New Synthetic Routes to Polyoxometalate Containing Ionic Liquids - An Investigation of their Properties (Paperback, 2015 ed.)

In his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and Moessbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials.

General

Imprint:	Springer Spektrum
Country of origin:	Germany
Series:	BestMasters
Release date:	February 2015
First published:	2015
Authors:	Sven Herrmann
Dimensions:	210 x 148 x 9mm (L x W x T)
Format:	Paperback
Pages:	122
Edition:	2015 ed.
ISBN-13:	978-3-658-08795-1
Categories:	Books > Science & Mathematics > Chemistry > Inorganic chemistry > General Books > Science & Mathematics > Chemistry > Physical chemistry > Catalysis Books > Professional & Technical > Industrial chemistry & manufacturing technologies > Industrial chemistry > General Promotions
LSN:	3-658-08795-1
Barcode:	9783658087951

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