Stereoselective Synthesis of Tetrasubstituted Alkenes via Torquoselectivity-Controlled Olefination of Carbonyl Compounds with Ynolates, by Mitsuru Shindo and Kenji Matsumoto.- Stereoselective Synthesis of Z-Alkenes, by Woon-Yew Siau, Yao Zhang and Yu Zhao.- Stereoselective Synthesis of Mono-fluoroalkenes, by Shoji Hara.- Recent Advances in Stereoselective Synthesis of 1,3-Dienes, by Michael De Paolis, Isabelle Chataigner and Jacques Maddaluno.- Selective Olefination of Carbonyl Compounds via Metal-Catalyzed Carbene Transfer from Diazo Reagents, by Yang Hu and X. Peter Zhang.- Selective Alkene Metathesis in the Total Synthesis of Complex Natural Product, by Xiaoguang Lei and Houhua Li.- Olefination Reactions of Phosphorus-Stabilized Carbon Nucleophiles, by Yonghong Gu and Shi-Kai Tian.- Alkene Synthesis Through Transition Metal-Catalyzed Cross-Coupling of N-Tosylhydrazones, by Yan Zhang and Jianbo Wang.

Thermal Separation Technology is a key discipline for many industries and lays the engineering foundations for the sustainable and economic production of high-quality materials. This book provides fundamental knowledge on this field and may be used both in university teaching and in industrial research and development. Furthermore, it is intended to support professional engineers in their daily efforts to improve plant efficiency and reliability. Previous German editions of this book have gained widespread recognition. This first English edition will now make its content available to the international community of students and professionals. In the first chapters of the book the fundamentals of thermodynamics, heat and mass transfer, and multiphase flow are addressed. Further chapters examine in depth the different unit operations distillation and absorption, extraction, evaporation and condensation, crystallization, adsorption and chromatography, and drying, while the closing chapter provides valuable guidelines for a conceptual process development.

lysts using enzyme, microbial, and plantbiochemistriesand genetic engi- neeringand "ProcessingResearch" describedtheconversionofplantcom- ponentsviaintegrationofmicrobiology,biochemistry,andchemistrywith engineering, separations, and hybrid systems. The "Enzymatic Processes and Enzyme Production" session focused on the manufacture and use of enzymes. The"IndustrialChemicals"sessionemphasizedrecentdevelop- mentsintheintegratedproductionandscale-upofchemicalsfrombiologi- cal rather than petrochemical routes. Special interest was on separation methods and their integrationintonew fermentation orhybrid processes. 35 oral presentations, a roundtable The technical program consisted of forum, two special topic discussions, and a poster session of 135 posters. Wecontinuedasuccessfulinformalroundtableserieswith"Bioenergy and Bioproducts: Forum on Recent Government Initiatives," which dis- cussedthePresident'sExecutiveOrder, the BioenergyInitiative, the Tech- nology Roadmap for Renewables Vision 2020, and other thrusts. These eventscontinuethe strongindustrial focus and activeindustrialparticipa- tionintheorganizingcommittee. Thishasbecomeverypopularbecauseit allows industrialand government participants to speakmore openly. AspecialTopicsDiscussionGroupwasheldon"C0 Sequestration," 2 ledby James W. Lee. Another onwas held on "Commercializationof Bio- mass-to-Ethanol" where chairs Jack N. Saddler and David J. Gregg made thegoal ofthisworkshop to showparticipantsthatweare close to demon- stratingthe technicalviability ofanintegratedbiomass-to-ethanolprocess and that progressive technical advances and policy decisions will likely greatly enhance the economic attractiveness of the process.

Carbon-based materials and their applications constitute a burgeoning topic of scientific research among scientists and engineers drawn to the field from diverse areas such as applied physics, materials science, biology, mechanics, electronics and engineering. Further development of existing materials, advances in their applications, and discovery of new forms of carbon are the themes addressed by the frontier research in these fields. This book covers all the fundamental topics concerned with amorphous and crystalline C-based materials, such as diamond, diamond-like carbon, carbon alloys, and carbon nanotubes. The goal is, by coherently progressing from growth -- and characterization techniques to technological applications for each class of material -- to fashion the first comprehensive state-of-the-art review of this fast evolving field of research in carbon materials.

1. Gives an in-depth account of the extraordinary optical property at the nanoscale and its use in sensing. 2. Useful for academia, researchers and engineers working in water treatment and purification. 3. Provides sensing application of thematic nanomaterials like quantum dots and core-shell.

Structure formation in crystallizing polymers, as occurring during processing, has not been treated so far in a coherent form. This fact explains, why this monograph is written as the ?rst book devoted to this subject. A quarter of a century ago the underdevelopment of this subject was obvious. Trial and error dominated. In fact, other apposite subjects as polymer melt rheology or heat transfer, had reached high levels. A great number of books has been devoted to them. Mold ?lling of amorphous polymers and the solidi?cation of these polymers by vitri?cation can nowadays be simulated numerically with a high degree of accuracy. In the solidi?ed sample even residual stresses and corresponding birefringence effects can accurately be 1 calculated . However, semicrystalline polymers, which form the majority of industrial po- mers, have been excluded from these considerations for good reasons. In fact, great uncertainties existed about the formation of quality determining crystalline str- tures. In particular, polyole?ns suffered from this shortcoming. In 1983 this fact instigated the polymer research group at the Johannes Kepler University in Linz to start with pertinent activities. The urgency of this kind of studies becomes evident, if advantages and hitches of these polymers are considered. 1. Versatility of processing: Injection molding into a great variety of shapes and sizes, from thin walled beakers to garden chairs, not to forget pipe and pro?le extrusion, cable coating, ?ber spinning, ?lm blowing. 2. Product qualities: Ductility, low density, good electric insulation, corrosion resistance, surface quality.

The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field.

Proceedings of the European Membrane Society XVI Annual Summer School on Integration of Membrane Processes into Bioconversions, held August 22-27, 1999, in Veszpr m, Hungary. The purpose of this book is to give an overview of the current situation of membrane separation processes in the field of bioengineering and also to describe how their joint application possibilities can be used in both laboratory and industrial scale applications. In commercial applications, focus is centered on the fields of food industry, chemical/fine chemical industry, and environmental protection. Most of the European experts in the interdisciplinary fields of membrane processes and bioconversions have contributed to the chapters in this work, making it the most up-to-date volume currently available.

This text provides the undergraduate chemical engineering student with the necessary tools for problem solving in chemical or bio-engineering processes. In a friendly, simple, and unified framework, the exposition aptly balances theory and practice. It uses minimal mathematical concepts, terms, algorithms, and describes the main aspects of chemical process optimization using MATLAB and GAMS. Numerous examples and case studies are designed for students to understand basic principles of each optimization method and elicit the immediate discovery of practical applications. Problem sets are directly tied to real-world situations most commonly encountered in chemical engineering applications. Chapters are structured with handy learning summaries, terms and concepts, and problem sets, and individually reinforce the basics of particular optimization methods. Additionally, the wide breadth of topics that may be encountered in courses such as Chemical Process Optimization, Chemical Process Engineering, Optimization of Chemical Processes, are covered in this accessible text. The book provides formal introductions to MATLAB, GAMS, and a revisit to pertinent aspects of undergraduate calculus. While created for coursework, this text is also suitable for independent study. A full solutions manual is available to instructors who adopt the text for their course.

This book provides a comprehensive overview of the main electrical technologies for process heating, which tend to be treated separately in specialized books. Individual chapters focus on heat transfer, electromagnetic fields in electro-technologies, arc furnaces, resistance furnaces, direct resistance heating, induction heating, and high-frequency and microwave heating. The author highlights those topics of greatest relevance to a wide-ranging teaching program, and at the same time offer a detailed review of the main applications of the various technologies. The content represents a synthesis of the extensive knowledge and experience that the author has accumulated while researching and teaching at the University of Padua's Engineering Faculty. This text on industrial electroheating technologies is a valuable resource not only for students of industrial, electrical, chemical, and material science engineering, but also for engineers, technicians and others involved in the application of electroheating and energy-efficient industrial processes.

This book covers the entire spectrum of green diesel and their applications in existing CI engines. This book discusses how a green diesel is a better fuel than biodiesel and petrodiesel and more suitable fuels for sustainable future development. The book begins with a concise overview of the fundamentals of the green diesel properties, preparation, and characterization of green diesel using hydroprocessing technology. The book covers recent developments in the domain of green diesel derived particularly from the second-/third-generation feedstocks. Various topics covered in this book include the catalysts involved in the processing of green diesel, characterization of the products as per ASTM/EN protocols. In addition, the book also illustrates characteristic features of green diesel and how it is different from biodiesel and petrodiesel. Other chapters cover performance and emission characteristics of green diesel in CI engines and techno-economic analysis. Moreover, the current status of green diesel industries is also incorporated. This book is of particular interest to graduate students and academic or industrial researchers/professionals working in the area of green diesel/green energy, bioenergy and mechanical, automobile, and chemical engineering. This book makes a forceful foundation for the establishment of green diesel refineries/biorefineries for a sustainable, cleaner, and greener future.

I am honored to chair this International Workshop on Functionally st Graded Materials in the 21 Century: A Workshop on Trends and Forecasts, and would like to first express my sincere gratitude to everyone participating. The Mechanical Engineering Laboratory and the Japan International Science and Technology Exchange Center (JISTEC) have co-organized this workshop with the sponsorship of the Science and Technology Agency of Japan and the cooperation of the Association of Mechanical Technology. This workshop is an international conference to focus on functionally graded materials and the aim is to provide an overview of the present global technical trends and the future development of functionally graded materials over the next 10 years. I am very happy to see many researchers meeting together here - including seven researchers invited from abroad. During the three-day oral sessions, 36 research reports will be presented, and I'm sure I'm not the only one who is very anxious to hear and participate in the upcoming interesting discussions. At present, the Mechanical Engineering Laboratory is conducting fundamental and ground-breaking research in such major areas as materials science and technology, bioengineering, information & system science, advanced machine technology, energy technology, manufacturing technology and robotics. In particular, we consider research on materials science and technology to have the highest priority for the 21st century. and since 1996 have participated in the US-Japan joint research project, Precompetitive Processing and Characterization of Functionally Graded Materials.

Prof. Baev presents in his book the development of the thermodynamic theory of specific intermolecular interactions for a wide spectrum of organic compounds: ethers, ketones, alcohols, carboxylic acids, and hydrocarbons. The fundamentals of an unconventional approach to the theory of H-bonding and specific interactions are formulated based on a concept of pentacoordinate carbon atoms. New types of hydrogen bonds and specific interactions are substantiated and on the basis of the developed methodology their energies are determined. The system of interconnected quantitative characteristics of the stability of specific intermolecular interactions is presented. The laws of their transformations are discussed and summarized. The new concept of the extra stabilizing effect of isomeric methyl groups on the structure and stability of organic molecules is introduced and the destabilization action on specific interactions is outlined.

This book covers the theoretical and practical aspects of the mixing of solids and presents an overview as well as detailed know-how and experience. The book demonstrates the state of the art of mixing and segregation technology, quality control, design of mixers, design scale-up and engineering of complete processes. Includes checklists, criteria for choosing batch or continuous process, and practical examples of installed systems.

A guide for younger R&D chemists as to how they can quickly evolve skills built around three factors -- people, knowledge and time. It covers the management of scientific personnel, management within a variety of R & D organizational structures, creating a climate of innovation, the management of projects including the time management and communication aspects of the job. As such, it teaches the vital managerial aspects of scientific jobs in industry, which are not taught at university, providing a deep and detailed insight into the intricacies of managing research.
The text is divided neatly into four sections:
* Harnessing the Human Resource
* Organising for an Innovative Environment
* Creativity and Innovation
* Project Management of Innovation
The author, Peter Bamfield, is now working as a consultant. Due to his long experience in the chemical industry, he was elected President of the Royal Society of Chemistry's Industrial Affairs Division, and thus has a profound first-hand view of staff, companies and organizations in and around the industry.
This third edition has been revised and updated to take into account global developments and recent changes in regulatory affairs.

Supercritical fluids which are neither gas nor liquid, but can be compressed gradually from low to high density, are gaining increasing importance as tunable solvents and reaction media in the chemical process industry. By adjusting the pressure, or more strictly the density, the properties of these fluids are customized and manipulated for the particular process at hand, be it a physical transformation, such as separation or solvation, or a chemical transformation, such as a reaction or reactive extraction. Supercritical fluids, however, differ from both gases and liquids in many respects. In order to properly understand and describe their properties, it is necessary to know the implications of their nearness to criticality, to be aware of the complex types of phase separation (including solid phases) that occur when the components of the fluid mixture are very different from each other, and to develop theories that can cope with the large differences in molecular size and shape of the supercritical solvent and the solutes that are present.

Supercritical fluids are neither gas nor liquid, but can be compressed gradually from low to high density and they are therefore interesting and important as tunable solvents and reaction media in the chemical process industry. By adjusting the density the properties of these fluids can be customised and manipulated for a given process - physical or chemical transformation. Separation and processing using supercritical solvents such as CO2 are currently on-line commercially in the food, essential oils and polymer industries. Many agencies and industries are considering the use of supercritical water for waste remediation. Supercritical fluid chromatography represents another, major analytical application. Significant advances have recently been made in materials processing, ranging from particle formation to the creation of porous materials.

The chapters in this book provide tutorial accounts of topical areas centred around: (1) phase equilibria, thermodynamics and equations of state; (2) critical behaviour, crossover effects; (3) transport and interfacial properties; (4) molecular modelling, computer simulation; (5) reactions, spectroscopy; (6) phase separation kinetics; (7) extractions; (8) applications to polymers, pharmaceuticals, natural materials and chromatography; (9) process scale-up.

This contributed volume provides a critical review of research in the field of Electrochemical Promotion of Catalysis (EPOC). It presents recent developments during the past decade that have led to a better understanding of the field and towards applications of the EPOC concept. The chapters focus on the implementation of EPOC for developing sinter-resistant catalysts, catalysts for hydrogen production, ammonia production and carbon dioxide valorization. The book also highlights the developments towards electropromoted dispersed catalysts and for self-sustained electrochemical promotion which are currently expanding. This authoritative analysis of EPOC is useful for various scientific communities working at the interface of heterogeneous catalysis, solid state electrochemistry and materials science. It is of particular interest to groups whose research focuses on developments towards a better and more sustainable future.

Completely revised and expanded throughout, Mixed Surfactant Systems, Second Edition surveys the latest results, newest experimental perspectives, and theoretical investigations of properties, behavior, and techniques applicable to mixed surfactant systems. This important book elucidates core theoretical notions while summarizing results of cutting-edge studies in nanoscale phase separation at monolayers of mixed amphiphiles, nanocapsule preparation through mixtures of cationic and anionic polymer amphiphiles, and the photodegradation of mixed surfactant systems by titanium dioxide. The book provides new sections on topics including: -Diffusion of mixed micelles -Mixed micelles of fluorinated and conventional surfactants -Sponge-like vesicles of mixed surfactants -Liquid crystals of mixed surfactants -Mixtures of surfactants and polymers -Photolysis of mixed surfactants Reflecting the abundance of current and emerging applications in the field, Mixed Surfactant Systems, Second Edition compiles chapters written by world-renowned leaders in industry for an up-to-date scientific account of the dynamics of mixed surfactant systems, including physicochemical properties and behavior of surfactant mixtures in detergency and surfactant precipitation.

Membrane science and technology is an expanding field and has become a prominent part of many activities within the process industries. It is relatively easy to identify the success stories of membranes such as desali nation and microfiltration and to refer to others as developing areas. This, however, does not do justice to the wide field of separations in which membranes are used. No other 'single' process offers the same potential and versatility as that of membranes. The word separation classically conjures up a model of removing one component or species from a second component, for example a mass transfer process such as distillation. In the field of synthetic membranes, the terminology 'separation' is used in a wider context. A range of separations of the chemical/mass transfer type have developed around the use of membranes including distillation, extraction, absorption, adsorption and stripping, as well as separations of the physical type such as filtration. Synthetic membranes are an integral part of devices for analysis, energy generation and reactors (cells) in the electrochemical industry."

The book entails investigative methods for better understanding of the degradation process and uses of high performance paints formulation and also compares them on mild steel (MS) and weathering steel (WS) through various AC/DC electrochemical test methods and surface characterization through electron microscopy, XRD and Raman spectroscopy. This book also deals with the corrosion studies undertaken considering three phases (solid, liquid and gas) with latest techniques and the emphasis has also been given on degradation of materials due to atmospheric corrosion as this is of immense interest to present engineers and researchers. MS has got versatile application as structural steel for construction of buildings, bridges, flyovers, pipelines etc. But this is very much prone to corrosion in industrial and marine environments in presence of harmful pollutants and other industrial effluents in addition to normal humid atmosphere. These corrosion problems are much severe in a tropical country like India with vast coastline. MS corrodes relatively faster and thus leads to colossal loss in every year and to reduce this loss some kind of protection in the form of paints and coatings is always used. Painting is an effective means but quite costly amounting 10-15% of the initial construction cost of superstructures besides cost of repainting at regular interval.

Volume 23 of Advances in Chemical Engineering covers the active field of process synthesis. There are currently three prevelant approaches to complex process synthesis strategies: heuristics-based selection, geometric representation, and optimization methods. This volume addresses a variety of these synthesis strategies for process subsystems, representing only a sample of the state-of-the-art of process synthesis research. The five papers in this volume address quite different process subsystems and application areas but still combine basic concepts related to a systematic approach. All five of the papers develop successful synthesis methods for their respective cutting-edge applications. As a group, the papers serve to highlight many unresolved issues in process synthesis and also provide guidelines for future research.
Key Features
* Considers current approaches to process synthesis problems
* Examines areas of possible future research
* Articles written by leading experts in the field

This book is tailored designed for both researchers as well as academics teaching or introducing Advanced Manufacturing course to their classrooms. It presents the current state of research in this field of research and major challenges identified so far, for the integration of additive manufacturing into chemical processes. Unique capability of transforming materials into functional devices with specific geometry using the emerging additive manufacturing technologies has stimulated significant interest in biology, engineering and materials science, to provide custom-made designs for tailored applications. However, the applications of this emerging technology in the field of chemical sciences and engineering have started very recently. Therefore, the major focus of this book is to introduce the basic principles of additive manufacturing practices as well as advent into conventional chemical processes and various unit operations. The potential advantage of introducing these additive manufacturing technologies has the potential to scale down large scale chemical processes into small scale, which offers several advantages including lower foot print, waste reduction and efficient heat integration as well as distributed chemical manufacturing.

This reference outlines the fundamental concepts and strategies for economic assessments for informed management decisions in industry. The book illustrates how to prepare capital cost and operating expense estimates, profitability analyses, and feasibility studies, and how to execute sensitivity and uncertainty assessments. From financial reports to opportunity costs and engineering trade-offs, Process Engineering Economics considers a wide range of alternatives for profitable investing and for projecting outcomes in various chemical and engineering fields. It also explains how to monitor costs, finances, and economic limitations at every stage of chemical project design, preparation, and evaluation.

Describes more than 1500 emulsifying agents currently available for industrial use. It has been compiled from information received from manufacturers and distributors of these products. Emulsifiers find use in industries such as food processing, drilling fluids, cosmetics, pharmaceuticals, heavy duty cleaners, textile manufacture, pulp and paper processing, adhesives, sealants, and agricultural products. The book lists the following information for each product, as available in the manufacturer's own words: Company Name, Product Category, Trade Name, Product Number, Product Description. Forty-six companies are represented. Also included are Chemical and Trade Name Indices and Suppliers' Addresses.