Surface thermodynamics forms the foundation of any meaningful study of capillarity and wetting phenomena. The second edition of Applied Surface Thermodynamics offers a comprehensive state-of-the-art treatment of this critical topic. It provides students and researchers with fundamental knowledge and practical guidelines in solving real-world problems related to the measurement and interpretation of interfacial properties.

Containing 40 percent new material and reorganized content, this second edition begins by presenting a generalized Gibbs theory of capillarity, including discussions of highly curved interfaces. Concentrating on drop-shape techniques, the book discusses liquid-fluid interfacial tension and its measurement. Next, the authors focus on contact angles with chapters on experimental procedures, thermodynamic models, and the interpretation of contact angles in terms of solid surface tension. The book discusses theoretical approaches to determining solid surface tension as well as interfacial tensions of particles and their manifestations. It concludes by discussing drop size dependence of contact angles and line tension.

What's New in the Second Edition:

• Recent progress in Axisymmetric Drop Shape Analysis (ADSA)
• Image processing methods for drop shape analysis
• Advanced applications and generalizations of ADSA
• Recent studies of contact angle hysteresis
• Contact angles on inert fluoropolymers
• Update on line tension and the drop size dependence of contact angles

Exploring a range of different aspects of surface science and its applications, the book logically progresses so that knowledge of previous chapters enhances the understanding of subsequent material, yet each chapter is freestanding so that experienced researchers can quickly refer to topics of particular interest.

The "greening" of industry processes, i.e. making them more sustainable, is a popular and often lucrative trend which has emerged over recent years. The 3rd volume of Green Chemical Processing considers sustainable chemistry in the context of corporate interests. The American Chemical Society's 12 Principles of Green Chemistry are woven throughout this text as well as the series to which this book belongs.

Shorter reaction times, higher product yields, and enhanced selectivity are some of the advantages microwave heating has over conventional methods, causing its use to transition from a curiosity to mainstream, both in industrial and academic settings. Microwave Heating as a Tool for Sustainable Chemistry showcases the application of microwave heating in a number of areas of preparative chemistry as well as in the biosciences.

From organic chemistry to materials and biological applications

The book begins with an introduction to microwave heating, the physical concepts behind it, its application in synthetic chemistry, and commercially available microwave equipment. It shows how microwave heating can be used to facilitate the clean and sustainable synthesis of organic compounds. The authors examine microwave heating as a tool for sustainable polymer chemistry, with discussions of the use of alternative solvents and feedstocks, the design of degradable polymeric materials, and recycling polymers. They then discuss the significant contribution made by microwave-promoted synthesis in the drug discovery process, with a focus on how the technology has been used to generate discovery chemistry libraries and as a tool for medicinal chemists. Other topics examined in this application-driven text include the use of microwave heating in the preparation of inorganic and organometallic compounds, in the production of inorganic materials, and in the area of biosciences.

Academic and industrial settings

The book examines the scale-up of microwave-promoted chemistry and describes the various approaches and the current commercially available microwave reactors available for scale-up. It also discusses microwave heating as a tool for teaching in the undergraduate organic chemistry laboratory. It explores curriculum, the broad range of reactions that can be performed, and the incorporation of green chemistry principles.

The author maintains a website with supplemental information.

This book contains a selection of revised and extended research articles written by prominent researchers participating in the 27th World Congress on Engineering and Computer Science (WCECS 2019) which was held in San Francisco, USA, on October 22-24, 2019. Topics covered include engineering mathematics, electrical engineering, communications systems, computer science, chemical engineering, systems engineering, manufacturing engineering, and industrial applications. With contributions carefully chosen to represent the most cutting-edge research presented during the conference, the book contains some of the state-of-the-art in engineering technologies and the physical sciences and their applications and serves as a useful reference for researchers and graduate students working in these fields.

How far will an ounce of prevention really go? While the answer to that question may never be truly known, Process Plants: A Handbook for Inherently Safer Design, Second Edition takes us several steps closer. The book demonstrates not just the importance of prevention, but the importance of designing with prevention in mind. It emphasizes the role of inherent safety in process safety management systems and in ensuring an appropriate process safety culture. Keeping the easy to understand style that made the first edition so popular, this book clearly delineates practical, everyday issues and complex technical ones.

The second edition provides:

• Coverage of new inherent safety metrics and how to measure the degree or level of inherent safety
• New examples of application of the various principles of inherently safer design and 20 new figures
• New emphasis on the role of inherently safer design in process safety management systems and in ensuring an appropriate process safety culture
• Discussion of dust explosion risk reduction by means of inherently safer approaches
• New chapter on case study development, providing a comprehensive approach to the prevention and mitigation of process incidents by timely incorporation of inherently safer design

This updated version of a classic text examines how to incorporate inherently safer design into process industry activities, revising and updating information based on recent research and developments. A how-to resource at its core, the book includes numerous examples that illustrate the principles of inherently safer design and how to apply them in practice. It explains how to measure the inherent safeness of a process, referencing metric tools that have been developed during the past decade and the tried and true methods that have become industry stand bys.

The goal of this book is to show the high potential of chiral sulfur-containing ligands to promote numerous asymmetric catalytic transformations. The important number of reports appeared in the literature over the last 35 years often highlighted spectacular results in terms of efficiency and enantioselectivity, allowing access to many biologically important molecules, which clearly demonstrates that these ligands can now be recognised as real competitors to the more usual phosphorus- or nitrogen-containing ligands. A key point of reference for post-graduate students, researchers and academics.

Rising oil costs have stimulated significant interest in the Fischer-Tropsch synthesis (FTS) as a method for producing a synthetic petroleum substitute. Drawn from the proceedings at a symposium held during the 236th meeting of the American Chemical Society in Philadelphia in August 2008, Advances in Fischer-Tropsch Synthesis, Catalysts, and Catalysis explores the recent developments in Fischer-Tropsch technology, which holds great promise in the area of renewable resources. Expert contributors explore a range of issues The book focuses on three main themes: catalyst preparation and activation, reaction mechanism, and process-related topics. A panel of expert contributors discusses synthesis of catalysts, carbon nanomaterials, nitric oxide calcinations, the influence of carbon, catalytic performance issues, chelating agents, and Cu and alkali promoters. They also explore Co/silica catalysts, thermodynamic control, the Two Alpha model, co-feeding experiments, internal diffusion limitations, Fe-LTFT selectivity, and the effect of co-fed water. Lastly, the book examines cross-flow filtration, kinetic studies, reduction of CO2 emissions, syncrude, and low-temperature water-gas shift. Attaining the maximum catalytic activity and catalyst life The themes explored in the book demonstrate that while the Fischer-Tropsch synthesis (FTS) has advanced in maturity, many issues remain concerning the preparation of increasingly active catalysts and the method of activation to attain the maximum catalytic activity and catalyst life. The book includes coverage of the structural features, their changes, and the application of increasingly sophisticated characterization techniques, shedding light on the reaction mechanism and providing a glimpse into the processes and reaction rates under realistic commercial process conditions.

This book highlights current efforts and research into achieving campus sustainability. The book start with Introduction followed by two chapters discusses best governance and practices in enhancing campus sustainability, while subsequent chapters elaborate on green building and bioenergy. In addition, the book discusses several initiatives regarding campus waste management including sewage recycling potential.

Despite the fact that crystals make up an estimated 80% of chemical and pharmaceutical products, few resources exist that provide practical guidance on achieving precision control of their size and size distribution. Based on a model developed by the author and his colleagues, Precision Crystallization: Theory and Practice of Controlling Crystal Size presents scientists and product engineers with the tools to control crystal nucleation, enabling them to ultimately control crystal size and size distribution for batch and continuous crystallizations.

At the cutting edge of crystallization science and technology, this volume presents information never before available. Introducing the Balanced Nucleation and Growth (BNG) model, the book demonstrates how the results of the nucleation process are quantitatively related to practical experimental control values such as:

• reaction addition rate
• crystal solubility
• temperature
• residence time (continuous crystallizations)
• the effect of ripening agents (crystal supersizing) during nucleation
• the effect of crystal growth restrainers (crystal nanosizing) during nucleation
• control of renucleation

The author shows how the BNG theory predicts previously unknown phenomena and also how it corrects erroneous perceptions of the importance of reaction volume on the outcome of crystal nucleation. Going above and beyond classical nucleation theories which rely to a large extent on guesswork, the BNG model gives precise guidance to scientists working in a range of critical areas, leading to promising implications for research, quality control, product development, production processes, pilot plant operations, and manufacturing.

By and large, the debate about the merits of including higher education services within free trade policies has occurred outside of the United States, even though the U.S. Office of the Trade Representative has specifically included higher education services in its March 2003 negotiating offer to the General Agreement on Trade in Services (GATS). This book emerged from research and conversations on the potential implications of free trade on American higher education, implications which have yet to lead to any real conversation or debate within the broad higher education community in the United States. It fills a niche in the literature on trade and higher education services by providing context and analysis of the trade issue in the American higher education context, as well as the pros and cons of free trade in higher education services from the perspectives of the U.S.-based actors.

The 20th century has seen a phenomenal growth in the global economy and continuous improvement in the standard of living in the industrialized countries. Sustainable development has become an ideal target in recent years and in the early 1990s the concept of "Green chemistry" was launched in the USA as a new paradigm, and since 1993 it has been promoted by the National Science Foundation (NSF) and the Environmental Protection Agency (EPA). The success of the pharmaceutical industry is, in large part, due to the towering achievement of organic chemistry, a mature science which emerged as a distinct discipline well over 150 years ago, however this has been both a blessing and a curse. Many of our most reliable strategies for assembling target molecules employ reactions which are fifty to one hundred years old and are often named in honour of their discoverers. During these early years, the chronic toxicological properties of chemicals were often completely unknown and many unwittingly became indispensable tools of the trade. Early pioneers in green chemistry included Trost (who developed the atom economy principle) and Sheldon (who developed the E-Factor). These measures were introduced to encourage the use of more sustainable chemistry and provide some benchmarking data to encourage scientists to aspire to more benign synthesis. Green chemistry is essentially the design of chemical processes and procedures that reduce or eliminate the use, or the generation, of hazardous substances. Green chemistry is a growing area of research and an increasing number of researchers are now involved in this field. The number of publications has dramatically increased and new recognition of advances made is necessary with respect to other research areas. The synthesis of "Fine Chemicals" represents one of the main goals in organic synthesis and this new book extensively examines the main processes and procedures for their preparation under eco-friendly conditions.

The book is a collection of selected research topics delivered by scientists involved in some of the more prominent fields of green chemistry. It is devoted to the synthesis of fine chemicals by the use of alternative eco-friendly solvents (ionic liquids, polyethylene glycol, water, etc.), supported organic catalysis, microwave irradiation or high pressure as contributors to more efficient processes, photochemistry as a green procedure and solvent-free processes. Each chapter gives an introduction to the various methods or procedures and their contribution to green chemistry and a variety of the most representative examples of the eco-friendly synthesis of fine chemicals are reported and discussed. In addition, there is a chapter dedicated to the application of simple reaction to the synthesis of complex molecules.The chapters are all written by authors who are experts in their field and are exhaustively referenced and the book will be invaluable for researchers and industrialists as well as academia.

Although computer technology has dramatically improved the analysis of complex transport phenomena, the methodology has yet to be effectively integrated into engineering curricula. The huge volume of literature associated with the wide variety of transport processes cannot be appreciated or mastered without using innovative tools to allow comprehension and study of these processes. Connecting basic principles with numerical methodology for solving the conservations laws, Computational Transport Phenomena for Engineering Analyses presents the topic in terms of modern engineering analysis. The book includes a production quality computer source code for expediting and illustrating analyses of mass, momentum, and energy transport.

The text covers transport phenomena with examples that extend from basic empirical analyses to complete numerical analyses. It includes a computational transport phenomena (CTP) code written in Fortran and developed and owned by the authors. The code does not require a lease and can run on a PC or a supercomputer. The authors also supply the source code, allowing users to modify the code to serve their particular needs, once they are familiar with the code. Using the CTP code, grid generation and solution procedures are described and visual solution presentations are illustrated thus offering extensive coverage of the methodology for a wide range of applications.

The authors illustrate and emphasize that the very general solutions afforded by solving the unsteady, multidimensional transport equations for real multicomponent fluids describe an immense body of physical processes. Bringing together a wealth of professional and instructional experience, this book stresses a problem-solving approach that uses one set of computational and graphical tools to describe all aspects of the analysis. It provides understanding of the principles involved so that code improvements and/or use of commercial codes can be accomplished knowledgeably.

Focusing on fossil-fueled, nonpolluting power generation systems, Zero Emissions Power Cycles presents alternative solutions to the severe emissions problems of power plants. Along with a description of new thermodynamic cycles and the results of computational analyses, this volume provides modern analytical tools and equations to evaluate exergy and introduce "currentology."

The authors explore various aspects of zero emissions power plant (ZEPP) technology, including carbon dioxide sequestration, ion transport, and oxygen enrichment. They show that ZEPP technology can:

• Provide affordable, clean power to meet expanding energy demand
• Solve critical environmental problems, such as eliminating carbon dioxide and pollutant emissions
• Address energy security issues by supporting the use of diverse fossil fuels, including integrated coal gasification and pulverized coal combustion
• Ease the economic cost of sustainable energy supplies primarily through the use of cogenerated carbon dioxide for enhanced oil recovery

Addressing the significant human contribution to global warming, this book presents reasonable and effective approaches to minimize the harmful pollution that results from fossil fuel emissions. It shows how to create and operate ZEPPs, making our energy future clean, secure, and inexpensive.

The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field.

In the development of next-generation nanoscale devices, higher speed and lower power operation is the name of the game. Increasing reliance on mobile computers, mobile phone, and other electronic devices demands a greater degree of speed and power. As chemical mechanical planarization (CMP) progressively becomes perceived less as black art and more as a cutting-edge technology, it is emerging as the technology for achieving higher performance devices. Nanoparticle Engineering for Chemical-Mechanical Planarization explains the physicochemical properties of nanoparticles according to each step in the CMP process, including dielectric CMP, shallow trend isolation CMP, metal CMP, poly isolation CMP, and noble metal CMP. The authors provide a detailed guide to nanoparticle engineering of novel CMP slurry for next-generation nanoscale devices below the 60nm design rule. They present design techniques using polymeric additives to improve CMP performance. The final chapter focuses on novel CMP slurry for the application to memory devices beyond 50nm technology. Most books published on CMP focus on the polishing process, equipment, and cleaning. Even though some of these books may touch on CMP slurries, the methods they cover are confined to conventional slurries and none cover them with the detail required for the development of next-generation devices. With its coverage of fundamental concepts and novel technologies, this book delivers expert insight into CMP for all current and next-generation systems.

This book presents the select peer-reviewed proceedings of the International Conference on Advances in Bioprocess Engineering and Technology (ICABET 2020). The book covers all aspects of bioprocesses, especially related to fermentation technology, food technology, environmental biotechnology, and sustainable energy. Along with this primary theme, the focus is on recent advances in bioprocessing research such as biosensors, micro-reactors, novel separation techniques, bioprocess control, bio-safety, advanced techniques for waste to wealth generation, and nanobiotechnology. This contents are divided according to the major themes of the conference: (i) Fermentation Technology and Bioreactor, (ii) Food Pharmaceuticals and Health care, (iii) Environment and Agriculture, and (iv) Sustainable Energy. This book is intended to help students, researchers, and industry professionals acquire knowledge on innovative technologies and recent advancements in the field of bioprocess engineering and technology.

While mathematically sophisticated methods can be used to better understand and improve processes, the nonlinear nature of food processing models can make their dynamic optimization a daunting task. With contributions from a virtual who s who in the food processing industry, Optimization in Food Engineering evaluates the potential uses and limitations of optimization techniques for food processing, including classical methods, artificial intelligence-genetic algorithms, multi-objective optimization procedures, and computational fluid dynamics.

The book begins by delineating the fundamentals and methods for analytical and numerical procedures. It then covers optimization techniques and how they specifically apply to food processing. The final section digs deep into fundamental food processes and provides detailed explanation and examples from the most experienced and published authors in the field. This includes a range of processes from optimization strategies for improving the performance of batch reactors to the optimization of conventional thermal processing, microwave heating, freeze drying, spray drying, and refrigeration systems, to structural optimization techniques for developing beverage containers, optimization approaches for impingement processing, and optimal operational planning methodologies. Each chapter presents the required parameters for the given process with the optimization procedure to apply.

An increasing part of the food processor s job is to optimize systems to squeeze more dollars out of overhead to offset rising utility and transportation costs. Logically combining optimization techniques from many sources into a single volume focused on food production processes, this book provides real solutions to increases in energy, healthcare, and product liability costs that impact the bottom line in food production.

Discussing the manufacture technology of pressure-sensitive adhesive and products, Volume 2 of the "Handbook of Pressure-Sensitive Adhesives and Products" includes the synthesis of pressure-sensitive raw materials and the design and formulation of pressure-sensitive adhesives. Taking into account monomers, polymerization methods, and polymerization technology, it addresses the offline and inline synthesis of pressure-sensitive raw materials and adhesives. The book describes the main formulation components, along with important chemical and technological additives, and considers the role of formulation as it correlates to formulation technology and equipment. It also highlights the components and build-up of pressure-sensitive products, including the equipment and methods involved in coating, converting, and confectionating.

Focusing on fundamentals of biofuel production from renewable energy sources and biohydrogen production, this book offers a complete understanding of the bioconversion processes. Each chapter begins with a fundamental explanation for general readers and ends with in-depth scientific details suitable for expert readers. It discusses different types of production technologies covering basic concepts, production strategies, commercial usage, and advances.

Fibre reinforced composite materials are showing sustained growth in an ever widening range of applications from food trays to spacecraft as well as contributing to resolving environmental problems, including enabling the forthcoming hydrogen economy to be realised. This second edition of Fundamentals of Fibre Reinforced Composite Materials has been fully updated throughout, providing an authoritative and modern introduction to the topic with a brief history of composite development, a review of composite applications, manufacture and markets, types of fibres and matrices used, and their properties with a detailed introduction into the computer simulation of composite behaviour. With extensive sets of sample problems accompanying each chapter, this book is ideally suited to undergraduate and graduate students of materials science, structural, mechanical, and aeronautical engineering, polymer science, metallurgy, and other courses. It will also be of use as a reference to researchers and engineers working with composite materials and material scientists in general. Features: Presents thorough discussions on composite history, composite applications and markets, types of fibres and resins used, and their respective properties Relates mathematical concepts to the structure of the material under discussion leading to the quantitative evaluation of safety factors Provides numerous sets of sample problems in each chapter

Examines regulatory and other strategies for improving chemical risk management in small enterprises in the European Union. This book considers what supports are necessary to secure the implementation of these strategies and is particularly concerned with the role of chemical product supply as envisaged by REACH.

This book provides practical information on obtaining and using a wide variety of plant based reagents for different sectors, addressing the needs and challenges in a single resource. The chapters complement each other seamlessly and present contributions from reputed international researchers and renowned professionals from industry, covering the latest efforts in the field. The book serves as the starting point for future collaborations in the new area "Plant Based Green Chemistry" between research, industry, and education, covering large ecologic and economic applications: perfume, cosmetic, pharmaceutical, food ingredients, nutraceuticals, biofuels, or fine chemicals industries. This book is aimed at professionals from industries, academicians engaged in plant based green chemistry, researchers and graduate level students, but will also be useful to food technologists and students and researchers involved in natural products chemistry.

The book entails investigative methods for better understanding of the degradation process and uses of high performance paints formulation and also compares them on mild steel (MS) and weathering steel (WS) through various AC/DC electrochemical test methods and surface characterization through electron microscopy, XRD and Raman spectroscopy. This book also deals with the corrosion studies undertaken considering three phases (solid, liquid and gas) with latest techniques and the emphasis has also been given on degradation of materials due to atmospheric corrosion as this is of immense interest to present engineers and researchers. MS has got versatile application as structural steel for construction of buildings, bridges, flyovers, pipelines etc. But this is very much prone to corrosion in industrial and marine environments in presence of harmful pollutants and other industrial effluents in addition to normal humid atmosphere. These corrosion problems are much severe in a tropical country like India with vast coastline. MS corrodes relatively faster and thus leads to colossal loss in every year and to reduce this loss some kind of protection in the form of paints and coatings is always used. Painting is an effective means but quite costly amounting 10-15% of the initial construction cost of superstructures besides cost of repainting at regular interval.

This is the first book to present the fundamentals of nonlinear and mixed-integer optimization. It includes their applications in the important area of process synthesis in chemical engineering. Topics that are unique include the theory and methods for mixed-integer nonlinear optimization. introduction to modelling issues in process synthesis and optimization based approaches in the synthesis and of heat recovery of systems, distillation-based systems, and reactor-based systems. As well as an ideal graduate text this book is designed as a reference for any engineering student or researcher.

The process industry has developed integrated process safety management programs to reduce or eliminate incidents and major consequences, such as injury, loss of life, property damage, environmental harm, and business interruption. Good documentation practices are a crucial part of retaining past knowledge and experience, and avoiding relearning old lessons. Following an introduction, which offers examples of how proper documentation might have prevented major explosions and serious incidents, the 21 sections in this book clearly present aims, goals, and methodology in all areas of documentation. The text contains examples of dozens of needed forms, lists of relevant industry organizations, sources for software, references, OSHA regulations, sample plans, and more.