Numerous solvents used in chemical processes have poisonous and unsafe properties that pose significant ecological concerns ranging from atmospheric emissions to the contamination of water effluents. To combat these ecological threats, over the course of the past two decades, the field of green chemistry has grown to develop more natural reaction processes and techniques involving the use of nonconventional solvents to diminish waste solvent production and thus decrease negative impact on the environment. Ionic liquids in particular are more environmentally friendly substitutes to conventional solvents, and as such, have seen more widespread use in the past decade. They have been used in such processes as extraction, separation, purification of organic, inorganic, and bioinorganic compounds, reaction media in biochemical and chemical catalysis, green organic and drug synthesis, among other industrial applications. Thus, in proving themselves a suitable greener media for economic viability in chemical processes, ionic liquids are leading to more sustainable development. This edition explores the application of ionic liquids as a green solvent. It contains a state-of-the-art overview on ionic liquids as green solvents for chemical processes and techniques, as well as some of their useful industrial applications.

Globalization and industrialization involve a number of reactions, products, extractions, and separations that require the use of organic solvents. These solvents are responsible for a number of ecological concerns, including atmospheric and land toxicity. Conventional organic solvents are regarded as volatile organic compounds; some are even limited due to their potential for ozone layer depletion. While supercritical liquids exhibit physical properties that could make them ideal substitutes for these volatile compounds, there is particular interest in the use of carbon dioxide as a solvent of crude material. In particular, carbon dioxide has apparent 'green' properties, like its noncombustible nature, the fact that it is generally nonpoisonous, and its relative inertness. Thus, the use of supercritical carbon dioxide can provide practical improvements to the sustainability of industrial products and processes. This book provides in-depth literature in the area of industrial green processes, focusing on the separation, purification, and extraction of compounds utilizing supercritical carbon dioxide as a green solvent.

Traditional methods in synthetic chemistry produce chemical waste and byproducts, yield smaller desired products, and generate toxic chemical substances, but the past two centuries have seen consistent, greener improvements in organic synthesis and transformations. These improvements have contributed to substance handling efficiency by using green-engineered forerunners like sustainable techniques, green processes, eco-friendly catalysis, and have minimized energy consumption, reduced potential waste, improved desired product yields, and avoided toxic organic precursors or solvents in organic synthesis. Green synthesis has the potential to have a major ecological and monetary impact on modern pharmaceutical R&D and organic chemistry fields. This book presents a broad scope of green techniques for medicinal, analytical, environmental, and organic chemistry applications. It presents an accessible overview of new innovations in the field, dissecting the highlights and green chemistry attributes of approaches to green synthesis, and provides cases to exhibit applications to pharmaceutical and organic chemistry. Although daily chemical processes are a major part of the sustainable development of pharmaceuticals and industrial products, the resulting environmental pollution of these processes is of worldwide concern. This edition discusses green chemistry techniques and sustainable processes involved in synthetic organic chemistry, natural products, drug syntheses, as well various useful industrial applications.

This book presents the applications of ion-exchange materials in the chemical and food industries. It includes topics related to the application of ion exchange chromatography in water softening, purification and separation of chemicals, separation and purification of food products and catalysis. This title is a highly valuable source of knowledge on ion-exchange materials and their applications suitable for postgraduate students and researchers but also to industrial R&D specialists in chemistry, chemical, and biochemical technology. Additionally, this book will provide an in-depth knowledge of ion-exchange column and operations suitable for engineers and industrialists.

This book explores key parameters, properties and fundamental concepts of electrocatalysis. It also discusses the engineering strategies, current applications in fuel-cells, water-splitting, metal-ion batteries, and fuel generation. This book elucidates entire category viewpoints together with industrial applications. Therefore, all the sections of this book emphasize the recent advances of different types of electrocatalysts, current challenges, and state-of-the-art studies through detailed reviews. This book is the result of commitments by numerous experts in the field from various backgrounds and expertise and appeals to industrialists, researchers, scientists and in addition understudies from various teaches.

This book exhibits novel semiconductor black phosphorous (BP) materials that are developed beyond other 2D materials (graphene and TMDs). It accurately reviews their manufacture strategies, properties, characterization techniques and different utilizations of BP-based materials. It clarifies all perspectives alongside down to earth applications which present a future direction in the biomedical, photo, environmental, energy, and other related fields. Hence, the sections accentuate the basic fundamentals, synthesis, properties, applications, state-of-the-art studies about the BP-based materials through detailed reviews. This book is the result of commitments by numerous experts in the field from various backgrounds and expertise. It will appeal to researchers, scientists and in addition understudies from various teaches, for example, semiconductor innovation, energy and environmental science. The book content incorporates industrial applications and fills the gap between the exploration works in the lab and viable applications in related ventures.

This volume explores the latest developments in the area of polymer electrolyte membranes (PEMs) used for high-temperature fuel cells. Featuring contributions from an international array of researchers, it presents a unified viewpoint on the operating principles of fuel cells, various methodologies used for the fabrication of PEMs, and issues related to the chemical and mechanical stabilities of the membranes. Special attention is given to the fabrication of electrospun nanocomposite membranes. The editors have consciously placed an emphasis on developments in the area of fast-growing and promising PEM materials obtained via hygroscopic inorganic fillers, solid proton conductors, heterocyclic solvents, ionic liquids, anhydrous H3PO4 blends, and heteropolyacids. This book is intended for fuel cell researchers and students who are interested in a deeper understanding of the organic-inorganic membranes used in fuel cells, membrane fabrication methodologies, properties and clean energy applications.

This book presents the applications of ion-exchange materials in the area of environmental analysis and treatment. It includes chapters on applications of organic, inorganic and composite ion exchange materials and hexacyanoferrates in various fields such as chemical and biochemical separations, water purification, removal of harmful impurities, dyes and cationic and anionic complexes. This title is a highly valuable source of knowledge on ion-exchange materials and their applications suitable for postgraduate students and researchers but also to industrial R&D specialists in chemistry, chemical, and biochemical technology. Additionally, this book will provide an in-depth knowledge of ion-exchange column and operations suitable for engineers and industrialists.

This book systematically describes free-standing films and self-supporting nanoarrays growing on rigid and flexible substrates, and discusses the numerous applications in electronics, energy generation and storage in detail. The chapters present the various fabrication techniques used for growing self-supporting materials on flexible and rigid substrates, and free-standing films composed of semiconductors, inorganic, polymer and carbon hybrid materials.

Advanced materials and nanotechnology is a promising, emerging field involving the use of nanoparticles to facilitate the detection of various physical and chemical parameters, including temperature, humidity, pH, metal ion, anion, small organic or inorganic molecules, gases, and biomolecules responsible for environmental issues that can lead to diseases like cancer, diabetes, osteoarthritis, bacterial infections, and brain, retinal, and cardiovascular diseases. By monitoring environmental samples and detecting these environmental issues, advanced nanotechnology in this type of sensory technology is able to improve daily quality of life. Although these sensors are commercially available for the detection of monovalent cations, anions, gases, volatile organic molecules, heavy metal ions, and toxic metal ions, many existing models require significant power and lack advanced technology for more quality selectivity and sensitivity. There is room in these sensors to optimize their selectivity, reversibility, on/off ratio, response time, and their environmental stability in real-world operating conditions. This book explores the methods for the development and design of environmentally-friendly, simple, reliable, and cost effective electrochemical nanosensors using powerful nanostructured materials. More specifically, it highlights the use of various electrochemical-based biosensor sensors involved in the detection of monovalent cations, anions, gases, volatile organic molecules, heavy metal ions, and toxic metal ions, with the ultimate goal of seeing these technologies reach market.

This book provides an overview of the sources, occurrence, fate and solution of microplastics. Microplastics in sediment and soil environment have been only scarcely surveyed, and no profound discussion on microplastics removal is summarized until this book. Here we focus on sharing clear schematic information and the book sufficiently supports important microplastic topics: such as microbial network, microplastic toxicology and accumulation, agricultural plastics, nylon microplastics, polystyrene microplastics, polyethylene microplastics and many more. The book mainly provides an overview of recent advances in knowledge of sources, occurrence, distribution, chemical behavior and ecological threats while it also presents information related to feasible solutions for microplastic pollution management. This comprehensive resource will be valuable up-to-date knowledge for environmental scientists, ecotoxicologists, ecologists, marine biologists, environmental chemists in the academic field and this book is intended to be beneficial information for environmental managers, water suppliers, wastewater treatment, plastics manufacturer, and policy makers as well.

This book presents sustainable synthetic pathways and modern applications of ammonia. It focuses on the production of ammonia using various catalytic systems and its use in fuel cells, membrane, agriculture, and renewable energy sectors. The book highlights the history, investigation, and development of sustainable pathways for ammonia production, current challenges, and state-of-the-art reviews. While discussing industrial applications, it fills the gap between laboratory research and viable applications in large-scale production.

This book presents sources of carbon dioxide emission, related environmental issues and methods for carbon dioxide utilization, storage, analysis, modeling and optimization. This first volume focused on biochemical methods of carbon dioxide sequestration such as forestry, biomineralization, geo-chemo-mechanical, mangrove plantation and biowaste.

This book summarizes recent developments in epoxy blends. It emphasizes new challenges for the synthesis, characterization, and properties of biofibers and biopolymers. It provides updates on all the important areas of biofibers and biopolymers in a comprehensive fashion, including synthesis, processing, characterisation and application. It provides a a one-stop reference for researchers and those working in industry and government. The book correlates macro, micro and nanostructure properties. Moreover, it provides cutting edge research from experts around the globe. The current status, trends, future directions and opportunities are discussed in detail, making the book also accessible for beginners to the subject and young researchers.

This book discusses various aspects of graphene fictionalization strategies from inorganic oxides and organic moieties including preparation, design, and characterization of functionalization material and its applications. Including illustrations and tables summarizing the latest research on manufacturing, design, characterization and applications of graphene functionalization, it describes graphene functionalization using different techniques and materials and highlights the latest technologies in the field of manufacturing and design. This book is a valuable reference resource for lecturers, students, researchers and industrialists working in the field of material science, especially polymer composites.

This book presents materials and physical methods for carbon dioxide sequestration. Materials include nanosponges, titanium oxide/zeolite hybrids, classical absorbents, metal oxides, ionic liquids, alkaline soils and metal organic frameworks. Methods include cryogenic capture, adsorption, solvent dissolution and soil sequestration.

This book discusses the fundamental of bending actuation with a focus on ionic metal composites. It describes the applications of ionic polymer metal composite (IPMC) actuators, from conventional robotic systems to compliant micro robotic systems used to handle the miniature and fragile components during robotic micro assembly. It also presents mathematical modelings of actuators for engineering, biomedical, medical and environmental systems. The fundamental relation of IPMC actuators to the biomimetic systems are also included.

Advanced Applications of Ionic Liquids discusses the intersection of nanotechnology with ionic liquids (ILs) and materials, along with opportunities for advanced engineering applications in various research fields. Novel materials at nano scales with ILs creates an upsurge in the thermal and electrochemical constancy of the nano scale particles, making them ideal for industrial applications. The implementation of ILs at nano scale includes an interaction of constituents, which is beneficial for electron transfer reactions. These new composites can be implemented as sensors, electronics, catalysts and photonics. Including ILs in polymer composites enhance electrochemical consistency, govern particle size, upsurge conductivity, reduce toxicity, and more. This book is a comprehensive reference for researchers working with IL based technologies for environmental and energy applications.

This book presents materials and physical methods for carbon dioxide sequestration. Materials include nanosponges, titanium oxide/zeolite hybrids, classical absorbents, metal oxides, ionic liquids, alkaline soils and metal organic frameworks. Methods include cryogenic capture, adsorption, solvent dissolution and soil sequestration.

Numerous solvents used in chemical processes have poisonous and unsafe properties that pose significant ecological concerns ranging from atmospheric emissions to the contamination of water effluents. To combat these ecological threats, over the course of the past two decades, the field of green chemistry has grown to develop more natural reaction processes and techniques involving the use of nonconventional solvents to diminish waste solvent production and thus decrease negative impact on the environment. Ionic liquids in particular are more environmentally friendly substitutes to conventional solvents, and as such, have seen more widespread use in the past decade. They have been used in such processes as extraction, separation, purification of organic, inorganic, and bioinorganic compounds, reaction media in biochemical and chemical catalysis, green organic and drug synthesis, among other industrial applications. Thus, in proving themselves a suitable greener media for economic viability in chemical processes, ionic liquids are leading to more sustainable development. This edition explores the application of ionic liquids as a green solvent. It contains a state-of-the-art overview on ionic liquids as green solvents for chemical processes and techniques, as well as some of their useful industrial applications.

Globalization and industrialization involve a number of reactions, products, extractions, and separations that require the use of organic solvents. These solvents are responsible for a number of ecological concerns, including atmospheric and land toxicity. Conventional organic solvents are regarded as volatile organic compounds; some are even limited due to their potential for ozone layer depletion. While supercritical liquids exhibit physical properties that could make them ideal substitutes for these volatile compounds, there is particular interest in the use of carbon dioxide as a solvent of crude material. In particular, carbon dioxide has apparent 'green' properties, like its noncombustible nature, the fact that it is generally nonpoisonous, and its relative inertness. Thus, the use of supercritical carbon dioxide can provide practical improvements to the sustainability of industrial products and processes. This book provides in-depth literature in the area of industrial green processes, focusing on the separation, purification, and extraction of compounds utilizing supercritical carbon dioxide as a green solvent.

Advanced materials and nanotechnology is a promising, emerging field involving the use of nanoparticles to facilitate the detection of various physical and chemical parameters, including temperature, humidity, pH, metal ion, anion, small organic or inorganic molecules, gases, and biomolecules responsible for environmental issues that can lead to diseases like cancer, diabetes, osteoarthritis, bacterial infections, and brain, retinal, and cardiovascular diseases. By monitoring environmental samples and detecting these environmental issues, advanced nanotechnology in this type of sensory technology is able to improve daily quality of life. Although these sensors are commercially available for the detection of monovalent cations, anions, gases, volatile organic molecules, heavy metal ions, and toxic metal ions, many existing models require significant power and lack advanced technology for more quality selectivity and sensitivity. There is room in these sensors to optimize their selectivity, reversibility, on/off ratio, response time, and their environmental stability in real-world operating conditions. This book explores the methods for the development and design of environmentally-friendly, simple, reliable, and cost effective electrochemical nanosensors using powerful nanostructured materials. More specifically, it highlights the use of various electrochemical-based biosensor sensors involved in the detection of monovalent cations, anions, gases, volatile organic molecules, heavy metal ions, and toxic metal ions, with the ultimate goal of seeing these technologies reach market.

This book systematically describes free-standing films and self-supporting nanoarrays growing on rigid and flexible substrates, and discusses the numerous applications in electronics, energy generation and storage in detail. The chapters present the various fabrication techniques used for growing self-supporting materials on flexible and rigid substrates, and free-standing films composed of semiconductors, inorganic, polymer and carbon hybrid materials.