Micro- and Nanostructured Multiphase Polymer Blend Systems: Phase Morphology and Interfaces focuses on the formation of phase morphology in polymer blends and copolymers and considers various types of blends including thermosets, thermoplastics, thermoplastic vulcanizates, and structured copolymers. The book carefully debates the processing, rheology, and crystallization aspects of the phase morphology of polymer blends. The text surveys theory, characterization, processing, and experimental aspects of phase morphology development and design of polymer blends. It examines the adhesion of polymer-polymer interfaces in immiscible polymer blends and the different ways by which nanostructures may be generated in thermosetting polymers. The book analyzes the polymerization process and the dynamic vulcanization of multicomponent polymer blends and the crystallization behavior occurring in blends with a confined morphology. It also discusses the structure-rheology relationship in compatibilized blends, the effects of elasticity on the structure development, and the rheological response in concentrated blends. Micro- and Nanostructured Multiphase Polymer Blend Systems examines the current state of the art, challenges, and future prospects in the field of polymer blends. The handpicked selection of topics and expert contributors makes this survey of phase morphology in polymer blends an outstanding resource for anyone involved in the field of polymer materials design.

Interest in green chemistry and clean processes has grown so much in recent years that topics such as fluorous biphasic catalysis, metal organic frameworks, and process intensification, which were barely mentioned in the First Edition, have become major areas of research. In addition, government funding has ramped up the development of fuel cells and biofuels. This reflects the evolving focus from pollution remediation to pollution prevention. Copiously illustrated with more than 800 figures, the Third Edition provides an update from the frontiers of the field. It features supplementary exercises at the end of each chapter relevant to the chemical examples introduced in each chapter. Particular attention is paid to a new concluding chapter on the use of green metrics as an objective tool to demonstrate proof of synthesis plan efficiency and to identify where further improvements can be made through fully worked examples relevant to the chemical industry. NEW AND EXPANDED RESEARCH TOPICS Metal-organic frameworks Metrics Solid acids for alkylation of isobutene by butanes Carbon molecular sieves Mixed micro- and mesoporous solids Organocatalysis Process intensification and gas phase enzymatic reactions Hydrogen storage for fuel cells Reactive distillation Catalysts in action on an atomic scale UPDATED AND EXPANDED CURRENT EVENTS TOPICS Industry resistance to inherently safer chemistry Nuclear power Removal of mercury from vaccines Removal of mercury and lead from primary explosives Biofuels Uses for surplus glycerol New hard materials to reduce wear Electronic waste Smart growth The book covers traditional green chemistry topics, including catalysis, benign solvents, and alternative feedstocks. It also discusses relevant but less frequently covered topics with chapters such as "Chemistry of Long Wear" and "Population and the Environment." This coverage highlights the importance of chemistry to everyday life and demonstrates the benefits the expanded exploitation of green chemistry can have for society.

The "flipped classroom" has become the new buzzword not only among educators but also in the general public, with articles in the USA Today, Washington Post, and The New York Times discussing this pedagogical approach. Simply stated, the flipped classroom is a high tech variation on a pedagogical method that has been around for generations. The time honored Socratic method aims to actively engage students with instructors asking them questions, leading them down a path where they are encouraged to see the connections between ideas. Additionally, flipped classrooms resemble the Thayer method, which expects students to take responsibility for their own learning by studying material before it is covered in class. Chemistry professors who teach in flipped classrooms embrace a variety of learning theories to guide their implementations. Most chemists who use active learning approaches in their classrooms value some aspect of constructivism theory, in which learners must begin their understanding of the concepts in their pre-class assignments. Later, students apply the concepts in class using active learning methods. For this book, the authors define the flipped classroom as one where students gain exposure to course content before class and the face-to-face time involves active learning. The call for and relevance of larger reform efforts in chemical education is not new and this book represents a continuation in the possibilities in achieving reform and meeting the goals of improving students' knowledge of chemistry. Muzyka and Luker provide a deeper, more encompassing picture of the cognitive and affective benefits of this pedagogy.

The world faces significant challenges as the population and consumption continue to grow while nonrenewable fossil fuels and other raw materials are depleted at ever-increasing rates. Moreover, environmental consciousness and a penchant for thinking in terms of material cycles have caught on with consumers: the use of environmentally compatible materials and production methods is desired. This volume, Green Materials and Environmental Chemistry: New Production Technologies, Unique Properties, and Applications takes a technical approach to address these issues using green design and analysis. This book provides an overview of the latest developments in environmental chemistry and sustainable materials written by experts in their respective research areas. This interdisciplinary volume offers research with the aim to minimize environmental impacts across all lifecycle phases in the design and engineering of products, processes, and systems as just one possible approach to addressing the larger issue of sustainability that includes environmental, economic, and social aspects.

Applications of composite materials and composite coatings have been increasing in the field of automobile and aerospace industries due to the versatility in their properties. Present book comprehensively reviews the composite materials and coatings with a focus on the mechanical and tribology applications. It covers type of fibres (natural and synthetic), reinforcements and their selection, matrix, and technologies used to produce composite materials. Various sections cover basics and associated failures of composites, strengthening mechanisms and background theories, composite manufacturing technologies, mechanical and tribology properties of past and currently used composites. Features:- Covers different types of fibers, reinforcements, matrix, and technologies used to produce composite materials. Details the tribology behavior of different novel composite coatings fabricated using different coating techniques. Reviews research on wear behavior of composite materials and coatings. Discusses reinforcement behavior with respect to the different processing routes. Illustrates rule of mixtures, failures, theories behind the strengthening mechanism. This book aims at professionals, graduate students and researchers in mechanical engineering, design engineering, composite materials, composite coatings, tribology, automobile, and aircraft.

This book provides a comprehensive overview of the concept of "Total Exposure Health" and presents details on subject areas which make up the framework. It provides in-depth coverage of the science and technology supporting exposure and risk assessment. This includes advances in toxicology and the "-omics" as well as new techniques for exposure assessment. The book concludes with a discussion on bioethics implications, including ethical considerations related to genetic testing. Discusses advances in exposure monitoring Presents a systems biology approach to human exposures Examines how overall well-being translates to worker productivity Considers the link between work-related risk factors and health conditions Covers the study of genomics in precision medicine and exposure science Explores bioethics in genomic studies Aimed at the exposure professionals (industrial hygienists, toxicologists, public health, environmental engineers), geneticists, molecular biologists, engineers and managers in the health and safety industry as well as professionals in the public administration field.

Emphasizing the static and dynamic behaviors of nanocomposite single- or multilayered structures in the framework of continuum mechanics-based approaches, Mechanics of Nanocomposites: Homogenization and Analysis investigates mechanical behaviors of polymeric matrices strengthened via various nanofillers and nanoparticles such as carbon nanotubes (CNTs), graphene platelets (GPLs), and graphene oxides (GOs). It covers equivalent properties of nanocomposites that are obtained via homogenization techniques based on micromechanics approaches. In addition, this comprehensive book: Discusses the effects of various nanofillers and identifies the amount of the improvement that can be induced in the stiffness of the polymeric nanocomposites by adding a finite content of the aforementioned nanosize reinforcements Magnifies the effect of the number of the stacking plies of the multi-layered nanocomposite structures on both static and dynamic responses of the continuous systems manufactured from such sandwich structures Presents a wide range of analytical and numerical solution procedures Investigates the effects of porosity along with mechanical characteristics of nanocomposites Considers the time-dependency of the material properties of the viscoelastic polymeric nanocomposite structures Performs analyses using an energy-based approach incorporated with the strain-displacement relations of both classical and higher-order shear deformable beam, plate, or shell theorems Aimed at researchers, academics, and professionals working across mechanical, materials, and other areas of engineering, this work ensures that readers are equipped to fully understand the mechanical characteristics of nanocomposite structures so that they can design, develop, and apply these materials effectively.

This book gives the definitive mathematical answer to what thermodynamics really is: a variational calculus applied to probability distributions. Extending Gibbs's notion of ensemble, the Author imagines the ensemble of all possible probability distributions and assigns probabilities to them by selection rules that are fairly general. The calculus of the most probable distribution in the ensemble produces the entire network of mathematical relationships we recognize as thermodynamics. The first part of the book develops the theory for discrete and continuous distributions while the second part applies this thermodynamic calculus to problems in population balance theory and shows how the emergence of a giant component in aggregation, and the shattering transition in fragmentation may be treated as formal phase transitions. While the book is intended as a research monograph, the material is self-contained and the style sufficiently tutorial to be accessible for self-paced study by an advanced graduate student in such fields as physics, chemistry, and engineering.

This unique book presents an integrated approach to the chemistry of art materials, exploring the many chemical processes involved. The Chemistry and Mechanism of Art Materials: Unsuspected Properties and Outcomes engages readers with historical vignettes detailing examples of unexpected outcomes due to materials used by known artists. The book discusses artists' materials focusing on relevant chemical mechanisms which underlie the synthesis and deterioration of inorganic pigments in paintings, the ageing of the binder in oil paintings, and sulfation of wall paintings as well as the toxicology of these pigments and solvents used by artists. Mechanisms illustrate the stepwise structural transformation of a variety of art materials. Based on the author's years of experience teaching college chemistry, the approach is descriptive and non-mathematical throughout. An introductory section includes a review of basic concepts and provides concise descriptions of analytical methods used in contemporary art conservation. Additional features include: Illustrations of chemical reactivity associated with art materials Includes a review of chemical bonding principles, redox and mechanism writing Covers analytical techniques used by art conservation scientists Accessible for readers with a limited science background Provides numerous references for readers seeking additional information

THE CURRENT STATE OF THE ART of waterborne polymers, paints, coatings, inks and printing processes is presented in this volume. This is the third volume in the series on waterborne coating and printing technology. It documents several invited papers and the proceedings of the International Symposium on Surface Phenomena and Latexes in Waterborne Coatings and printing Technology sponsored by the Fine Particle Society (FPS). The FPS meeting was held in Las Vegas, Nevada, July 13-17, 1992. The volume deals with various basic and applied aspects of research on waterborne coating printing technology. Major topics discussed involve waterborne polymers and polymer blends, pigment grinding, millbases, paint formulation, and characterization of coating films. This edition includes sixteen selected papers related to recent developments in waterborne technology. These papers are divided in three broad categories: (1) Waterborne Polymers and pigment Dispersions, (2) Latex Film, Wetting Phenomena and Printing Gloss, (3) Surfactants and Polymers in Aqueous Coating printing Systems. This volume includes discussions of various waterborne polymers in coating printing systems. The editors hope that this volume will serve its intended objective of reflecting the current understanding of formulation and process problems related to waterborne coatings, paints and inks. In addition, it will be a valuable reference source for both novices as well as experts in the field of waterborne technology. It will also help the readers to understand underlying surface phenomena and will enhance the reader's potential for solving critical formulation, evaluation and process problems.

Offers a comprehensive overview of all types of tests used in lubricant condition monitoring programmes. Discusses monitoring the condition of all types of components, machines, equipment, and systems used in all industries. Considers new and emerging machines, equipment, and systems, including electric and hybrid vehicles. Suggests which tests to use for each type of machine, equipment, or system and, just as importantly, which tests not to use. Provides practical examples of how to set up, run, and manage condition monitoring programmes and how to achieve significant cost savings through planned and predictive maintenance schedules.

Sheet and film processes include coating, papermaking, metal rolling, and polymer film extrusion. Products produced by these processes include paper, bumper stickers, plastic bags, windshield safety glass, and sheet metal. The total capitalization of industries that rely on these processes is well over $ 500 billion worldwide. These processes are notorious for being difficult to control.The goal of this book is to present the theoretical background and practical techniques for the identification and control of sheet and film processes. It is explained why many existing industrial control systems perform poorly for sheet and film processes. Identification and control algorithms are described and illustrated which provide consistent and reliable product quality. These algorithms include an experimental design technique that ensures that informative data are collected during input-output experimentation, model identification techniques that produce a process model and an estimate of its accuracy, and control techniques that take into account actuator constraints as well as robustness to model uncertainties.The algorithms covered in this book are truly the state of the art. Variations on some of the algorithms have been implemented on industrial sheet and film processes. Other algorithms are in various stages of implementation. All of the algorithms have been applied to realistic simulation models constructed from industrial plant data; many of these studies are included in this book.

The present issue of Structure and Bonding is dedicated to applied group 13 chemistry, particularly for the elements boron and aluminum, and to a lesser degree gallium and indium. Although boron is a trace element (0.01 g kg 1) in the earth's crust, it has been concentrated in a few locations by geochemical processes and is relatively easy to mine as borax. Aluminum, on the other hand, is the most abundant metal in the earth's crust (82 g kg 1) and dispersed widely throughout the globe. Thus, boron and aluminum are readily available and their associated products or compounds are usually inexpensive and thereby easy to commercialize. The chapters were chosen to encompass both applied and fundamental aspects of their subiects. The first chapter 'Borates in Industrial Use' provides a complete, and perhaps, quintessential, coverage of compounds containing boron oxygen bonds. In the chapter Schubert explains the close relationship between the basic properties of the boron compounds and their associated uses. The remaining four chapters focus, to some degree, on aluminum. Since a great deal of literature exists in this area, these chapters are more focused on areas of emerging utility, and contain a great deal of fundamental information. Uhl's contribution in Chapter 2 provides basic synthesis and structural information for aluminum and gallium hydrazides. These types of compounds are being explored as potential molecular precursors to metal nitrides such as the important blue green laser material gallium nitride.

Electrolyte solutions play a key role in traditional chemical industry processes as well as other sciences such as hydrometallurgy, geochemistry, and crystal chemistry. Knowledge of electrolyte solutions is also key in oil and gas exploration and production, as well as many other environmental engineering endeavors. Until recently, a gap existed between the electrolyte solution theory dedicated to diluted solutions, and the theory, practice, and technology involving concentrated solutions. Electrolytes: Supramolecular Interactions and Non-Equilibrium Phenomena in Concentrated Solutions addresses concentrated electrolyte solutions and the theory of structure formation, super and supramolecular interactions, and other physical processes with these solutions-now feasible due to new precision measurement techniques and experimental data that have become available. The first part of the book covers the electrolyte solution in its stationary state-electrostatic, and various ion-dipole, dipole-dipole, and mutual repulsion interactions. The second part covers the electrolyte solution in its nonstationary status, in the case of forced movement between two plates-electrical conductivity, viscosity, and diffusion. This theoretical framework allows for the determination of activity coefficients of concentrated electrolyte solutions, which play a key role in many aspects of electrochemistry and for developing novel advanced processes in inorganic chemical plants.

This book explores the remarkable information correspondences and probability structures of proteins. Correspondences are pervasive in biochemistry and bioinformatics: proteins share homologies, folding patterns, and mechanisms. Probability structures are just as paramount: folded state graphics reflect Angstrom-scale maps of electron density. The author explores protein sequences (primary structures), both individually and in sets (systems) with the help of probability and information tools. This perspective will enhance the reader's knowledge of how an important class of molecules is designed and put to task in natural systems, and how we can approach class members in hands-on ways.

Green Chemistry and Biodiversity: Principles, Techniques, and Correlations reports on new approaches to designing chemicals and chemical transformations that are beneficial for human health and the environment, a continuing emerging important field of study. This volume provides a collection of innovative research on the development of alternative sustainable technologies, taking a broad view of the subject and integrating a wide variety of approaches. With a focus on the interdisciplinary applications of green chemistry and biodiversity, this volume will be a rich resource for scientists and researchers in many subfields of chemistry and chemical engineering.

This book reviews several domains of polymer science, especially new trends in polymerization synthesis, physical-chemical properties, and inorganic systems. Composites and nanocomposites are also covered in this book, emphasizing nanotechnologies and their impact on the enhancement of physical and mechanical properties of these new materials. Kinetics and simulation are discussed and also considered as promising techniques for achieving chemistry and predicting physical property goals. This book presents a selection of interdisciplinary papers on the state of knowledge of each topic under consideration through a combination of overviews and original unpublished research.

Applies the principles of chemistry, microbiology, and metallurgy to help readers reliably determine the mechanistic cause of corrosion damage and failures and select appropriate methods for mitigating future corrosion incidents Presents up-to-date advances in molecular technologies and their application to corrosion failure investigations Offers specific guidelines for conducting MIC failure analyses and case studies to illustrate their application Gives state-of-the-art information on MIC analytical tools and methods

This volume is devoted to compounds in which the spiro centre is part of a pyranoid or furanoid or an iminosugar ring. The chapters contributed deal with methodological peculiarities of syntheses of natural and artificial sugar derived spirocycles as well as their biological applications and other utilities including marketed drugs. Carbohydrates are ubiquitous molecules in nature and participate in a vast number of biological interactions. Especially their conjugates with practically all kinds of primary and secondary metabolic small molecules (and also biomacromolecules) representing valuable tools for glycobiology research and also lead compounds for drug discovery. While monosaccharides per se appear as heterocycles, their natural conjugates frequently exhibit spiro(hetero)cyclic derivatives, in many cases of high therapeutical relevance. As a consequence, the field of carbohydrate-spiro-heterocycles attracts intense interest from both chemical and biomedical aspects therefore this volume will be of interest for synthetic and medicinal chemists and (glyco)biologists, as well as researchers involved in various biomedical fields.

This title covers the fundamentals of carbon nanomaterials in a logical and clear manner to make concepts accessible to researchers from different disciplines. It summarizes in a comprehensive manner recent technological and scientific accomplishments in the area of carbon nanomaterials and their application in lithium ion batteries The book also addresses all the components anodes, cathodes and electrolytes of lithium ion battery and discusses the technology of lithium ion batteries that can safely operate at high temperature.

Batch reaction systems pose unique challenges to process safety managers because they do not operate in a steady state. The sequence of processing steps, and frequent start-ups and shutdowns, increase the possibility of human errors and equipment failures. And, since batch plants are often designed for shared use, frequent modification of piping and layout may occur, resulting in complex "management of change" issues. This book identifies the singular concerns of batch reaction systems--including potential sources of unsafe conditions--and provides a "how-to" guide for the practicing engineer in dealing with them by applying appropriate practices to prevent accidents.

This book introduces the theory and applications of nanometer photocatalysis, and it briefly presents the concept of photocatalysts, photocatalytic reaction mechanisms and kinetics, and photocatalytic reactor design. In addition, the use of photocatalysis in the control of flue-gas pollutants is discussed in detail. The book also describes how a photocatalytic reactor is designed and implemented to evaluate the photocatalytic oxidation capacity of different photocatalysts on elemental mercury in a simulated flue gas. After that, the effect of photocatalysts on the SO2, NOx and Hg removal in the flue gas is studied. Photocatalytic cleaning technology can be applied not only in gas pollutant cleaning at power plants, but also in wastewater purification. Readers gain a comprehensive understanding of possible mercury emission control methods and the industrial applications of these technologies.

This book provides a comprehensive overview of contemporary basic research, emerging technology, and commercial and industrial applications associated with the electrophoretic deposition of nanomaterials. This presentation of the subject includes an historical survey, the underlying theory of electrophoresis, dielectrophoresis, and the colloidal deposition of materials. This is followed by an assessment of the experimental equipment and procedures for electrophoretic and dielectrophoretic aggregation, manipulation, and deposition of nanoparticles, nanotubes, and other nanomaterials. Additional chapters explore the specific science and technology of electrophoretic film formation, using widely studied and application-driven nanomaterials, such as carbon nanotubes, luminescent nanocrystals, and nano-ceramics. The concluding chapters explore industrial applications and procedures associated with electrophoretic deposition of nanomaterials.