Precise measurements of the calcium (Ca) isotopes have provided
constraints on Ca cycling at global and local scales, and
quantified rates of carbonate diagenesis in marine sedimentary
systems. Key to applying Ca isotopes as a geochemical tracer of Ca
cycling, carbonate (bio)mineralization, and diagenesis is an
understanding of the impact of multiple factors potentially
impacting Ca isotopes in the rock record. These factors include
variations in stable isotopic fractionation factors, the influence
of local-scale Ca cycling on Ca isotopic gradients in carbonate
settings, carbonate dissolution and reprecipitation, and the
relationship between the Ca isotopic composition of seawater and
mineral phases that record the secular evolution of seawater
chemistry.
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