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Electronic Structure and Magneto-Optical Properties of Solids (Hardcover, 2004 ed.)
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Electronic Structure and Magneto-Optical Properties of Solids (Hardcover, 2004 ed.)
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The aim of this book is to review recent achievements in the
theoretical investigations of the electronic structure, optical,
magneto-optical (MO), and x-ray magnetic circular dichroism (XMCD)
properties of compounds and Multilayered structures. Chapter 1 of
this book is of an introductory character and presents the
theoretical foundations of the band theory of solids such as the
density functional theory for ground state properties of solids
including local density approximation (LDA). It also presents some
modifications to the LDA, such as gradient correction,
self-interaction correction, LDA+U method, orbital polarization
correction, GW approximation, and dynamical mean- field theory. The
description of the magneto-optical effects and linear response
theory are also presented. The book describes the MO properties for
a number of 3d materials, such as elemental ferromagnetic metals
(Fe, Co and Ni) and paramagnetic metals in external magnetic fields
(Pd and Pt), some important 3d compounds such as XPt3 (X=V, Cr, Mn,
Fe and Co), Heusler alloys, chromium spinel chalcogenides, MnB and
strongly correlated magnetite Fe304. theoretical investigations of
the electronic structure, optical and MO properties of transition
metal multilayered structures (MLS). The book presents also the MO
properties of f band ferromagnetic materials: Tm, Nd, Sm, Ce and La
monochalcogenides, some important Yb compounds, SmB6 and Nd3S4,
UFe2, U3X4 (X=P, As, Sb, Bi, Se and Te), UCu2P2, UCuP2, UCuAs2,
UAsSe, URhA1, UGa2 and UPd3. Within the total group of alloys and
compounds, we discuss their MO spectra in relationship to: the
spin-orbit coupling strength, the magnitude of the local magnetic
moment, the degree of hybridization in the bonding, the
half-metallic character, or, equivalently, the Fermi level filling
of the bandstructure, the intraband plasma frequency, and the
influence of the crystal structure. The last chapter results recent
theoretical investigations on the MXCD in various representative
transition metal 4f and 5f systems are presented.
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