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Advances in Carbene Chemistry, Volume 2 (Hardcover)
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Advances in Carbene Chemistry, Volume 2 (Hardcover)
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Beginning as chemical curiosities, carbenes are now solidly
established as reactive intermediates with fascinating and
productive research areas of their own. Five decades of divalent
carbon chemistry have provided us with a vast repertoire of new,
unusual and surprising reactions. Some of those reactions, once
classified as exotic, have become standard methods in organic
synthesis. These highly reactive carbene species have been
harnessed and put to work to achieve difficult synthetic tasks that
other reactive intermediates cannot easily perform.
The fruitful relationship between experiment and theory has pushed
carbene chemistry further toward the direction of reaction control;
that is, regio- and stereoselectivity in intra- and intermolecular
addition and insertion reactions. The interplay between experiment
and modern spectroscopy has led to the characterisation of many
carbenes that are crucial to both an understanding and a further
development of this field.
Understanding of carbene chemistry has advanced dramatically,
especially in the last decade, and new developments continue to
emerge. Some of the recent exciting findings have been collected in
the first volume of "Advances in Carbene Chemistry." With this
second volume, the series will continue to provide a periodic
coverage of carbene chemistry in its broadest sense - leading into
the next century.
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