current techniques for converting bulk polymers into nano-size materials. The authors highlight various physical and chemical approaches for preparation of nano-size polymers. They describe the properties of these materials and their extensive potential commercial applications.

This book focuses on the fundamental principles and latest research findings in hydrogen energy fields including: hydrogen production, hydrogen storage, fuel cells, hydrogen safety, economics, and the impact on society. Further, the book introduces the latest development trends in practical applications, especially in commercial household fuel cells and commercial fuel cell vehicles in Japan. This book not only helps readers to further their basic knowledge, but also presents the state of the art of hydrogen-energy-related research and development. This work serves as an excellent reference for beginners such as graduate students, as well as a handbook and systematic summary of entire hydrogen-energy systems for scientists and engineers.