Lea's Chemistry of Cement and Concrete, Fifth Edition, examines the suitability and durability of different types of cements and concretes, their manufacturing techniques and the role that aggregates and additives play in achieving concrete's full potential of delivering a high-quality, long-lasting, competitive and sustainable product.

This book is devoted to CO2 capture and utilization (CCU) from a green, biotechnological and economic perspective, and presents the potential of, and the bottlenecks and breakthroughs in converting a stable molecule such as CO2 into specialty chemicals and materials or energy-rich compounds. The use of renewable energy (solar, wind, geothermal, hydro) and non-fossil hydrogen is a must for converting large volumes of CO2 into energy products, and as such, the authors explore and compare the availability of hydrogen from water using these sources with that using oil or methane. Divided into 13 chapters, the book offers an analysis of the conditions under which CO2 utilization is possible, and discusses CO2 capture from concentrated sources and the atmosphere. It also analyzes the technological (non-chemical) uses of CO2, carbonation of basic minerals and industrial sludge, and the microbial-catalytic-electrochemical-photoelectrochemical-plasma conversion of CO2 into chemicals and energy products. Further, the book provides examples of advanced bioelectrochemical syntheses and RuBisCO engineering, as well as a techno-energetic and economic analysis of CCU. Written by leading international experts, this book offers a unique perspective on the potential of the various technologies discussed, and a vision for a sustainable future. Intended for graduates with a good understanding of chemistry, catalysis, biotechnology, electrochemistry and photochemistry, it particularly appeals to researchers (in academia and industry) and university teachers.

This book represents the systematic coverage of mass and energy balancing in the process industries. The classical treatment of balances in the available literature is complemented in the following areas:
- systematic analysis of large systems by Graph theory
- comprehensive thermodynamic analysis (entropy and availability)
- balancing on the basis of measured plant data (data reconciliation)
- measurement design and optimisation
- dynamic balancing
- plant-wide regular mass and energy balancing as a part of company's information system.

The major areas addressed are:
- single- and multi-component balancing
- energy balance
- entropy and exergy (availability) balances
- solvability of balancing problems
- balancing with data reconciliation
- dynamic balancing
- measurement design and optimisation
- regular balancing of large industrial systems.

The book is directed to chemical engineers, plant designers, technologists, information technology managers, control engineers and instrumentation engineers in process industries. Major areas of applications are process industries and energy production, such as oil refining, natural gas processing, petrochemistry, chemical industries, mineral processing and utility production and distribution systems. University students and teachers of chemical engineering and control will also find the book invaluable.

There are several physico-chemical processes that determine the behavior of multiphase fluid systems - e.g., the fluid dynamics in the different phases and the dynamics of the interface(s), mass transport between the fluids, adsorption effects at the interface, and transport of surfactants on the interface - and result in heterogeneous interface properties. In general, these processes are strongly coupled and local properties of the interface play a crucial role. A thorough understanding of the behavior of such complex flow problems must be based on physically sound mathematical models, which especially account for the local processes at the interface. This book presents recent findings on the rigorous derivation and mathematical analysis of such models and on the development of numerical methods for direct numerical simulations. Validation results are based on specifically designed experiments using high-resolution experimental techniques. A special feature of this book is its focus on an interdisciplinary research approach combining Applied Analysis, Numerical Mathematics, Interface Physics and Chemistry, as well as relevant research areas in the Engineering Sciences. The contributions originated from the joint interdisciplinary research projects in the DFG Priority Programme SPP 1506 "Transport Processes at Fluidic Interfaces."

Charge and Energy Storage in Electrical Double Layers presents the basic scientific concepts and implementation of procedures devised to obtain capacitive energy from changes in the potential of electrical double layers when the salinity of solutions is changed. Capacitive deionization- the closely connected reciprocal process-is also considered. The book covers the fundamentals of electrical double layers and ions transport in porous media, the description of promising techniques of energy extraction, and the practical problems involved in each. It is written for scientists in academia and industry, and for graduate students working in supercapacitors, capacitive mixing and deionization.

This book is a practical guide to optical, optoelectronic, and semiconductor materials and provides an overview of the topic from its fundamentals to cutting-edge processing routes to groundbreaking technologies for the most recent applications. The book details the characterization and properties of these materials. Chemical methods of synthesis are emphasized by the authors throughout the publication. Describes new materials and updates to older materials that exhibit optical, optoelectronic and semiconductor behaviors; Covers the structural and mechanical aspects of the optical, optoelectronic and semiconductor materials for meeting mechanical property and safety requirements; Includes discussion of the environmental and sustainability issues regarding optical, optoelectronic, and semiconductor materials, from processing to recycling.

This book covers the latest developments in phenolic foams and their applications. Compared with polystyrene and polyurethane foams, phenolic foams are known as third-generation polymeric foams. Phenolic foams exhibit excellent fire-retardant properties, including low flammability, low peak heat release rate, no dripping during combustion, and low toxicity. This book discusses various aspects of phenolic foams including properties, synthesis, fabrication methodologies, and applications. The contents also cover the methods for toughening of phenolic foams to make them more widely applicable. This book is of interest to both academics and industry alike. It is also a useful reference for fire safety regulators and policy-makers looking for new materials and methods for sustainable fire protection.

This book covers the entire spectrum of green diesel and their applications in existing CI engines. This book discusses how a green diesel is a better fuel than biodiesel and petrodiesel and more suitable fuels for sustainable future development. The book begins with a concise overview of the fundamentals of the green diesel properties, preparation, and characterization of green diesel using hydroprocessing technology. The book covers recent developments in the domain of green diesel derived particularly from the second-/third-generation feedstocks. Various topics covered in this book include the catalysts involved in the processing of green diesel, characterization of the products as per ASTM/EN protocols. In addition, the book also illustrates characteristic features of green diesel and how it is different from biodiesel and petrodiesel. Other chapters cover performance and emission characteristics of green diesel in CI engines and techno-economic analysis. Moreover, the current status of green diesel industries is also incorporated. This book is of particular interest to graduate students and academic or industrial researchers/professionals working in the area of green diesel/green energy, bioenergy and mechanical, automobile, and chemical engineering. This book makes a forceful foundation for the establishment of green diesel refineries/biorefineries for a sustainable, cleaner, and greener future.

Tailored Thin Coatings for Corrosion Inhibition Using a Molecular Approach discusses the fundamentals and applications of various thin coatings for the inhibition of fouling and corrosion from a molecular perspective. It provides the reader with a fundamental understanding of why certain coatings perform better than others in a given environment. Surface analytical and electrochemical techniques in understanding the coating performance are emphasized throughout the book, providing readers with a useful reference on how to pursue a systematic corrosion inhibitor R&D program that involves the testing of coating performance using various, currently available, state-of-the-art laboratory techniques. Wherever relevant, environmental considerations of the discussed coatings' technologies are highlighted and discussed, with current and upcoming regulatory trends put forth by different governmental organizations.

This book describes strategies and mechanism of reversible deactivation radical polymerization (RDRP) to synthesize functional polymers. Several approaches such as atom transfer radical polymerization and the combination of click chemistry and RDRP are summarized. Contributors from interdisciplinary fields highlight applications in nanotechnology, self-healing materials, oil and water resistant coatings and controlled drug delivery systems.

Anisotropic Particle Assemblies: Synthesis, Assembly, Modeling, and Applications covers the synthesis, assembly, modeling, and applications of various types of anisotropic particles. Topics such as chemical synthesis and scalable fabrication of colloidal molecules, molecular mimetic self-assembly, directed assembly under external fields, theoretical and numerical multi-scale modeling, anisotropic materials with novel interfacial properties, and the applications of these topics in renewable energy, intelligent micro-machines, and biomedical fields are discussed in depth. Contributors to this book are internationally known experts who have been actively studying each of these subfields for many years. This book is an invaluable reference for researchers and chemical engineers who are working at the intersection of physics, chemistry, chemical engineering, and materials science and engineering. It educates students, trains the next generation of researchers, and stimulates continuous development in this rapidly emerging area for new materials and innovative technologies.

"Advances in Water Treatment and Pollution Prevention" explores the most up-to-date studies in the field of water pollution. More specifically, this book examines the causes and effects of this threatening phenomenon and identifies the preventive measures that can be taken to contain, and even to defeat, water pollution worldwide.
The papers gathered in this volume pinpoint the need to implement greener water treatments to prevent water pollution from impacting ecosystems, human well-being and economies any further. They also successfully outline the processes that have been studied, optimized and developed so far to sustain our environment.
"Advances in Water Treatment and Pollution Prevention" will represent a valuable resource to academic researchers, students, institutions, environmentalists, and anyone interested in environmental policies aimed at safeguarding both the quality and the quantity of water.

This book presents the work of the RILEM Technical Committee 276-DFC: Digital fabrication with cement-based materials. The most important outcomes of the technical committee are presented. First, a unified process classification for digital fabrication with concrete is proposed, discussed and illustrated. Then, a state of the art of the testing methods (both at a material and structural level and in the fresh and hardened state) is provided. The gathered knowledge is expected to form the foundation of some quality control procedures for fresh properties along with hardened properties and service life performance. The book will benefit academics, practitioners, industry and standardization committees interested in digital fabrication with cement-based materials.

Energy Optimization in Process Systems and Fuel Cells, Third Edition covers the optimization and integration of energy systems, with a particular focus on fuel cell technology. With rising energy prices, imminent energy shortages, and the increasing environmental impacts of energy production, energy optimization and systems integration is critically important. The book applies thermodynamics, kinetics and economics to study the effect of equipment size, environmental parameters, and economic factors on optimal power production and heat integration. Author Stanislaw Sieniutycz, highly recognized for his expertise and teaching, shows how costs can be substantially reduced, particularly in utilities common in the chemical industry. This third edition contains substantial revisions and modifications, with new material on catalytic reactors, sorption systems, sorbent or catalyst regenerators, dryers, and more.

This book comprises the proceedings of the 5th International Conference on Mechanical, System, and Control Engineering 2021. The contents of this volume focus on recent technological advances in the field of system dynamics and simulation, precision mechanics, production technology, structural dynamics, nanomaterial engineering, cloud computing and services, energy engineering and management, etc. This book proves a valuable resource for those in academia and industry.

Organic Chemistry: Structure, Mechanism, Synthesis, Second Edition, provides basic principles of this fascinating and challenging science, which lies at the interface of physical and biological sciences. Offering accessible language and engaging examples and illustrations, this valuable introduction for the in-depth chemistry course engages students and gives future and new scientists a new approach to understanding, rather than merely memorizing the key concepts underpinning this fundamental area. The book builds in a logical way from chemical bonding to resulting molecular structures, to the corresponding physical, chemical and biological properties of those molecules. The book explores how molecular structure determines reaction mechanisms, from the smallest to the largest molecules-which in turn determine strategies for organic synthesis. The book then describes the synthetic principles which extend to every aspect of synthesis, from drug design to the methods cells employ to synthesize the molecules of which they are made. These relationships form a continuous narrative throughout the book, in which principles logically evolve from one to the next, from the simplest to the most complex examples, with abundant connections between the theory and applications. Featuring in-book solutions and instructor PowerPoint slides, this Second Edition offers an updated and improved option for students in the two-semester course and for scientists who require a high quality introduction or refresher in the subject.

Centrifugal Materials Processing; L.L. Regel, W.R. Wilcox. Convection in Crystal Growth under High Gravity on a Centrifuge; J. Friedrich, G. Muller. Segregation in Crystal Growth under High Gravity on a Centrifuge: A Comparison between Experimental and Theoretical Results; J. Friedrich, G. Muller. Analysis of Thermal Convection in Molten Tin Under Centrifugal Conditions; L. Bergelin, A. Chevy. Thermal Stability During Centrifugation: Flow Visualization Experiment; Numerical Results; W.A. Arnold, L.L. Regel. Flow Visualization Study of Convection in a Centrifuge; P.V. Skudarnov, et al. Determination of Solid/Melt Interface Shape and Growth Rate During Gradient Freeze Solidification on a Centrifuge Using Current Interface Demarcation; I. Moskowitz, et al. In Situ Observation of Directional Solidification in High Gravity; Y. Inatomi, et al. Impurity Distribution and Superconducting Properties of PbTe: T1 Crystals Grown in a Centrifuge; R. Parfeniev, et al. A Low Cost Centrifuge for Materials Processing in High Gravity; Y.A. Chen, et al. 20 Additional Articles. Index.

This book outlines the methodologies, approaches and tools for modelling chemicals in a Life Cycle Assessment (LCA) perspective, and also covers the main advantages and drawbacks of applying LCA to chemical processes. In the first part of this book, authors pay close attention to the limitations of modelling the environmental and social impacts of chemical processes, providing valuable insights to the problems of the Life Cycle Inventory (LCI) analysis for chemical processes. In the second part of this book, readers will learn about the LCA application to chemical processes in the laboratory and industrial scale. In each chapter of this book, readers will also find specific case studies on the modelling and application of LCA in the chemical industry.

This book bridges the gap between theoretical concepts and their implementations, especially for the high-performance structures/components related to advanced composite materials. This work focuses on the prediction of various structural responses such as deformations, natural frequencies etc. of advanced composites under complex environments and/or loading conditions. In addition, it discusses micro-mechanical material modeling of various advanced composite materials that involve different structures ranging from basic to advanced, such as beams, flat and curved panels, shells, skewed, corrugated, and other materials, as well as various solution techniques via analytical, semi-analytical, and numerical approaches. This book: Covers micro-mechanical material modeling of advanced composite materials Describes constitutive models of different composite materials and kinematic models of different structural configuration Discusses pertinent analytical, semi-analytical, and numerical techniques Focusses on structural responses relating to deformations, natural frequencies, and critical loads under complex environments Presents actual demonstrations of theoretical concepts as applied to real examples using Ansys APDL scripts This book is aimed at researchers, professionals, and graduate students in mechanical engineering, material science, material engineering, structural engineering, aerospace engineering, and composite materials.

This volume will capture transformational changes in both the chemistry and engineering side of solvent extraction, creating new directions and deepening our understanding of the structure and dynamics of liquid-liquid systems from the molecular- to nano- to meso- to bulk-scale. Reviews will cover advances in microfluidics, new tools for understanding the structure and dynamics of the liquid-liquid interface, ionic liquids in liquid-liquid extraction, molecular dynamics to visualize interactions in the solvent phase, liquid-liquid electrochemistry to interrogate the energetics of interfacial transport and complexation, design of new extractants, and the streamlining of process applications.

This indispensable book describes lubricant additives, their synthesis, chemistry, and mode of action. All important areas of application are covered, detailing which lubricants are needed for a particular application. Laboratory and field performance data for each application is provided and the design of cost-effective, environmentally friendly technologies is fully explored. This edition includes new chapters on chlorohydrocarbons, foaming chemistry and physics, antifoams for nonaqueous lubricants, hydrogenated styrene-diene viscosity modifiers, alkylated aromatics, and the impact of REACh and GHS on the lubricant industry.

This thesis details the significant progress made in improving the performance of organic transistors and the network conductivity of carbon nanotubes. The first section investigates organic semiconductor nucleation and growth on the most common dielectric surface used to fabricate organic thin film transistors. The nucleation and growth of the semiconductor was determined to be a critical factor affecting the device performance. Excellent dielectric modification layers, which promote desirable semiconductor growth leading to high conductivity were identified, and a technologically relevant deposition technique was developed to fabricate high quality dielectric modification layers over large areas. This may represent an important step towards the realization of large area organic circuity. In the final section, lessons learned from studying organic semiconductor nucleation and growth were utilized to improve the conductivity of carbon nanotube networks. Selective nucleation of materials at the junctions between nanotubes in the network significantly decreased the network's sheet resistance. The resulting networks may be promising candidates for transparent electrodes with a variety of optoelectronic applications.

Industrial Chemistry Case Studies presents material on a variety of aspects of the UK chemical and pharmaceutical industries in the late 1990s. It covers the economic dimension of the industries, some environmental concerns and constraints, and the issue of scaling up processes from the laboratory bench to full-scale production. Using a case study approach, with questions and answers included, there are real-life examples drawn from a number of different industrial areas including the nuclear industry, pharmaceuticals and steel making. Industrial Chemistry Case Studies is intended primarily for post-16 students and their teachers, but will also be of interest to a wider audience who may wish to be more informed about today's chemical industry.

Industrial Catalysis: Chemistry and Mechanism is an essential textbook for upper-level undergraduate and graduate students with an interest in the underlying concepts of catalysis, industrial organic chemistry and the mechanism of catalysis. For undergraduates it provides an introduction to the basic catalytic principles and industrial processes. Graduate students will find that the book gives an in-depth understanding of the mechanism of catalytic surface intermediates and the practice of modern catalysis research. For the post graduate and industrial chemist involved in catalysis research, it is a valuable reference text as a compendium of mechanisms by which major industrial catalytic processes operate.This unique book fills the gap between basic organic chemistry and fundamental chemical principles of catalysis, and is a must read for students and researchers in the field.

The field of nanocatalysis is undergoing rapid development. Nanocatalysis can help in designing catalysts with excellent activity, greater selectivity, and high stability. Their properties can easily be tuned by tailoring the size, shape, and morphology of the particular nanomaterial. Exhibiting both homogeneous and heterogeneous catalytic properties, nanocatalysts allow for rapid and selective chemical transformations, with the benefits of excellent product yield and ease of catalyst separation and recovery. Nanocatalysis: Synthesis of Bioactive Heterocycles reviews the catalytic performance and the synthesis and characterization of nanocatalysts, examining the current state of the art and pointing the way towards new avenues of research specially synthesis of bioactive heterocycles. Top researchers summarize synthetic methodologies for the synthesis of bioactive heterocycles using a nanocatalytic framework. The catalytic performance and the synthesis and characterization of nanocatalysts are reviewed. State of the art methods and new and emerging applications of nanocatalysts in the synthesis of biologically active heterocycles are detailed. Additional features include: Focuses on designing and synthesizing nanocatalysts specifically for the synthesis of different bioactive heterocycles. Demonstrates how nanocatalysis can produce catalysts with excellent activity, greater selectivity, and high stability. Explores tuning catalysts properties by tailoring the size, shape, and morphology of a nanomaterial. Offers the reader insights into the field of nanoscience via nanocatalysis. Nanocatalysis: Synthesis of Bioactive Heterocycles is a must read for researchers in organic chemistry, medicinal chemistry and biochemistry.