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Organometallic Modeling of the Hydrodesulfurization and Hydrodenitrogenation Reactions (Paperback, Softcover reprint of the original 1st ed. 2002)
Loot Price: R1,519
Discovery Miles 15 190
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Organometallic Modeling of the Hydrodesulfurization and Hydrodenitrogenation Reactions (Paperback, Softcover reprint of the original 1st ed. 2002)
Series: Catalysis by Metal Complexes, 24
Expected to ship within 10 - 15 working days
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The fields of hydrodesulfurization (HDS) and hydrodenitrogenation
(HDN) continue to attract the attention of researchers in the
various disciplines connected to these fascinating problems that
represent two of the key outstanding chemical challenges for the
petroleum refining industry in view of their very strong
environmental and commercial implications. One area that has
flourished impressively over the last 15 years is the
organometallic chemistry of thiophenes and other related
sulfur-containing molecules. This has become a powerful method for
modeling numerous surface species and reactions implicated in HDS
schemes, and nowadays it represents an attractive complement to the
standard procedures of surface chemistry and heterogeneous
catalysis, for understanding the complex reaction mechanisms
involved in this process. Similar developments have begun to appear
in connection with HDN mechanisms, although in a much more modest
scale and depth. Some years ago when, encouraged by Prof. B. R.
James, this book was planned, several excellent reviews and
monographs treating different aspects of HDS were already available
including some on the subject of organometallic models. However, it
seemed appropriate to try to summarize the most striking features
of this chemistry in an updated and systematic way, and inasmuch as
possible in connection with the common knowledge and beliefs of the
mechanisms of heterogeneous HDS catalysis. Hopefully, this attempt
to build some conceptual bridges between these two traditionally
separated areas of chemistry has met with some success.
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