The current state of the art of several aspects of minerals and petroleum is presented in this volume. It documents the proceedings of the Internationl symposium on Particle Technology and Surface Phenomena in Minerals and Petroleum sponsored by the Fine Particle Society (FPS). This meeting was held in San Diego, California, August 21-25, 1990. The symposium upon which this volume is based was organized in five sessions emphasizing various basic and applied aspects of research on minerals and petroleum technology. Major topics discussed involve surface phenomena in minerals, mineral flotation, characterization of aspaltenes, theoretical aspects of reservoir simulation, porosity, permeability, residual water saturation, hydrocarbon and gas potential in north slope Alaska, polymer/alkaline flooding, surfactant flooding and foam flooding for enhanced oil recovery. This edition includes eighteen selected papers presented in the symposium. These papers are divided in four broad categories: (1) Asphaltene Aggregation and Characterization, (2) Theoretical Aspects and Reservoir Characterization, (3) Colloidal Dispersions in Minerals/Petroleum, and (4) Surface Phenomena and Petroleum Recovery. Several mineral and oil recovery processes using various chemicals with special reference to surface phenomena and particle technology are described in these sections.

Incorporating all recent developments and applications of crystallization technology, this volume offers a clear account of the field's underlying principles, reviews of past and current research, and provides guidelines for equipment and process design. The book takes a balanced functional approach in its critical survey of research literature, and includes several problems based on real practical situations that illustrate theoretical development. Several new concepts and techniques used in process simulation and identification analysis are featured.

In light of recent alarming environmental trends combined with increasing commercial viability of fuel cells, the time is propitious for a book focusing on the systematic aspects of cell plant technology. This multidisciplinary text covers the main types of fuel cells, R&D issues, plant design and construction, and economic factors to provide industrial and academic researchers working in electrical systems design, electrochemistry, and engineering with a unique and comprehensive resource.

If a Writer would know how to behave himself with relation to Posterity; let him consider in old Books, what he finds, that he is glad to know; and what Omissions he most laments. Jonathan Swift This book emerges from a long story of teaching. I taught chemical engineering thermodynamics for about ten years at the University of Naples in the 1960s, and I still remember the awkwardness that I felt about any textbook I chose to consider-all of them seemed to be vague at best, and the standard of logical rigor seemed immensely inferior to what I could find in books on such other of the students in my first class subjects as calculus and fluid mechanics. One (who is now Prof. F. Gioia of the University of Naples) once asked me a question which I have used here as Example 4. 2-more than 20 years have gone by, and I am still waiting for a more intelligent question from one of my students. At the time, that question compelled me to answer in a way I didn't like, namely "I'll think about it, and I hope I'll have the answer by the next time we meet. " I didn't have it that soon, though I did manage to have it before the end of the course.

Practicing engineers and scientist will benefit from this book's presentation of the most accurate information on the subject. The equations for fifteen important cryogenic fluids are presented in a basic format, accompanied by pressure-enthalpy and temperature-entropy charts and tables of thermodynamic properties. The book is supported by ICMPROPRS - an interactive computer program for the calculation of thermodynamic properties of the cryogenic fluids - that can be downloaded from the World Wide Web.

Despite achievements in the application of enzymes, antibodies and biological receptors to diagnostics and sensing, the last two decades have also witnessed the emergence of a number of alternative technologies based on synthetic chemistry. This volume shows how synthetic receptors can be designed with characteristics that make them attractive alternatives to biological molecules in the sensory and diagnostics fields, with contributions from leading experts in the area. Subjects covered include synthetic receptors for a range of biomolecules, the use of antimicrobial peptides for the detection of pathogenic microorganisms, the development of molecularly imprinted polymer (MIP) nanoparticles, the in silico design of MIPs and MIP-based sensors, and two chapters examining the development of sensors from an industrial point of view. The particular focus of all chapters is on practical aspects, either in the development process or the applications of the synthesized materials. This book will serve as an important reference work for business leaders and technology experts in the sensors and diagnostics sector.

The study of multiphase flows is of utmost interest for engineers who are more or less inevitably faced with them when handling various industrial processes or when dealing with environmental problems such as the dispersion of pollutants. It is also a large kingdom assembling many beautiful and weird landscapes in which wandering researchers may be caught by the fascination of precious stones or mysterious insets to deep and obscure caverns. Unfortunately, it is also an historically disconnected field of research, as testified by any textbook contents or by the scientific programs of conferences devoted to multiphase flows. For instance, is there a relation between fluidization and the study of interfacial waves, or between the behaviour of an annular film of liquid and the one of a free surface heated from below? The answer is indeed: yes. To help reveal some unity behind the avatars of multiphase flow behaviours, it has been decided to focus the interest on the instability phenomena. This book therefore provides the reader with most of the papers which have been accepted and/or presented at the international symposium on "instabilities in multiphase flows" held at the National Institute for Applied Science (INS A) in Rouen, France, from the 11 th of May to the 14th of May 1992. The topic of the conference has produced a strong emphasis on instability theory and nonlinear dynamics, including chaotic phenomena.

One area of science that has shown an explosive growth over the last few decades is materials science. Inherently by nature products of both basic and applied research, materials make possible life and society as we know it today. Materials, ranging from ceramics to semiconductors to composites, are such that new ones must not only be designed and made ... they must also be characterized in terms of their physical, chemical, and mechanical properties. Thus, many new state of-the-art techniques involving spectroscopy, microscopy, and other approaches are now routinely used. Modem materials have wide applications in many sectors of technology. Films, for example, constitute an enormous area of materials and are used extensively. Films in tum can be integrated with other systems such as superconducting metal oxides and organic superconductors. Additionally, ceramics can also be synthesized and fabricated as films for different applications. Catalysts, too, can vary widely in both composition and form. The number of applications for catalysts in industry must easily rank as one of the highest number of applications for any class of materials. Catalysis is impOltant for a wide range of activities in industry, from petroleum refining to the synthesis of a large number of industrial feedstock materials. Researchers in this area of materials are constantly trying to unravel new approaches to making better catalysts."

This brief covers novel techniques for clean hydrogen production which primarily involve sodium hydroxide as an essential ingredient to the existing major hydrogen production technologies. Interestingly, sodium hydroxide plays different roles and can act as a catalyst, reactant, promoter or even a precursor. The inclusion of sodium hydroxide makes these processes both kinetically and thermodynamically favorable. In addition possibilities to produce cleaner hydrogen, in terms of carbon emissions, are described. Through modifications of steam methane reformation methods and coal-gasification processes, from fossil as well as non-fossil energy sources, the carbon dioxide emissions of these established ways to produce hydrogen can significantly be reduced. This brief is aimed at those who are interested in expanding their knowledge on novel techniques and materials to produce clean hydrogen and capture carbon dioxide at a large-scale. The detailed thermodynamic analysis, experimental findings and critical analysis of such techniques are well discussed in this brief. Therefore, this book will be of great interest and use to students, engineers and researchers involved in developing the hydrogen economy as well as mitigating carbon dioxide emissions at a large-scale.

Water-based technology has undergone revolutionary changes during the past two decades. Interest in the properties and uses of water-based coatings, paints and inks has continued to grow since the establishment of the Clean Air Act of 1970. The present book is devoted to recent developments and trends in water-based coating and ink technology. This volume is divided in three broad catagories: (1) Additives and Water-based Coating/Ink Systems, (2) Surface Modifications and Wettability, and (3) Ink/Coating Formulations and Their characterization. The role of various additives to improve the performance and properties of water-based coatings with special reference to surface phenomena such as wettability, adhesion, surface energies, dispersion stability, particle size and size distribution are presented in these sections. This volume documents the proceedings of the International symposium on Surface Phenomena and Additives in Water-Based Coatings and Printing Technology sponsored by the 21st Annual Meeting of the Fine Particle Society (FPS). This meeting was held in San Diego, california, AUgust 21-25, 1990. The symposium upon which this volume is based was organized in four sessions emphasizing several basic and applied aspects of water-based coatings and printing technology. Major topics discussed include advances in water-based technology, water-based flexo and gravure inks, hydrophobically-modified cellulosic thickeners, organosilicones, uv curable silicone release coatings, surface characterization of Ti02 pigments, polymer substrates, flexographic plates and coating films, pigment wetting and dispersing agents, hydrotrope effect in emulsion polymers, film thickness control, particle size measurements, rheological properties, and statistically designed mixtures for ink formulations.

Databook of Solvents, Second Edition, has been redesigned to include all high production volume solvents and has been completely updated with the most up-to-date findings, data and commercial developments. With more than 250 of the most essential solvents used in everyday industrial practice, the book includes their physical properties, health and safety considerations (such as carcinogenicity, reproduction/developmental toxicity, flammability), and first aid guidance. Emphasis is placed on cost-saving and efficient replacements for more toxic solvents. Detailed information is also given for usage considerations, including outstanding properties, potential substitutes, features, and recommended benefits for each solvent.

to the Fundamental and Applied Catalysis Series Catalysis is important academically and industrially. It plays an essential role in the manufacture of a wide range of products, from gasoline and plastics to fertilizers and herbicides, which would otherwise be unobtainable or prohibitively expensive. There are few chemical-or oil-based material items in modem society that do not depend in some way on a catalytic stage in their manufacture. Apart from manu facturing processes, catalysis is finding other important and ever-increasing uses; for example, successful applications of catalysis in the control of pollution and its use in environmental control are certain to increase in the future. The commercial importance of catalysis and the diverse intellectual challenges of catalytic phenomena have stimulated study by a broad spectrum of scientists, including chemists, physicists, chemical engineers, and material scientists. Increas ing research activity over the years has brought deeper levels of understanding, and these have been associated with a continually growing amount of published material. As recently as sixty years ago, Rideal and Taylor could still treat the subject comprehensively in a single volume, but by the 1950s Emmett required six volumes, and no conventional multivolume text could now cover the whole of catalysis in any depth. In view of this situation, we felt there was a need for a collection of monographs, each one of which would deal at an advanced level with a selected topic, so as to build a catalysis reference library.

The fluorine atom, by virtue of its electronegativity, size, and bond strength with carbon, can be used to create compounds with remarkable properties. Small molecules containing fluorine have many positive impacts on everyday life of which blood substitutes, pharmaceuticals, and surface modifiers are only a few examples. Fluoropolymers, too, while traditionally associated with extreme high performance applications have found their way into our homes, our clothing, and even our language. A recent American president was often likened to the tribology of PTFE. Since the serendipitous discovery of Teflon at the DuPont Jackson Laboratory in 1938, fluoropolymers have grown steadily in technological and marketplace importance. New synthetic fluorine chemistry, new processes, and new apprecia tion of the mechanisms by which fluorine imparts exceptional properties all contribute to accelerating growth in fluoropolymers. There are many stories of harrowing close calls in the fluorine chemistry lab, especially from the early years, and synthetic challenges at times remain daunting. But, fortunately, modem techniques and facilities have enabled significant strides toward taming both the hazards and synthetic uncertainties, In contrast to past environmental problems associated with fluorocarbon refrigerants, the exceptional properties of fluorine in polymers have great environmental value. Some fluoropolymers are enabling green technologies such as hydrogen fuel cells for automobiles and oxygen selective membranes for cleaner diesel combustion.

Increasing emphasis on safety, productivity and quality control has provided an impetus to research on better methodologies for fault diagnosis, modeling, identification, control and optimization ofchemical process systems. One of the biggest challenges facing the research community is the processing of raw sensordata into meaningful information. Wavelet analysis is an emerging field of mathematics that has provided new tools and algorithms suited for the type of problems encountered in process monitoring and control. The concept emerged in the geophysical field as a result ofthe need for time-frequency analytical techniques. It has since been picked up by mathematicians and recognized as a unifying theory for many ofthe methodologies employed in the past in physics and signal processing. l Meyer states: "Wavelets are without doubt an exciting and intuitive concept. The concept brings with it a new way of thinking, which is absolutely essential and was entirely missing in previously existing algorithms. " The unification ofthe theory from these disciplines has led to applications of wavelet transforms in many areas ofscience and engineering including: * pattern recognition * signal analysis * time-frequency decomposition * process signal characterization and representation * process system modeling and identification * control system design, analysis and implementation * numerical solution ofdifferential equations * matrix manipulation About a year ago, in talking to various colleagues and co-workers, it became clear that a number of chemical engineers were fascinated with this new concept.

This book addresses the behavior of inorganic material in combustion systems. The past decade has seen unprecedented improvements in understanding the rates and mecha nisms of inorganic transformations and in developing analytical tools to predict them. These tools range from improved fuel analysis procedures to predictive computer codes. While this progress has been met with great enthusiasm within the research community, the practices of the industrial community remain largely unchanged. The papers in this book were selected from those presented at an Engineering Foundation Conference of the same title. All have been peer reviewed. The intent of the conference was to illustrate the application of advanced technology to ash-related problems in boilers and, by so doing, engage the research and industrial communities in more productive dialog. Those attending the conference generally felt that we were successful on these counts. We also engaged the industrial community to a greater extent than ever before in the conference discussion and presentation. We hope these proceedings will facilitate a continued and improved interaction between industrial and research communities. Behavior of inorganic material has long been recognized as one of the major considerations affecting the design and operation of boilers that burn ash-producing fuels. The practical problems associated with the behavior are sometimes catastrophic and spec tacular, ranging from major slag falls that damage the bottom of furnaces to complete plugging of convection passes."

The ninth International Cryogenic Materials Conference (ICMC) was held on the campus of the University of Alabama at Huntsville (UAH) in collaboration with the Cryogenic Engineering Conference (CEC) on June 11-14, 1991. The continuing bond between these two major conferences in the field of cryogenics is indicative of the extreme interdependence of their subject matter. The major purpose of the conference is sharing of the latest advances in low temperature materials science and technology. However, the many side benefits which accrue when this many experts gather, such as identification of new research areas, formation of new collaborations which often cross the boundaries of both scientific discipline and politics, and a chance for those new to the field to meet the old-timers, may override the stated purpose. This 1991 ICMC was chaired by F. R. Fickett of the National Institute of Standards and Technology. K. T. Hartwig, of Texas A&M served as Program Chairman with the assistance of eleven other Program Committee members. We especially appreciate the contributions of the CEC board and its Conference Chairman, J. Hendricks of Alabama Cryogenic Engineering, to the organization. of this joint conference. UAH hosted the conference. The local arrangements and management, under the watchful eye of Ann Yelle and Mary Beth Magathan of the UAH conference staff, were excellent. Participation in the CEC/ICMC continues to exceed expectations with 650 registrants for the combined conference.

Over the last several years, the field of materials science has witnessed an explosion of new, advanced materials. They encompass many uses and include superconductors, alloys, glasses, and catalysts. Not only are there quite a number of new enhies into these generic classes of materials, but the materials themselves represent a wide array of physical forms as well. Bulk materials, for example, are being synthesized and applica tions found for them, while still other materials are being synthesized as thin films for yet still more new (and in some cases, as yet unknown) applications. The field continues to expand with (thankfully ) no end in sight as to the number of new possibilities. As work progresses in this area, there is an ever increasing demand for knowing not only what material is formed as an end product but also details of the route by which it is made. The knowledge of reaction mechanisms in their synthesis many times allows a researcher to tailor a preparative scheme to either arrive at the final product in a purer state or with a better yield. Also, a good fundamental experimental knowledge of impuri ties present in the final material helps the investigator get more insight into making it."

Filling the need for new and improved energy sources is an area where societal effects of science and technology will surely increase. The editors and authors have attempted in this volume to present the most current work on the science and technology of coal and coal utilization. Serious disagreement exists on several key issues such as carbon dioxide release and acid rain. At the same time, however, coal is the world's most abundant fossil fuel and will have to be used to supply the world's energy needs for the next several decades. The 1979 National Research Council Report, "En ergy in Transition: 1985-2010," has estimated that the United States alone may go from a 1979 coal consumption of 14 QUADS per annum (approximately 750 million tons per year) to approximately 40-50 QUADS per annum (approximately 2 billion tons per year) by the year 2010. If this scale of coal utilization is to become a reality, a significant level of research and development will be necessary to establish advanced process technologies and to improve related areas such as materials and instrumentation. The editors hope that this volume will allow a technically educated person to become aware of the several aspects of coal utilization, from characterization of coal itself to the processes of coal utilization. B. R. Cooper and W. A. Ellingson March, 1983 vii Contents 1. THE SCIENCE AND TECHNOLOGY OF COAL AND COAL UTILIZATION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Bernard R. Cooper and William A. Ellingson 2. COAL CHARACTERIZATION. . . . . . . . . . . . . . . . . . . . . . . . . . . .

Developed from the Global Foundation's International Conference on Environment and Nuclear Energy, held in October 1997, this volume examines the impact of nuclear energy on regional and global environmental issues under a variety of scenarios. These include competition in deregulated energy environments, constraints levied upon use of fossil energy, and possible expansion of nuclear power into energy sectors beyond the generation of electricity, process heat, and fuels production. It also assesses the overall role of nuclear energy in meeting future energy needs arising from growing world populations and economic development.

Microfluidic fuel cells and batteries represent a special type of electrochemical power generators that can be miniaturized and integrated in a microfluidic chip. Summarizing the initial ten years of research and development in this emerging field, this SpringerBrief is the first book dedicated to microfluidic fuel cell and battery technology for electrochemical energy conversion and storage. Written at a critical juncture, where strategically applied research is urgently required to seize impending technology opportunities for commercial, analytical, and educational utility, the intention is for this book to be a 'one-stop shop' for current and prospective researchers in the general area of membraneless, microfluidic electrochemical energy conversion. As the overall goal of the book is to provide a comprehensive resource for both research and technology development, it features extensive descriptions of the underlying fundamental theory, fabrication methods, and cell design principles, as well as a thorough review of previous contributions in this field and a future outlook with recommendations for further work. It is hoped that the content will entice and enable new research groups and engineers to rapidly gain traction in their own laboratories towards the development of next generation microfluidic electrochemical cells.

The field of high-temperature superconductivity has encouraged an inter disciplinary approach to research. It has required significant cooperation and collaboration among researchers, each of whom has brought to it a rich variety of experience from many other fields. Recently, great improvements have been made in the quality of research. The subject has matured and been launched into the next stage through the resonance between science and technology. The current progress of materials processing and engineering in this field is analogous to that previously seen in the development of semiconductors. These include the appearance of materials taking the place of YBa2Cu307 owing to their improved properties (higher critical temperatures and stronger flux pin ning) in which rare earth ions with large radii (La, Nd, Sm) substitute for Y; the development of technology enabling growth control on the nanometer scale; and precise and reproducible measurements that can be used as rigorous tests of theoretical models, which in turn are expected to lead to the develop ment of new devices. For further progress in high-T research, academics and c technologists must pool their knowledge and experience. I hope that this volume will promote that goal by providing the reader with the latest results of high-temperature superconductor research and will stimulate further discussion and collaboration.

The Advanced Study Institute on Breakdown and Discharges in Gases was held in Les Arcs, France, June 28 to July 10, 1981. The object of the Institute was to provide a broad but compre hensive presentation of the various topics in the field of Gaseous electronics. To achieve this goal, a number of lectures, seminars, and panel discussions were scheduled. Each topic was developed by two tutorial and/or review lectures, and brought to the present state of the topic by seminars and panel discussions. The program of topics and speakers was selected with the assistance of the advisory committee composed of: J. A. Rees, European Coordinator, England; M. Goldman, French Coordinator, France; A. H. Guenther, USA; M. Kristiansen, USA; and A. V. Phelps, USA. The most memorable aspect of the Institute was the sustained high interest of the faculty and participants for the two week period. The daily schedule was demanding: five hours of lectures, two hours of seminars and one of discussion. These sessions were often extended because of presentation by the participants of im proptu seminars. The discussions were intense. Majestic }10nt Blanc provided the backdrop for the lecture hall, and these surroundings and the weather contributed to the overall positive mood. It was a wonderful occasion. The lectures and seminars have been collected into two volumes."

The vast eruption of books about energy that has appeared in the past decade has yielded few that could properly be called learning or. alternatively. teaching texts. This one is based principally on ten years of course offerings to senior undergraduates and graduate students at the Massachusetts Institute of Tech nology. and to middle-level and senior executives who attended accelerated study programs there. Teaching and learning are different; the first is an external act meant to stimulate the second. which is a very internal one. They are surely related. but it does not automatically follow that because I teach. the listener learns. This book. Learning about Energy. attempts to bridge that gap by putting in the hands of teachers. students. and independent readers a broad overview of the energy field. at a level that permits them to enter the more specialized topics with substantial perspective about the whole of it. The material is used for a one-semester course at M.I.T.. but could be one or two semesters there or elsewhere. according to how a thoughtful instructor might abridge some parts. or extend others via the numerous references. the problems at the ends of chapters. and current topics. Learning about Energy deals with energy as more than technology or eco nomics or any other specific parts. It deals with energy as part of the fabric of civilization. This requires some elaboration. As people and societies need food."