Since the third edition of this reference was completed, there have been major changes in the global chemical industry. With less emphasis on new processes for making basic chemicals and more emphasis on pollution prevention and waste disposal, petrochemical processes are giving way to biochemical processes. These changes are reflected in the new processes being developed, many of which have their own names. In addition, niche improvements are still being made in petrochemistry, and some of these processes have new names as well. Gathering and defining a large portion of special named processes that may fall outside standard chemical texts or be scattered among industry manuals, Encyclopedic Dictionary of Named Processes in Chemical Technology, Fourth Edition provides a single-source reference on an extensive array of named processes. It provides concise descriptions of those processes in chemical technology that are known by special names that are not self-explanatory. While overviews of the chemical technology industry are present in other books, most of the names defined within this volume are unique to this compilation. This reference includes named processes in current commercial use around the world, processes that have been or are being piloted on a substantial scale, and even obsolete processes that have been important in the past. The length of the dictionary entries reflects their importance and topicality. The text includes references that document the origins of the processes and review the latest developments. Written by a highly experienced and respected author, this user-friendly text is presented in a practical dictionary format that is useful for a broad audience including industrial chemists and engineers.

Over the past several decades, the theme of supramolecular chemistry (SC) has permeated nearly all aspects of chemical endeavor. Not surprisingly, it has also pervaded the field of solvent extraction (SX), inspiring the framework for this volume of Ion Exchange and Solvent Extraction. In addition, tools for studying aggregation have grown increasingly sophisticated, leading to a greater understanding of what we now recognize as SC phenomena in SX. Volume 21, Supramolecular Aspects of Solvent Extraction identifies how supramolecular behavior occurs and is studied in the context of SX and how SC is influencing the direction of SX.
With contributions by internationally recognized specialists from different fields, this volume examines how principles of SC are being used in advancing the design of new highly selective SX systems and for understanding aggregation phenomena in SX systems. The book begins with a discussion of the nature and definition of SC and its general use in the design of novel SX reagents. Chapter 2 expands the subject of ion-pair recognition to introduce outer-sphere recognition of metal complexes.
Chapter 3 reviews the literature on calixarenes as extraction reagents for metal ions. Chapter 4 extends the utility of this chemistry, describing the use of calixarenes for the extraction of biomolecules. Chapter 5 examines the liquid liquid interface as an expression of supramolecular phenomena in SX, reviewing interfacial aggregation in model two-phase systems and metal extraction systems. The final chapter explores the problem of aggregation in SX, the historical attempts to understand it, and recent progress that has been made in addressing the issue.

The recently published book by the author, "Engineering Heat Transfer," already dealt with exact computation of heat exchangers and tube banks. In design c- putationthisisaccomplishedviacorrectivefactors;thelattermakesitpossibleto compute the actual mean temperature difference by starting from the logarithmic onerelativeto?uidsinparallel?oworcounter?ow. As far as veri?cation computation is concerned, corrective factors were int- ducedtocomputeacertaincharacteristicfactorcorrectly, asisfundamentalforthis typeofcomputation. Basedontheabove, theauthordecidedtoinvestigatefurther, re?ne, andwiden thistopic: theoutcomeofthisworkhasresultedinthishandbook. Newtypesofexchangerswereexamined;thecalculationwasre?nedtoproduce practicallyexactvaluesforthefactors. Thescopeoftheinvestigationwasincreased by widening the range of the starting factors. Furthermore, a greater number of valuestobeincludedinthetableswasconsidered. Finally, afewcharacteristicsof certainvaluesofthecorrectivefactorswerehighlighted. The?rstsectionisanintroduction;itsummarizesthefundamentalcriteriaofheat transferandproceedstoillustratethebehaviorof?uidsinbothparallelandcounter ?ow. Italsoshowshowtocomputethemeanisobaricspeci?cheatforsome?uids; itillustratesthesigni?canceofdesigncomputationandveri?cationcomputation. In addition, itillustrateshowtoproceedwithheatexchangersandtubebankstocarry outbothdesignandveri?cationcomputationcorrectly. AppendixAthenincludes36tablesasareferencefordesigncomputation, The tablescontainthecorrectivefactorsrequiredtoobtaintheactualmeantemperature differencebystartingfromthemeanlogarithmictemperaturedifferencerelativeto ?uidsinparallel?oworcounter?ow. Finally, Appendix B includes 35 tables for veri?cation computation. As far as heatexchangers areconcerned, itshowsthevaluesoffactor ? whichisrequired forthistypeofcomputation. Thevaluesofthecorrectivefactorsforcoilsandtube banksarealsopresented. Milano, Italy DonatelloAnnaratone v Notation c=speci?cheat(J/kgK) d=diameter(m) E=ef?ciencyfactor h=enthalpy(kJ/kg) k=thermalconductivity(W/mK) M=mass?owrate(kg/s) m=massmoisturepercentage(%) q=heatpertimeunit(W) 2 S=surface(m ) ? t=temperature( C) 2 U=overallheattransfercoef?cient(W/m K) x=thickness(m) 2 ? =heattransfercoef?cient(W/m K) ? =characteristicfactor ? =characteristicfactor ? =ef?ciency ? =correctivefactor ? =correctivefactor ? =characteristicfactor ? ?t=temperaturedifference( C) vii viii Notation Superscripts =heating?uid =heated?uid Subscripts c=counter?ow e=exchanger i=inside l=logarithmic m=mean o=outside p=constantpressure(isobaric), parallel?ow w=wall 1=inlet(forheatingorheated?uid) 2=outlet(forheatingorheated?uid) Contents 1 Introduction to Computation . . . . . . . . . . . . . . . . . . . . . 1 1. 1 GeneralConsiderations . . . . . . . . . . . . . . . . . . . . . . 1 1. 2 MeanIsobaricSpeci?cHeat . . . . . . . . . . . . . . . . . . . . 3 1. 2. 1 WaterandSuperheatedSteam . . . . . . . . . . . . . . . 4 1. 2. 2 AirandOtherGases. . . . . . . . . . . . . . . . . . . . 4 2 Design Computation. . . . . . . . . . . . . . . . . . . . . . . . . . 7 2. 1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 2. 2 FluidsinParallelFloworinCounterFlow . . . . . . . . . . . . 8 2. 3 TheMeanDifferenceinTemperatureinReality . . . . . . . . . 12 2. 3. 1 FluidsinCrossFlow. . . . . . . . . . . . . . . . . . . . 14 2. 3. 2 HeatExchangers. . . . . . . . . . . . . . . . . . . . . . 15 2. 3. 3 Coils. . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 2. 3. 4 TubeBankswithVariousPassagesoftheExternalFluid . 21

This volume contains ?ve chapters. The topics covered are the cathodic reduction of nitrate, for which the key issues are pr- uct selectivity and current ef?ciency; a discussion of ionic l- uids known as molten or fused salts in key industrial processes; the properties of nanowires made of metals and semiconductors by means of electrodeposition into porous templates and template synthesis; and an overview of a range of alloys used in elect- plating, and trends in ammonium electrolysis. Also, included is a review of the applications of synchroton x-ray scattering to the electrochemical interphase. Chapter 1 by Celia Milhano and Derek Pletcher reviews the cathodic reduction of nitrate as a "truly fascinating reaction" since processes for nitrate removal from drinking water and effluents and reducing nitrates in nuclear waste is an essential step in n- lear waste disposal. The authors also review electrochemical membrane technology not involving the cathodic reduction of - trate. In Chapter 2, the authors discuss substances called ionic l- uids, and the fact that this is really a new more modern term for molten or fused salts. However, the label of ionic liquids is usu- ly applied to the liquid state of salts at or near room temperature, which is a way to differentiate low-melting salts from higher me- ing cousins. These molten or fused salts form the basis of several key industrial processes, and this chapter is primarily devoted to the non-haloaluminate ionic liquids as reviewed by Tetsuya Tsuda and Charles L. Hussey.

Strong theoretical and practical knowledge of process control is essential for plant practicing engineers and operators. In addition being able to use control hardware and software appropriately, engineers must be able to select or write computer programs that interface the hardware and software required to run a plant effectively. Designed to help readers understand control software and strategies that mimic human activities, Fundamentals of Automatic Process Control provides an integrated introduction to the hardware and software of automatic control systems.

Featured Topics

• Basic instruments, control systems, and symbolic representations
• Laplacian mathematics for applications in control systems
• Various disturbances and their effects on uncontrolled processes
• Feedback control loops and traditional PID controllers
• Laplacian analysis of control loops
• Tuning methods for PID controllers
• Advanced control systems
• Virtual laboratory software (included on CD-ROM)

Modern plants require operators and engineers to have thorough knowledge of instrumentation hardware as well as good operating skills. This book explores the theoretical analysis of the process dynamics and control via a large number of problems and solutions spread throughout the text. This balanced presentation, coupled with coverage of traditional and advanced systems provides an understanding of industrial realities that prepares readers for the future evolution of industrial operations.

Providing comprehensive discussions of the physical and chemical properties, manufacture, and industrial uses of biosurfactants, this reference offers first-hand accounts of biosurfactant research of leading biotechnology laboratories. It introduces promising possible uses of biosurfactants in medicine, in environmental control, and for marine organisms. In contributions of more than 30 leading international experts, the text reviews the biosynthetic mechanisms for surfactants and their precursor molecules; explicates the biophysics of microbial surfactants and examines the production of immobilized biocatalysts, lipopeptides, and rhamnolipids. It also presents information on the economics of biosurfactants.

Designed for undergraduates, graduate students, and industry practitioners, Bioseparations Science and Engineering fills a critical need in the field of bioseparations. Current, comprehensive, and concise, it covers bioseparations unit operations in unprecedented depth. In each of the chapters, the authors use a consistent method of explaining unit operations, starting with a qualitative description noting the significance and general application of the unit operation. They then illustrate the scientific application of the operation, develop the required mathematical theory, and finally, describe the applications of the theory in engineering practice, with an emphasis on design and scaleup. Unique to this text is a chapter dedicated to bioseparations process design and economics, in which a process simular, SuperPro Designer (R) is used to analyze and evaluate the production of three important biological products. New to this second edition are updated discussions of moment analysis, computer simulation, membrane chromatography, and evaporation, among others, as well as revised problem sets. Unique features include basic information about bioproducts and engineering analysis and a chapter with bioseparations laboratory exercises. Bioseparations Science and Engineering is ideal for students and professionals working in or studying bioseparations, and is the premier text in the field.

This book explains the aspiring vision of a sustainable hydrogen generating system which employs nanotechnology one way or the other and presents a detailed update on research activities, achievements and challenges. It explores how nanotechnology is reshaping science in general and how this can be applied to the generation and storage of hydrogen energy. This book begins by highlighting the importance of hydrogen a source of sustainable energy and its impact on the technical advances of fuel cells, internal combustion engines, batteries and power plants. The book depicts the role of nanotechnology in the development of sustainable hydrogen. Comprehensive studies on various nanotechnologies involved in hydrogen generation are discussed in separate chapters, representing a complete picture of hydrogen generation utilizing nanotechnology. This book serves as a useful research tool for academics and practitioners looking towards new ways to develop and consume energy, without conceding our environment. Providing the advantages and disadvantages of each technology discussed, this book shows the benefits of utilizing nanotechnology in this field.

Momentum Press is proud to bring to you Chemical Sensors: Simulation and Modeling Volume 4: Optical Sensors, edited by Ghenadii Korotcenkov. This is the fourth of a new multi-volume comprehensive reference work that provides computer simulation and modeling techniques in various fields of chemical sensing and the important applications for chemical sensing such as bulk and surface diffusion, adsorption, surface reactions, sintering, conductivity, mass transport, and interphase interactions. In this fourth volume, you will find background and guidance on: Approaches used for modeling and simulation of various types of optical sensors such as fiber optic, surface plasmon resonance, Fabry-Perot interferometers, transmittance in the midinfrared region, luminescence-based devices, and more Approaches used for design and optimization of optical systems aimed for both remote gas sensing and gas analysis chambers for the nondispersive infrared (NDIR) spectral range Multiscale atomistic simulation of hierarchical nanostructured materials for optical chemical sensing Chemical sensors are integral to the automation of myriad industrial processes and everyday monitoring of such activities as public safety, engine performance, medical therapeutics, and many more. This multi-volume reference work covering simulation and modeling will serve as the perfect complement to Momentum Press's 6-volume reference work, Chemical Sensors: Fundamentals of Sensing Materials and Chemical Sensors: Comprehensive Sensor Technologies, which present detailed information related to materials, technologies, construction, and application of various devices for chemical sensing. Each simulation and modeling volume in the present series reviews modeling principles and approaches peculiar to specific groups of materials and devices applied for chemical sensing.

An overview of fundamental principles, novel application areas of biotechnology and its impact on international economy. Recent developments in the field of biotechnology are covered with the help of short papers and poster abstracts. Thus, relationships between fundamental principles and applications have been defined, while current research in the field as well as future needs and prospects are presented. The book encompasses the whole spectrum of biotechnology, emphasizing both scientific and commercial aspects of new developments and how they can meet the challenges of industry. The book gives a perspective on the current state of biotechnology research throughout the world with the help of contributors from 15 different countries. It is designed to serve as a reference book for both academics and industrialists, indicating new starting points to young researchers for new projects in the field.

This book gives the definitive mathematical answer to what thermodynamics really is: a variational calculus applied to probability distributions. Extending Gibbs's notion of ensemble, the Author imagines the ensemble of all possible probability distributions and assigns probabilities to them by selection rules that are fairly general. The calculus of the most probable distribution in the ensemble produces the entire network of mathematical relationships we recognize as thermodynamics. The first part of the book develops the theory for discrete and continuous distributions while the second part applies this thermodynamic calculus to problems in population balance theory and shows how the emergence of a giant component in aggregation, and the shattering transition in fragmentation may be treated as formal phase transitions. While the book is intended as a research monograph, the material is self-contained and the style sufficiently tutorial to be accessible for self-paced study by an advanced graduate student in such fields as physics, chemistry, and engineering.

This book outlines the physical and chemical foundations of high-temperature processes for producing silicon, manganese and chromium ferroalloys, alloys of molybdenum, vanadium, titanium, alkaline earth and rare earth metals, niobium, zirconium, aluminum, boron, nickel, cobalt, phosphorus, selenium and tellurium, iron-carbon alloys by carbon, silicone and aluminothermic methods. The chapters introduce the industrial production technologies of these groups of ferroalloys, the characteristics of charge materials, and the technological parameters of the melting processes. A description of ferroalloy furnaces is given in detail. Topics such as waste recycling, fines agglomeration technologies, and environmental issues are considered.

Compiling recent advances in membrane separations technology, this highly relevant book introduces cost-effective solutions for separation problems in a wide range of industries. It discusses membrane use in oil, petrochemicals, and fossil fuels; natural gas exploration; bioseparation; water purification and wastewater treatment; and chemical manufacturing. It describes the role of membrane technologies in resource recovery, pollution prevention, and energy production, as well as environmental monitoring and quality control. A concise resource for emerging technologies, this book provides the tools to implement effective production processes, improve environmental protection and public health, and explore new opportunities for sustainable growth.

Applications, Processes, and Controls is the second volume in the Handbook for Critical Cleaning, Second Edition. Should you clean your product during manufacturing? If so, when and how? Cleaning is essential for proper performance, optimal quality, and increased sales. Inadequate cleaning of product elements can lead to catastrophic failure of the entire system and serious hazards to individuals and the general public. Gain a competitive edge with proven cleaning and contamination-control strategies A decade after the bestselling original, the Handbook for Critical Cleaning, Second Edition helps manufacturers meet today's challenges, providing practical information and perspective about cleaning chemistries, equipment, processes, and applications. With 90% new or revised chapters plus supplementary online material, the handbook has grown into two comprehensive volumes: Cleaning Agents and Systems, and Applications, Processes, and Controls. Helping manufacturers become more efficient and productive, these books: Show how to increase profitability and meet both existing and expected product demand Clarify the sea of print and Internet information about cleaning chemistries and techniques Address challenges of performance, miniaturization, and cost, as well as regulatory and supply chain pressures Offer clearly written guidance from the viewpoints of more than 70 leading industry contributors in technical, management, academic, and regulatory disciplines Overview chapters by the editors, industry icons Barbara and Ed Kanegsberg, meld the different viewpoints and compile and critique the options. The result is a complete, cohesive, balanced perspective that helps manufacturers better select, implement, and maintain a quality, value-added cleaning process. The second volume, Handbook for Critical Cleaning: Applications, Processes, and Controls, addresses how to implement, validate, monitor, and maintain a critical cleaning process. Topics include cleanrooms, materials compatibility, worker safety, sustainability, and environmental constraints. The book shows readers how to draw from diverse disciplines-including aerospace, art conservation, electronics, food, life sciences, military, optics, and semiconductors-to achieve superior productivity.

The idea of this book is to present the up-to-date research results on Nitrate Esters as explosive materials. It covers many aspects including the material structures, nitrating agent, chemical synthesis devices, preparation technology, and applications etc. In particular, this work sheds light on the comprehensive utilization and thorough destruction of the used Nitrate Easters which is crucial for preventing repeated pollution. This is a highly informative and instructive book providing insight for the researchers working on nitrating theory, energetic materials and chemical equipments.

This immensely practical guide to PIV provides a condensed, yet exhaustive guide to most of the information needed for experiments employing the technique. This second edition has updated chapters on the principles and extra information on microscopic, high-speed and three component measurements as well as a description of advanced evaluation techniques. What's more, the huge increase in the range of possible applications has been taken into account as the chapter describing these applications of the PIV technique has been expanded.

New and Future Developments in Microbial Biotechnology and Bioengineering: Recent Advances in Application of Fungi and Fungal Metabolites: Biotechnological Interventions and Futuristic Approaches is an invaluable resource for researchers planning to work in applied biotechnological interventions and futuristic approaches to fungi and fungal metabolite utilization. Special emphasis is placed on new research relating to fungal-based recombinant DNA technology and genomics analysis which place yeasts and filamentous fungi at the forefront of various contemporary commercial applications. Written in an easy-to-follow language by active researchers, the book presents cutting-edge fungal biotechnological applications in a manner that is accessible to all.

Recent Developments in Bioenergy Research reviews all these topics, reports recent research findings, and presents potential solutions to challenging issues. The book consolidates the most recent research on the (bio)technologies, concepts and commercial developments that are currently in progress on different types of widely-used biofuels and integrated biorefineries across biochemistry, biotechnology, biochemical engineering and microbiology. Chapters include very recent/emerging topics, such as non-ionic and ionic liquids/surfactants for enhancement of lignocellulose enzymatic hydrolysis and lignocellulose biomass as a rich source of bio-ionic liquids. The book is a useful source of information for those working in the area of- industrial wastewater treatment and microbial fuel cells, but is also a great resource for senior undergraduate and graduate students, researchers, professionals, biochemical engineers and other interested individuals/groups working in the field of biofuel/bioenergy.

New and Future Developments in Microbial Biotechnology and Bioengineering: Recent Advances in Application of Fungi and Fungal Metabolites: Environmental and Industrial Aspects provides a comprehensive overview of recent development and applied aspects of fungi and its metabolites in environmental and industrial settings. Fungi and fungal metabolites have great prospects for developing new products in a wide range of sectors. Many fungal metabolites are environmentally friendly, clean, non-toxic agents used for environmental management practices. This book offers a systems approach and provides a means to share the latest developments and advances about the exploitation of fungal products, including their vide uses in the field of environment and industry.

The purpose of this volume is to provide a brief review of the previous work on model reduction and identifi cation of distributed parameter systems (DPS), and develop new spatio-temporal models and their relevant identifi cation approaches.

In this book, a systematic overview and classifi cation on the modeling of DPS is presented fi rst, which includes model reduction, parameter estimation and system identifi cation. Next, a class of block-oriented nonlinear systems in traditional lumped parameter systems (LPS) is extended to DPS, which results in the spatio-temporal Wiener and Hammerstein systems and their identifi cation methods. Then, the traditional Volterra model is extended to DPS, which results in the spatio-temporal Volterra model and its identification algorithm. All these methods are based on linear time/space separation. Sometimes, the nonlinear time/space separation can play a better role in modeling of very complex processes.

Thus, a nonlinear time/space separation based neural modeling is also presented for a class of DPS with more complicated dynamics. Finally, all these modeling approaches are successfully applied to industrial thermal processes, including a catalytic rod, a packed-bed reactor and a snap curing oven. The work is presented giving a unifi ed view from time/space separation. The book also illustrates applications to thermal processes in the electronics packaging and chemical industry. This volume assumes a basic knowledge about distributed parameter systems, system modeling and identifi cation. It is intended for researchers, graduate students and engineers interested in distributed parameter systems, nonlinear systems, and process modeling and control.

Environmentally Degradable Materials (EDPs) should replace petroleum-based plastics where recycling is not viable for logistic or labor cost reason. This book discusses the general background of obtaining such systems, compatibilization methodologies, control of the rate of degradation and final products after degradation, life time assessment, toxicological aspects, applications and market aspects. This book is a complete guide to the subject of biodegradable materials based on multi-component polymeric systems, mainly such as hydrogels, and interpenetrating polymeric networks. This book is a complete guide to the subject of biodegradable materials based on multicomponent polymeric systems such as mainly hydrogels, interpenetrating polymeric networks.

Surface and colloid chemistry principles impact many aspects of our daily lives, ranging from the cleaners and cosmetics we use to combustion engines and cement. Exploring the range of this field of study, Surface and Colloid Chemistry provides a detailed analysis of its principles and applications and demonstrates how they relate to natural phenomena and industrial processes.

Surface and colloid chemistry at work in nature and industry:

• rain drops
• combustion engines
• soap bubbles
• foam
• food products
• air pollution
• waste-water treatment
• washing and cleaning
• cosmetics
• painting and printing
• oil and gas production
• oil spills
• plastics and polymers
• biology and pharmaceuticals
• milk products
• cement
• adhesive
• coal

The book begins with an introduction to surfaces and colloids. It describes basic considerations regarding liquids and capillarity, and examines the liquid-solid interface phenomena. It explores the physicochemical properties of surfactants, Langmuir-Blodgett films, adsorption on solid surfaces, and adsorption as it relates to cleaning processes. Then the author examines colloidal systems and thin liquid films before moving on to emulsion science and technology. The final chapter provides examples of applications in science and a range of industries.

Examples and Illustrations

Integrating real-world examples throughout the text, this volume stimulates readers to consider both fundamental theory and industrial applications. More than 100 figures elucidate the concepts described in the text. Sample questions and answers are provided where appropriate, along with detailed data and discussions. Pertinent references are offered to facilitate further study.

Touted as the new darling of the chemical industry, alkyl polyglycosides are gaining in popularity due to the fact that they are readily biodegradable, low-toxic, and made from renewable resources. Sugar-Based Surfactants compiles the most recent and relevant aspects of sugar-based surfactants, including self-association, phase behavior, and interfacial properties. Focusing on both colloidal and interfacial science, the book deals with the adsorption of surfactants in both the air-liquid and solid-liquid interfaces. It also covers new advances in surfactant science, such as the development of a family of potent surface active agents that are non-toxic, and thus usable in ubiquitous consumer products

This book covers different aspects of gas injection, from the classic pressure maintenance operation to enhanced oil recovery (EOR), underground gas storage (UGS), and carbon capture and storage (CCS). The authors detail the unique characteristics and specific criteria of each application, including: material balance equations phase behaviour reservoir engineering well design operating aspects surface facilities environmental issues Examples, data, and simulation codes are provided to enable the reader to gain an in-depth understanding of these applications. Fundamentals and Practical Aspects of Gas Injection will be of use to practising engineers in the fields of reservoir engineering, and enhanced oil recovery. It will also be of interest to researchers, academics, and graduate students working in the field of petroleum engineering.

Presenting the end-use and application technologies of pressure-sensitive adhesives and products, Volume Three of the "Handbook of Pressure-Sensitive Adhesives and Products" discusses the build up and classes of pressure-sensitive products, the main representatives of pressure-sensitive products, and their application domains. It divides the main product classes of solvent-based, water-based, and hot-melt-based formulations by their debonding characteristics and water and temperature resistance, and illustrates build-up by adhesive-coated, adhesiveless, carrierless, and linerless pressure-sensitive products. It presents application technology, equipment, and novel products such as RFID, medical, and labels, as well as the self-adhesive competitors of pressure-sensitive products. It also lists professional organizations and suppliers, along with the main literature sources.