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Organic molecules are the proficient materials which have been used
in Organic field effect transistors and organic thin film
transistors. Among the extensive range of ET materials reported in
the literatures, the materials based on oxadiazole were supposed to
be among the most effective ones. This book deals with Density
Functional Theory (DFT) which is well suited to explore the
properties of the conjugated -electron systems. We report the
ground-state geometry optimizations of newly designed oxadiazole
based oligomers using the DFT method with B3LYP functional and
6-31G** basis set. The relevant absorption spectra computed at the
TD-B3LYP/6-31G** level of theory. The electronic, photophysical and
charge transfer properties have been discussed in detail. The
effect of electron deactivating group at different positions has
been investigated and discussed."
This book describes the synthesis and characterization using
proton-NMR, IR, CHNS analyzer, single crystal X-ray diffractometer
and quantum chemical studies of novel derivatives of
5-aminotetrazole. The reactions involving acid chlorides were
performed in inert atmosphere. The reactions with sulfonyl
chlorides gave products with cleaved tetrazole ring structure. In
1H NMR spectrums, aromatic protons were observed at 7.4-7.9 ppm in
all derivatives. The density functional theory has been used to
investigate the geometric and electronic properties of all the
compounds. The B3LYP/6-311G** level of theory was found better than
the B3LYP/6-31G** level of theory to reproduce the experimental
data. The HOMOs and LUMOs of all the compounds under study were
also calculated.
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