Metals and Alloys continues the series of graduate textbooks on Industrial Chemistry by Mark A. Benvenuto. It shows the essential industrial applications, processes and chemistry background for the extraction of metals, as well as the production and applications of alloys. The book discusses how large scale and minor processes affect every-day life, challenges in prevention and removal of waste by-products and illustrates selected chemical processes for which efforts have been made to improve and "green" industrial production of metals and alloys. Sources for metals are sorted by metal and alloy and backed by basic chemical background information and process set up. Overviews on worldwide ore distribution, refined metal and alloy production numbers are another focus of the book. Discusses sources, key processes and applications. Connects what students learn in class to real, large-scale metals chemistry that makes modern life possible. Intended for students, graduate students and beginners in the fiield of Chemistry, Chemical Process Engineering, Chemical Engineering and Materials Science. Visit degruyter.com for more information on books by Mark A. Benvenuto: Industrial Chemistry (2013), Industrial Chemistry: For Advanced Students (2015) and Industrial Inorganic Chemistry (2015). About the Author: Mark Anthony Benvenuto A Fellow of the American Chemical Society, he received his PhD in inorganic chemistry from the University of Virginia. After a post-doctoral fellowship at the Pennsylvania State University, he joined the University of Detroit Mercy, where he is now the Department Chairman and teaches an industrial chemistry course.

This book presents an overview of the characterization of electronic waste. In addition, processing techniques for the recovery of metals, polymers and ceramics are described. This book serves as a source of information and as an educational technical reference for practicing scientists and engineers, as well as for students.

Research for the development of more efficient photocatalysts has experienced an almost exponential growth since its popularization in early 1970's. Despite the advantages of the widely used TiO2, the yield of the conversion of sun power into chemical energy that can be achieved with this material is limited prompting the research and development of a number of structural, morphological and chemical modifications of TiO2 , as well as a number of novel photocatalysts with very different composition. Design of Advanced Photocatalytic Materials for Energy and Environmental Applications provides a systematic account of the current understanding of the relationships between the physicochemical properties of the catalysts and photoactivity. The already long list of photocatalysts phases and their modifications is increasing day by day. By approaching this field from a material sciences angle, an integrated view allows readers to consider the diversity of photocatalysts globally and in connection with other technologies. Design of Advanced Photocatalytic Materials for Energy and Environmental Applications provides a valuable road-map, outlining the common principles lying behind the diversity of materials, but also delimiting the imprecise border between the contrasted results and the most speculative studies. This broad approach makes it ideal for specialist but also for engineers, researchers and students in related fields.

This concise volume explains when to procure new equipment, how to prepare specifications for floating inquiries, and guidelines for detailed technical discussions with vendors in the chemical and related industries. It covers the common equipment and supplies used in chemical plants, refineries-please delete reference to refineries, and effluent treatment facilities such as pumps, blowers, reactors, heat exchangers, waste heat recovery boilers, heat and acid resistant lining etc. The book serves as a checklist to the plant managements for procurement of the correct equipment in the most efficient timeframe insuring that projects are not delayed due to long time required for procurement of new equipment.

This book describes new and efficient calorimetric measurement methods, which can be used to accurately follow the chemical kinetics of liquid phase reaction systems. It describes apparatus and techniques for the precise measuring of the rate of heat liberation in discontinuous and continuous isothermal as well as non-isothermal reactions. The presented methodology can be used to follow the development of chemical reactions online, even in industrial scales. Written by an experienced scientist and practitioner, who can look back on long-standing expert knowledge in chemical engineering, the book contains many practical hints and instructions. The reader will find a sound compact introduction to fundamentals, and comprehensive technical background information and instructions for performing own kinetic experiments. This book is the fusion of scientific background information and long hands-on experience in the practice.

This book provides insights into the development and usage of coal in chemical engineering. The reactivity of coal in processes such as pyrolysis, gasification, liquefaction, combustion and swelling is related to its structural properties. Using experimental findings and theoretical analysis, the book comprehensively answers three crucial issues that are fundamental to the optimization of coal chemical conversions: What is the structure of coal? How does the underlying structure determine the reactivity of different types of coal? How does the structure of coal alter during coal conversion? This book will be of interest to both individual readers and institutions involved in teaching and research into chemical engineering and energy conversion technologies. It is aimed at advanced- level undergraduate students. The text is suitable for readers with a basic knowledge of chemistry, such as first-year undergraduate general science students. Higher-level students with an in-depth understanding of the chemistry of coal will also benefit from the book. It will provide a useful reference resource for students and university-level teachers, as well as practicing engineers.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

This thesis describes novel strategies for the rational design of several cutting-edge high-efficiency photocatalysts, for applications such as water photooxidation, reduction, and overall splitting using a Z-Scheme system. As such, it focuses on efficient strategies for reducing energy loss by controlling charge transfer and separation, including novel faceted forms of silver phosphate for water photooxidation at record high rates, surface-basic highly polymerised graphitic carbon nitride for extremely efficient hydrogen production, and the first example of overall water splitting using a graphitic carbon nitride-based Z-Scheme system. Photocatalytic water splitting using solar irradiation can potentially offer a zero-carbon renewable energy source, yielding hydrogen and oxygen as clean products. These two ‘solar’ products can be used directly in fuel cells or combustion to provide clean electricity or other energy. Alternatively they can be utilised as separate entities for feedstock-based reactions, and are considered to be the two cornerstones of hydrogenation and oxidation reactions, including the production of methanol as a safe/portable fuel, or conventional catalytic reactions such as Fischer-Tropsch synthesis and ethylene oxide production. The main driving force behind the investigation is the fact that no photocatalyst system has yet reported combined high efficiency, high stability, and cost effectiveness; though cheap and stable, most suffer from low efficiency.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts presents a complete overview of the selective catalytic reduction of NOx by ammonia/urea. The book starts with an illustration of the technology in the framework of the current context (legislation, market, system configurations), covers the fundamental aspects of the SCR process (catalysts, chemistry, mechanism, kinetics) and analyzes its application to useful topics such as modeling of full scale monolith catalysts, control aspects, ammonia injections systems and integration with other devices for combined removal of pollutants.

This book introduces two of the most exciting heat pumping technologies, the coabsorbent and the thermal recovery (mechanical vapor) compression, characterized by a high potential in primary energy savings and environmental protection. New cycles with potential applications of nontruncated, truncated, hybrid truncated, and multi-effect coabsorbent types are introduced in this work. Thermal-to-work recovery compression (TWRC) is the first of two particular methods explored here, including how superheat is converted into work, which diminishes the compressor work input. In the second method, thermal-to-thermal recovery compression (TTRC), the superheat is converted into useful cooling and/or heating, and added to the cycle output effect via the coabsorbent technology. These and other methods of discharge gas superheat recovery are analyzed for single-, two-, three-, and multi-stage compression cooling and heating, ammonia and ammonia-water cycles, and the effectiveness results are given. The author presents absorption-related topics, including the divided-device method for mass and heat transfer analysis, and truncation as a unique method for a better source-task match. Along with advanced gax recovery, the first and second principles of COP and exergy calculation, the ideal point approaching (i.p.a.) effect and the two-point theory of mass and heat transfer, the book also addresses the new wording of the Laplace equation, the Marangoni effect true explanation, and the new mass and heat exchangers based on this effect. The work goes on to explore coabsorbent separate and combined cooling, heating, and power (CHP) production and advanced water-lithium bromide cycle air-conditioning, as well as analyzing high-efficiency ammonia-water heat-driven heating and industrial low-temperature cooling, in detail. Readers will learn how coabsorbent technology is based on classic absorption, but is more general. It is capable of offering effective solutions for all cooling and heating applications (industry, agriculture, district, household, etc.), provided that two supplying heat-sink sources with temperatures outdistanced by a minimum of 12-15C are available. This book has clear and concise presentation and illustrates the theory and applications with diagrams, tables, and flowcharts.

This book is a simple and didactic account of the developments and practical applications of predictive, adaptive predictive, and optimized adaptive control from a perspective of stability, including the latest methodology of adaptive predictive expert (ADEX) control. ADEX Optimized Adaptive Control Systems is divided into six parts, with exercises and real-time simulations provided for the reader as appropriate. The text begins with the conceptual and intuitive knowledge of the technology and derives the stability conditions to be verified by the driver block and the adaptive mechanism of the optimized adaptive controller to guaranty the desired control performance. The second and third parts present strategic considerations of predictive control and related adaptive systems necessary for the proper design of driver block and adaptive mechanism and thence their technical realization. The authors then proceed to detail the stability theory that supports predictive, adaptive predictive and optimized adaptive control methodologies. Benchmark applications of these methodologies (distillation column and pulp-factory bleaching plant) are treated next with a focus on practical implementation issues. The final part of the book describes ADEX platforms and illustrates their use in the design and implementation of optimized adaptive control systems to three different challenging-to-control industrial processes: waste-water treatment; sulfur recovery; and temperature control of superheated steam in coal-fired power generation. The presentation is completed by a number of appendices containing technical background associated with the main text including a manual for the ADEX COP platform developed by the first author to exploit the capabilities of adaptive predictive control in real plants. ADEX Optimized Adaptive Control Systems provides practicing process control engineers with a multivariable optimal control solution which is adaptive and resistant to perturbation and the effects of noise. Its pedagogical features also facilitate its use as a teaching tool for formal university and Internet-based open-education-type graduate courses in practical optimal adaptive control and for self-study.

Proton exchange membrane (PEM) fuel cells are promising clean energy converting devices with high efficiency and low to zero emissions. Such power sources can be used in transportation, stationary, portable and micro power applications. The key components of these fuel cells are catalysts and catalyst layers. "PEM Fuel Cell Electrocatalysts and Catalyst Layers" provides a comprehensive, in-depth survey of the field, presented by internationally renowned fuel cell scientists. The opening chapters introduce the fundamentals of electrochemical theory and fuel cell catalysis. Later chapters investigate the synthesis, characterization, and activity validation of PEM fuel cell catalysts. Further chapters describe in detail the integration of the electrocatalyst/catalyst layers into the fuel cell, and their performance validation. Researchers and engineers in the fuel cell industry will find this book a valuable resource, as will students of electrochemical engineering and catalyst synthesis.

Methanol - The Chemical and Energy Feedstock of the Future offers a visionary yet unbiased view of methanol technology. Based on the groundbreaking 1986 publication "Methanol" by Friedrich Asinger, this book includes contributions by more than 40 experts from industry and academia. The authors and editors provide a comprehensive exposition of methanol chemistry and technology which is useful for a wide variety of scientists working in chemistry and energy related industries as well as academic researchers and even decision-makers and organisations concerned with the future of chemical and energy feedstocks.

Though the game-theoretic approach has been vastly studied and utilized in relation to economics of industrial organizations, it has hardly been used to tackle safety management in multi-plant chemical industrial settings. Using Game Theory for Improving Safety within Chemical Industrial Parks presents an in-depth discussion of game-theoretic modeling which may be applied to improve cross-company prevention and -safety management in a chemical industrial park. By systematically analyzing game-theoretic models and approaches in relation to managing safety in chemical industrial parks, Using Game Theory for Improving Safety within Chemical Industrial Parks explores the ways game theory can predict the outcome of complex strategic investment decision making processes involving several adjacent chemical plants. A number of game-theoretic decision models are discussed to provide strategic tools for decision-making situations. Offering clear and straightforward explanations of methodologies, Using Game Theory for Improving Safety within Chemical Industrial Parks provides managers and management teams with approaches to asses situations and to improve strategic safety- and prevention arrangements.

This book investigates the potential medical benefits natural biomaterials can offer in developing countries by analyzing the case of Bolivia. The book explores the medical and health related applications of Bolivian commodities: quinoa, barley, sugarcane, corn, sorghum and sunflower seeds. This book helps readers better understand some of the key health concerns facing countries like Bolivia and how naturally derived biomaterials and therapeutics could help substantially alleviate many of their problems.

First published in 1918, this book forms the second of two volumes on the properties of oils, fats and waxes. The texts were designed to meet the needs of technical workers and chemists requiring guidance on the basic principles underlying the area. Volume one focuses on chemical and general properties; volume two concentrates on practical and analytical matters. Numerous illustrative figures are incorporated throughout. This book will be of value to anyone with an interest in chemistry and the history of science.

First published in 1918, as the second edition of a 1917 original, this book forms part one of two volumes on the properties of oils, fats and waxes. The texts were designed to meet the needs of technical workers and chemists requiring guidance on the basic principles underlying the area. Volume one focuses on chemical and general properties; volume two concentrates on practical and analytical matters. Numerous illustrative figures are incorporated throughout. This book will be of value to anyone with an interest in chemistry and the history of science.

Manuel Kroiss examines the differentiation of hematopoietic stem cells using machine learning methods. This work is based on experiments focusing on the lineage choice of CMPs, the progenitors of HSCs, which either become MEP or GMP cells. The author presents a novel approach to distinguish MEP from GMP cells using machine learning on morphology features extracted from bright field images. He tests the performance of different models and focuses on Recurrent Neural Networks with the latest advances from the field of deep learning. Two different improvements to recurrent networks were tested: Long Short Term Memory (LSTM) cells that are able to remember information over long periods of time, and dropout regularization to prevent overfitting. With his method, Manuel Kroiss considerably outperforms standard machine learning methods without time information like Random Forests and Support Vector Machines.

In his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and Moessbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials.

Practical applications of soft-matter dynamics are of vital importance in material science, chemical engineering, biophysics and biotechnology, food processing, plastic industry, micro- and nano-system technology, and other technologies based on non-crystalline and non-glassy materials. Principles of Soft-Matter Dynamics. Basic Theories, Non-invasive Methods, Mesoscopic Aspects covers fundamental dynamic phenomena such as diffusion, relaxation, fluid dynamics, normal modes, order fluctuations, adsorption and wetting processes. It also elucidates the applications of the principles and of the methods referring to polymers, liquid crystals and other mesophases, membranes, amphiphilic systems, networks, and porous media including multiphase and multi-component materials, colloids, fine-particles, and emulsions. The book presents all formalisms, examines the basic concepts needed for applications of soft-matter science, and reviews non-invasive experimental techniques such as the multi-faceted realm of NMR methods, neutron and light quasi-elastic scattering, mechanical relaxation and dielectric broadband spectroscopy which are treated and compared on a common and consistent foundation. The standard concepts of dynamics in fluids, polymers, liquid crystals, colloids and adsorbates are comprehensively derived in a step-by-step manner. Principles and analogies common to diverse application fields are elucidated and theoretical and experimental aspects are supplemented by computational-physics considerations. Principles of Soft-Matter Dynamics. Basic Theories, Non-invasive Methods, Mesoscopic Aspects appeals to graduate and PhD students, post-docs, researchers, and industrial scientists alike.

This book offers a comprehensive approach to innovation management. Based on a solid scientifi c basis, it provides concepts to initiate, pursue, target and supervise innovation projects through specifi c action steps. Suitable methods are given for inventions by development, research, forecast and creativity. Each chapter offers examples and shortcut rules to facilitate the comprehension for the reader. Moreover, the author explains the historic origins of innovation and its role in economy, business, and technological progress, underlining the importance of innovation for the improvement of business or the disruption of established models. The science of innovation aims to give a solid theoretical background to students of appropriate academic courses and to anyone interested in supporting and developing innovation projects.

Industrial biorefineries have been identified as the most promising routes to the creation of a bio-based economy. Partial biorefineries already exist in some energy crop, forest-based, and lignocellulosic product facilities. Biorefineries: For Biomass Upgrading Facilities examines the variety of different technologies which integrated bio-based industries use to produce chemicals; biofuels; food and feed ingredients; biomaterials; and power from biomass raw materials. Conversion technologies are also covered, since biomass can be converted into useful biofuels and biochemicals via biomass upgrading and biorefinery technologies.

Biorefineries: For Biomass Upgrading Facilities will prove a practical resource for chemical engineers, and fuel and environmental engineers. It will also be invaluable in academic fields, providing useful information for both researchers and students.

Guaranteeing a high system performance over a wide operating range is an important issue surrounding the design of automatic control systems with successively increasing complexity. As a key technology in the search for a solution, advanced fault detection and identification (FDI) is receiving considerable attention. This book introduces basic model-based FDI schemes, advanced analysis and design algorithms, and mathematical and control-theoretic tools. This second edition of Model-Based Fault Diagnosis Techniques contains: * new material on fault isolation and identification and alarm management; * extended and revised treatment of systematic threshold determination for systems with both deterministic unknown inputs and stochastic noises; * addition of the continuously-stirred tank heater as a representative process-industrial benchmark; and * enhanced discussion of residual evaluation which now deals with stochastic processes. Model-based Fault Diagnosis Techniques will interest academic researchers working in fault identification and diagnosis and as a text it is suitable for graduate students in a formal university-based course or as a self-study aid for practising engineers working with automatic control or mechatronic systems from backgrounds as diverse as chemical process and power engineering.

The book gives an overview of environmental friendly gaseous and vapour, refrigerated compressed gas, solid lubricant, mist lubrication, minimum quantity lubrication (MQL) and vegetable oils that can be used as lubricants and additives in industrial machining applications. This book introduces vegetable oils as viable and good alternative resources because of their environmental friendly, non-toxic and readily biodegradable nature. The effectiveness of various types of vegetables oils as lubricants and additives in reducing wear and friction is discussed in this book. Engineers and scientist working in the field of lubrication and machining will find this book useful.