This book introduces models and methodologies that can be employed towards making the Industry 4.0 vision a reality within the process industries, and at the same time investigates the impact of uncertainties in such highly integrated settings. Advances in computing power along with the widespread availability of data have led process industries to consider a new paradigm for automated and more efficient operations. The book presents a theoretically proven optimal solution to multi-parametric linear and mixed-integer linear programs and efficient solutions to problems such as process scheduling and design under global uncertainty. It also proposes a systematic framework for the uncertainty-aware integration of planning, scheduling and control, based on the judicious coupling of reactive and proactive methods. Using these developments, the book demonstrates how the integration of different decision-making layers and their simultaneous optimisation can enhance industrial process operations and their economic resilience in the face of uncertainty.

For more than ten years, the Science for Conservators Series have been the key basic texts for conservators throughout the world. Scientific concepts are basic ot the conservation of artefacts of every type, yet many conservators have little or no scientific training. These introductory volumes provide non-scientists with the essential theoretical background to their work.

This book presents the proceedings of the International Conference on Health, Safety, Fire, Environment, and Allied Sciences (HSFEA 2018). The book highlights the latest developments in the field of science and technology aimed at improving health and safety in the workplace. The volume comprises content from leading scientists, engineers, and policy makers, discussing the effect of vehicular pollution, process, engineering, construction and other industrial activities on air quality and the impact these have on health and the environment. The contents of this volume will be of interest to researchers, practitioners, and policy makers alike.

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Distillation based on Mass Transfer Processes, starting from the basic equation of ternary distillation published by Hausen in 1932 and exploiting the properties of this equation covering all modes of distillation. The material is intended as a graduate textbook for an advanced course on distillation but will also help the practicing engineer to better understand the complex interrelationships of multi-component distillation.

This book focuses on the mechanical properties and performance of products made of fiber-based materials. It helps students to develop skills for solving problems of product performance and engineering challenges in product development. Organized with a problem-based approach - practical examples of product performance are presented and the relevant mechanics are analyzed to deduce which material properties control the performance. The new edition covers state-of-the-art and green technologies as modeling of fiber networks and applications of nanocellulose.

This book outlines the methodologies, approaches and tools for modelling chemicals in a Life Cycle Assessment (LCA) perspective, and also covers the main advantages and drawbacks of applying LCA to chemical processes. In the first part of this book, authors pay close attention to the limitations of modelling the environmental and social impacts of chemical processes, providing valuable insights to the problems of the Life Cycle Inventory (LCI) analysis for chemical processes. In the second part of this book, readers will learn about the LCA application to chemical processes in the laboratory and industrial scale. In each chapter of this book, readers will also find specific case studies on the modelling and application of LCA in the chemical industry.

The editors and authors, with backgrounds in academia and industry, tie together recent and established technologies for the upcoming change to sustainable industrial chemistry. The extensive worldwide activities towards that goal are exemplified with a series of green processes. Some of these processes are already commercially applied (squalene to squalane, hydraulic fluids from vegetable oils, biosourced polycarbonates), others are ready for a large scale implementation (glycerol to acrylic acid, biosourced acrylonitrile and levulinic acid, polyamides from fatty nitriles-esters hydrogenation, butadiene from bioethanol) or are being developed (cyclic carbonates from epoxides, selective pyrolysis of biomass). This book is an indispensable source for the researchers and professionals who work for a greener chemical industry. The chapters have been arranged to guide students through the design of new processes for more sustainable chemistry, using case studies as examples.

The book systematically presents fundamental principles, properties, implementation methodologies, technologies and applications of polymer synthesis. Ring opening metathesis polymerization, click chemistry, macromolecular self-assembly, carbon nanomaterials and their modification with polymers are discussed in detail. With abundant illustrations, it is an essential reference for polymer chemists, material scientists, and graduate students.

The homogenization of single phase gases or liquids with chemical reactive components by mixing belongs to one of the oldest basic operations applied in chemical engineering. The design of equipment for mixing processes is still derived from measurements of the mixing time which is related to the applied methods of measurement and the special design of the test equipment itself.

This book was stimulated by improved modern methods for experimental research and visualization, for simulations and numerical calculations of mixing and chemical reactions in micro and macro scale of time and local coordinates. It is aimed to improve the prediction of efficiencies and selectivities of chemical reactions in macroscopic scale. The results should give an understanding of the influence of the construction of different mixing equipment on to the momentum, heat and mass transfer as well as reaction processes running on microscopic scales of time and local coordinates.

Newly developed methods of measurement are adjusted to the scales of the selected special transport and conversion processes. They allow a more detailed modeling of the mixing processes by the formulation of an appropriate set of momentum-, heat- and mass balance equations as well as boundary conditions in time and local coordinates together with constitutive equations and reaction kinetics equations as closure laws for numerical and analytical calculations. The latter were empirically derived in the past and therefore of limited reliability only.

The improved and more detailed modeling leads to a major progress in predicting mixing processes on the different scales adjusted to transport and reaction processes in molecular, micro- and macro dimensions.

As a consequence improved numerical calculations are performed on the basis of newly derived experimental, measurement and modeling methods which are the basis for the prediction of mixing time as well as conversion rates and selectivities of chemical reactions during the mixing process. The research efforts are focused onto the design of the technical equipment for flow mixing processes. Mixing is performed inside velocity fields leading to deformation gradients from free or wall induced boundary layers. The different kinds of process equipment are jet mixer, static mixer and mixing vessels equipped with rotating stirrers. Especially in micro mixing newly developed constructions are investigated permitting the scale up from laboratory to technical dimensions.

This volume is devoted to compounds in which the spiro centre is part of a pyranoid or furanoid or an iminosugar ring. The chapters contributed deal with methodological peculiarities of syntheses of natural and artificial sugar derived spirocycles as well as their biological applications and other utilities including marketed drugs. Carbohydrates are ubiquitous molecules in nature and participate in a vast number of biological interactions. Especially their conjugates with practically all kinds of primary and secondary metabolic small molecules (and also biomacromolecules) representing valuable tools for glycobiology research and also lead compounds for drug discovery. While monosaccharides per se appear as heterocycles, their natural conjugates frequently exhibit spiro(hetero)cyclic derivatives, in many cases of high therapeutical relevance. As a consequence, the field of carbohydrate-spiro-heterocycles attracts intense interest from both chemical and biomedical aspects therefore this volume will be of interest for synthetic and medicinal chemists and (glyco)biologists, as well as researchers involved in various biomedical fields.

This book surveys reliability, availability, maintainability and safety (RAMS) analyses of various engineering systems. It highlights their role throughout the lifecycle of engineering systems and explains how RAMS activities contribute to their efficient and economic design and operation. The book discusses a variety of examples and applications of RAMS analysis, including: * software products; * electrical and electronic engineering systems; * mechanical engineering systems; * nuclear power plants; * chemical and process plants and * railway systems. The wide-ranging nature of the applications discussed highlights the multidisciplinary nature of complex engineering systems. The book provides a quick reference to the latest advances and terminology in various engineering fields, assisting students and researchers in the areas of reliability, availability, maintainability, and safety engineering.

'Dripping with delicious detail' - Aditya Chakrabortty Taking the reader on a journey through North East Scotland, Merseyside, South Wales, the Thames Estuary and London, this is the story of Britain's oil-soaked past, present and future. Travelling the country, the authors discover how the financial power and political muscle of an industry built the culture of a nation from pop music to kitchen appliances, and how companies constructed an empire, extracting the wealth of the world from Iran to Nigeria and Alaska. Today, the tide seems to be going out - Britain's refineries have been quietly closed, the North Sea oilfields are declining and wind farms are being built in their place. As the country painfully shifts into its new post-industrial role in the shadow of Covid, Brexit and the climate crisis, many believe the age of oil to be over. But is it? Speaking to oil company executives and traders, as well as refinery workers, filmmakers and musicians, activists and politicians, the authors put real people at the heart of a compelling story.

This book is divided into four parts that outline the use of science and technology for applications pertaining to chemical and bioprocess engineering. The book endeavors to help academia, researchers, and practitioners to use the principles and tools of Chemical and Bioprocess Engineering in a pertinent way, while attempting to point out the novel thoughts associated with the brain storming concepts encountered. As an example, the ability to use case studies appropriately is more important, to most practitioners.

This textbook addresses the chemical and physicochemical principles of supramolecular host-guest chemistry in solution. It covers the thermodynamics and dynamics of inclusion and highlights several types of organic hosts. Various applications of host-guest chemistry in analytical and environmental chemistry as well as pharmaceutical and chemical industry demonstrate the versatile usability of molecular cages.

The major objective of this book is to introduce advanced design and (online) optimization methods for fault diagnosis and fault-tolerant control from different aspects. Under the aspect of system types, fault diagnosis and fault-tolerant issues are dealt with for linear time-invariant and time-varying systems as well as for nonlinear and distributed (including networked) systems. From the methodological point of view, both model-based and data-driven schemes are investigated.To allow for a self-contained study and enable an easy implementation in real applications, the necessary knowledge as well as tools in mathematics and control theory are included in this book. The main results with the fault diagnosis and fault-tolerant schemes are presented in form of algorithms and demonstrated by means of benchmark case studies. The intended audience of this book are process and control engineers, engineering students and researchers with control engineering background.

This book advances a new view of phenomena associated with the spray of liquids from a nozzle in a gas. New results of experimental studies and numerical simulation of the hydrodynamics of an emerging two-phase flow and accompanying interphase heat and mass transfer therein are presented. The book is ideal for specialists who develop and use technologies involving the spraying of liquids in a gas, such as burning and pyrolysis of liquid hydrocarbons, granulation and drying of polymers, and dust and gas scrubbing.

This book addresses the developing area of biomass for technological applications. Written by leading researchers in the field, the book differs from other literature available by providing a detailed, in-depth discussion of the characteristics of these materials. The use of biomass for technological applications is a rapidly growing area in materials engineering and green bioprocesses. In this approach, pre-treatments focus on the bioavailability of nutrients and facilitate the use of biomass for delivering byproducts (e.g. enzymes) and for bioenergy production, both of which are discussed at length in this book. In this regard, it explores various aspects of the structural complexity of residual biomass produced by agricultural, industrial and livestock activities for biotechnological purposes, and assesses both conventional and emerging pre-treatments (e.g. biological, enzymatic and physical-chemical). This book reveals the advantages of these techniques, both individually and in combination, making it an excellent resource for all readers interested in cutting-edge applications of biomass.

Organic and Inorganic Fluorine Chemistry provides an introduction to fluorine chemistry and an overview of the most important fluorinated compounds and general preparation techniques. The book is divided into three parts, covering general aspects, inorganic fluorides and fluoroorganic compounds. The inorganic part presents the most important element fluorides and oxyfluorides, their preparation as well as their most characteristic properties. The organic section focuses on the different types of fluorination and the corresponding reagents. The application of these techniques is discussed for many different types of substrates. The book addresses advanced students in chemistry as well as researchers in academia and industry. The readers will benefit from a large number of original references which give access to further information. In addition, study questions at the end of each chapter will help to repeat and internalise the most important aspects.

This textbook presents a modern treatment of fundamentals of heat and mass transfer in the context of all types of multiphase flows with possibility of phase-changes among solid, liquid and vapor. It serves equally as a textbook for undergraduate senior and graduate students in a wide variety of engineering disciplines including mechanical engineering, chemical engineering, material science and engineering, nuclear engineering, biomedical engineering, and environmental engineering. Multiphase Heat Transfer and Flow can also be used to teach contemporary and novel applications of heat and mass transfer. Concepts are reinforced with numerous examples and end-of-chapter problems. A solutions manual and PowerPoint presentation are available to instructors. While the book is designed for students, it is also very useful for practicing engineers working in technical areas related to both macro- and micro-scale systems that emphasize multiphase, multicomponent, and non-conventional geometries with coupled heat and mass transfer and phase change, with the possibility of full numerical simulation.

This book includes the best papers from two conferences on machining and abrasive machining, organized in Poland on September 11-12, 2019. The chapters discuss classical topics and emerging methods and models in machining, measurement, and quality control. They cover new technologies, such as water jet machining, discuss important topics such as energy efficiency in machining, and analyze different cutting methods, materials and mechanisms.

Separation processes on an industrial scale account for well over half of the capital and operating costs in the chemical industry. Knowledge of these processes is key for every student of chemical or process engineering. This book is ideally suited to university teaching, thanks to its wealth of exercises and solutions. The second edition boasts an even greater number of applied examples and case studies as well as references for further reading.

This book presents the aspects of cellulose obtained in correlation with its integration into the new concept of biorefining. The authors detail the individual steps of pulp manufacture as well as properties and fiber characterization techniques for paper, cellulose derivatives and processing by-products. This book is of interest to scientists and advanced students working in the fields of renewable resources and biorefining.