Alistair Lennox's thesis reports on the reactivity of organotrifluoroborates, which are becoming increasingly important reagents in synthesis. The thesis is divided into three sections. The first section describes a method for preparing organotrifluoroborates. The second section reports on a mechanistic investigation into the main application of RBF3K reagents as coupling partners in Suzuki-Miyaura coupling, phenomena identified as arising from organotrifluoroborate hydrolysis and fluoride release. The final section reports on a detailed investigation into the hydrolysis mechanism, a prerequisite for their Suzuki-Miyaura coupling, and how it may be predicted and controlled. This research has uncovered many interesting and useful details and shows how problems associated with Suzuki-Miyaura coupling can best be addressed. There has already been wide industrial uptake of the new procedures and insights. The broad nature and clear and succinct style will make the thesis a valuable resource for anyone working in synthesis, organometallic chemistry, or in homogeneous catalysis.

This book comprehensively details the applications of ionic liquids in rare earth green separation and utilization based on the unique interactions of ionic liquids with rare earth ions. It consists of nine chapters demonstrating the synthesis and properties of ionic liquids, coordination chemistry of ionic liquids and rare earth, ionic liquids as diluents, extractants, adsorption resins for rare earth extraction and separation, electrodeposition of rare earth metals in ionic liquids, and preparation of rare earth material with the aid of ionic liquids. It is both interesting and useful to chemists, metallurgists and graduate students working on fundamental research of ionic liquids as well as professionals in the rare earth industry. It provides considerable insights into green chemistry and sustainable processes for rare earth separation in order to meet the environmental challenge of rare earth metallurgy around the globe, especially in China. Ji Chen is a Professor of Chemistry at the Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, China.

This book gives background information why shale formations in the world are important both for storage capacity and enhanced gas recovery (EGR). Part of this book investigates the sequestration capacity in geological formations and the mechanisms for the enhanced storage rate of CO2 in an underlying saline aquifer. The growing concern about global warming has increased interest in geological storage of carbon dioxide (CO2). The main mechanism of the enhancement, viz., the occurrence of gravity fingers, which are the vehicles of enhanced transport in saline aquifers, can be visualized using the Schlieren technique. In addition high pressure experiments confirmed that the storage rate is indeed enhanced in porous media. The book is appropriate for graduate students, researchers and advanced professionals in petroleum and chemical engineering. It provides the interested reader with in-depth insights into the possibilities and challenges of CO2 storage and the EGR prospect.

This book brings together recent research from across the world on enriched methane, and examines the production, distribution and use of this resource in internal combustion engines and gas turbines. It aims to provide readers with an extensive account of potential technological breakthroughs which have the capacity to revolutionize energy systems. Enriched methane, a gas mixture composed by methane and hydrogen (10-30%vol), constitutes the first realistic step towards the application of hydrogen as an energy vector. It provides strong benefits in terms of emissions reduction, that is -11% of CO2, eq emission with the combustion of a 30%vol H2 mixture, if hydrogen is produced from renewable energy sources. Enriched methane offers the following advantages:* it can be produced at competitive costs; * it can be distributed by means of the medium pressure natural gas grid;* it can be stored in traditional natural gas storage systems; <* it can feed natural gas internal combustion engine, improving conversion efficiency. This book is intended for academics in chemical engineering and energy production, distribution and storage. It is also intended for energy producers, engineering companies and R&D organizations.

This book explores the Energy Minimization Multi-scale (EMMS) theory and the drag model for heterogeneous gas-solid fluidized flows. The results show that the cluster density plays a critical role with regard to drag. A novel cluster model is proposed and indicates that the profile of cluster density is single-peaked with the maximum value located at solid concentrations of 0.1~0.15. The EMMS theory is improved with the cluster model and an accurate drag model is developed. The model's universality is achieved by investigating the relationship between the heterogeneity and flow patterns. The drag model is subsequently verified numerically and experimentally.

The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field.

Providing a critical and extensive compilation of the downstream processes of natural gas that involve the principle of gas processing , transmission and distribution, gas flow and network analysis, instrumentation and measurement systems and its utilisation, this book also serves to enrich readers understanding of the business and management aspects of natural gas and highlights some of the recent research and innovations in the field. Featuring extensive coverage of the design and pipeline failures and safety challenges in terms of fire and explosions relating to the downstream of natural gas technology, the book covers the needs of practising engineers from different disciplines, who may include project and operations managers, planning and design engineers as well as undergraduate and postgraduate students in the field of gas, petroleum and chemical engineering. This book also includes several case studies to illustrate the analysis of the downstream process in the gas and oil industry. Of interest to researchers is the field of flame and mitigation of explosion: the fundamental processes involved are also discussed, including outlines of contemporary and possible future research and challenges in the different fields.

Transformation and Utilization of Carbon Dioxide shows the various organic, polymeric and inorganic compounds which result from the transformation of carbon dioxide through chemical, photocatalytic, electrochemical, inorganic and biological processes. The book consists of twelve chapters demonstrating interesting examples of these reactions, depending on the types of reaction and catalyst. It also includes two chapters dealing with the utilization of carbon dioxide as a reaction promoter and presents a wide range of examples of chemistry and chemical engineering with carbon dioxide. Transformation and Utilization of Carbon Dioxide is a collective work of reviews illustrative of recent advances in the transformation and utilization of carbon dioxide. This book is interesting and useful to a wide readership in the various fields of chemical science and engineering. Bhalchandra Bhanage is a professor of industrial and engineering chemistry at Institute of Chemical Technology, India. Masahiko Arai is a professor of chemical engineering at Hokkaido University, Japan.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal

The two volumes of Handbook of Gas Sensor Materials provide a detailed and comprehensive account of materials for gas sensors, including the properties and relative advantages of various materials. Since these sensors can be applied for the automation of myriad industrial processes, as well as for everyday monitoring of such activities as public safety, engine performance, medical therapeutics, and in many other situations, this handbook is of great value. Gas sensor designers will find a treasure trove of material in these two books.

This book is a compendium of the finest research in nanoplasmonic sensing done around the world in the last decade. It describes basic theoretical considerations of nanoplasmons in the dielectric environment, gives examples of the multitude of applications of nanoplasmonics in biomedical and chemical sensing, and provides an overview of future trends in optical and non-optical nanoplasmonic sensing. Specifically, readers are guided through both the fundamentals and the latest research in the two major fields nanoplasmonic sensing is applied to - bio- and chemo-sensing - then given the state-of-the-art recipes used in nanoplasmonic sensing research.

This book is a comprehensive review of high-temperature polymer electrolyte membrane fuel cells (PEMFCs). PEMFCs are the preferred fuel cells for a variety of applications such as automobiles, cogeneration of heat and power units, emergency power and portable electronics. The first 5 chapters of the book describe rationalization and illustration of approaches to high temperature PEM systems. Chapters 6 - 13 are devoted to fabrication, optimization and characterization of phosphoric acid-doped polybenzimidazole membranes, the very first electrolyte system that has demonstrated the concept of and motivated extensive research activity in the field. The last 11 chapters summarize the state-of-the-art of technological development of high temperature-PEMFCs based on acid doped PBI membranes including catalysts, electrodes, MEAs, bipolar plates, modelling, stacking, diagnostics and applications.

In this thesis Christian Sohar describes his investigation into the gigacycle fatigue behavior of tool steels. In an interdisciplinary approach he uses knowledge and methods from a wide variety of disciplines including materials science, metallurgy, chemistry, physics and mechanical engineering. Christian gives a general introduction into steel tools and fatigue in materials. Later he extensively discusses the experimental techniques and results. Indeed it is the detail of the content in this thesis which makes it an invaluable resource for students entering the field and scientists working in related disciplines. Overall, the thesis helps us understand more about the mechanical behavior of metallic materials with complex microstructure and high hardness.

This book is written for scientists involved in the calibration of viscometers. A detailed description for stepping up procedures to establish the viscosity scale and obtaining sets of master viscometers is given in the book. Uncertainty considerations for standard oils of known viscosity are presented. The modern viscometers based on principles of tuning fork, ultrasonic, PZT, plate waves, Love waves, micro-cantilever and vibration of optical fiber are discussed to inspire the reader to further research and to generate improved versions. The primary standard for viscosity is pure water. Measurements of its viscosity with accuracy/uncertainty achieved are described. The principles of rotational and oscillation viscometers are explained to enhance the knowledge in calibration work. Devices used for specific materials and viscosity in non SI units are discussed with respect to the need to correlate viscosity values obtained by various devices. The description of commercial viscometers meets the needs of the user.

An instructive reference that will help control researchers and engineers, interested in a variety of industrial processes, to take advantage of a powerful tuning method for the ever-popular PID control paradigm. This monograph presents explicit PID tuning rules for linear control loops regardless of process complexity. It shows the reader how such loops achieve zero steady-position, velocity, and acceleration errors and are thus able to track fast reference signals. The theoretical development takes place in the frequency domain by introducing a general-transfer-function-known process model and by exploiting the principle of the magnitude optimum criterion. It is paralleled by the presentation of real industrial control loops used in electric motor drives. The application of the proposed tuning rules to a large class of processes shows that irrespective of the complexity of the controlled process the shape of the step and frequency response of the control loop exhibits a specific performance. This specific performance, along with the PID explicit solution, formulates the basis for developing an automatic tuning method for the PID controller parameters which is a problem often met in many industry applications-temperature, pH, and humidity control, ratio control in product blending, and boiler-drum level control, for example. The process of the model is considered unknown and controller parameters are tuned automatically such that the aforementioned performance is achieved. The potential both for the explicit tuning rules and the automatic tuning method is demonstrated using several examples for benchmark process models recurring frequently in many industry applications.

The use of isoconversional kinetic methods for analysis of thermogravimetric and calorimetric data on thermally stimulated processes is quickly growing in popularity. The purpose of this book is to create the first comprehensive resource on the theory and applications of isoconversional methodology. The book introduces the reader to the kinetics of physical and chemical condensed phase processes that occur as a result of changing temperature and discusses how isoconversional analysis can provide important kinetic insights into them. The book will help the readers to develop a better understanding of the methodology, and promote its efficient usage and successful development.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

This concise volume explains when to procure new equipment, how to prepare specifications for floating inquiries, and guidelines for detailed technical discussions with vendors in the chemical and related industries. It covers the common equipment and supplies used in chemical plants, refineries-please delete reference to refineries, and effluent treatment facilities such as pumps, blowers, reactors, heat exchangers, waste heat recovery boilers, heat and acid resistant lining etc. The book serves as a checklist to the plant managements for procurement of the correct equipment in the most efficient timeframe insuring that projects are not delayed due to long time required for procurement of new equipment.

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Methanol: Science and Engineering provides a comprehensive review of the chemistry, properties, and current and potential uses and applications of methanol. Divided into four parts, the book begins with a detailed account of current production methods and their economics. The second part deals with the applications of methanol, providing useful insights into future applications. Modeling of the various reactor systems is covered in the next section, with final discussions in the book focusing on the economic and environmental impact of this chemical. Users will find this to be a must-have resource for all researchers and engineers studying alternative energy sources.

Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts presents a complete overview of the selective catalytic reduction of NOx by ammonia/urea. The book starts with an illustration of the technology in the framework of the current context (legislation, market, system configurations), covers the fundamental aspects of the SCR process (catalysts, chemistry, mechanism, kinetics) and analyzes its application to useful topics such as modeling of full scale monolith catalysts, control aspects, ammonia injections systems and integration with other devices for combined removal of pollutants.

The Role of Metals and Ligands in Organic Hydroformylation, by Luca Gonsalvi, Antonella Guerriero, Eric Monflier, Frédéric Hapiot, Maurizio Peruzzini. Hydroformylation in Aqueous Biphasic Media Assisted by Molecular Receptors, by Frédéric Hapiot, Hervé Bricout, Sébastien Tilloy, Eric Monflier. Asymmetric Hydroformylation, by Bernabé F. Perandones, Cyril Godard, Carmen Claver. Domino Reactions Triggered by Hydroformylation, by Elena Petricci, Elena Cini. Rhodium-Catalyzed Hydroformylation in Fused Azapolycycles Synthesis, by Roberta Settambolo. Hydroformylation in Natural Product Synthesis, by Roderick W. Bates, Sivarajan Kasinathan.

This Brief describes the influence of the different organic chelating agents on the topography, physical properties and phases of SPPS-deposited spinel ferrite splats. The author describes how by using the SPPS process, the coating is produced directly from a solution precursor and how all physical and chemical reactions such as evaporation, decomposition, crystallization and coating formation occur in a single step. The author details not only the innovative approach to liquid feeding, but also focuses on its effects on the spinel ferrite system. The results of experimentation as well as detailed explanations of the experiments are included.

The need for batteries has grown exponentially in response to the increase in global energy demand and to the ambitious goals that governments have set up for sustainable energy development worldwide, especially in developed countries. While lithium-ion batteries currently dominate the energy storage market, the limited and unevenly distributed lithium resources have caused huge concerns over the sustainability of the lithium-ion battery technology. Sodium-ion batteries have significant benefits over lithium-ion batteries, including sodium's abundance in the Earth's crust. These batteries have therefore gained research interest, and efforts are being made to use them in place of lithium-ion batteries. While the past decade has witnessed significant research advances and breakthroughs in developing the sodium-ion battery technology, there still remain fundamental challenges that must be overcome to push the technology forward. This book comprises 13 chapters that discuss the fundamental challenges, electrode materials, electrolytes, separators, advanced instrumental analysis techniques, and computational methods for sodium-ion batteries from renowned scientists. The book is a unique combination of all aspects associated with sodium-ion batteries and can therefore be used as a handbook.