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This book provides comprehensive coverage of nanocomposite materials obtained by the sol-gel method, from synthesis to applications and including design tools for combining different properties. Sol-gel nanocomposites are of great interest in meeting processing and application requirements for the development of multifunctional materials. These materials are already commercialized for a number of applications from scratch-resistant and anti-adhesive coatings to optical materials with active and passive properties. Biomedical applications, holographic recordings, fuel cells and hydrogen storage, resists and catalysts are among the potential uses. The novel mechanical, optical and electronic properties of nanocomposite materials depend not only on the individual component materials, but also on their morphology and nanoscale interfacial characteristics. Sol-gel is a highly versatile method for obtaining both the matrix and the filler of the nanocomposite and for chemically adjusting the interface to optimize structure and properties. Although nanocomposites are widely discussed in the literature, the focus has been mainly on polymer nanocomposites. This book addresses nanocomposites based on inorganic or hybrid organic-inorganic matrices, with an emphasis on the scientific principles which are the basis for nanocomposite sol-gel synthesis and applications. A didactic approach is followed, with different topics developed from a fundamental point of view together with key examples and case studies. First comprehensive treatment of nanocomposites obtained by sol-gel methods Focuses on nanocomposites with inorganic and hybrid organic-inorganic matrices Describes design tools to optimize structure and properties for various applications Covers synthesis, processing, characterization, and modeling Uses first principles to describe the influence of interfacial characteristics on materials properties Presents case studies for both films and bulk applications Provides examples of products on the market, with descriptions of the scientific principles at the base of their success Includes contributions from recognized leaders in this multidisciplinary area.
This book provides comprehensive coverage of nanocomposite materials obtained by the sol-gel method, from synthesis to applications and including design tools for combining different properties. Sol-gel nanocomposites are of great interest in meeting processing and application requirements for the development of multifunctional materials. These materials are already commercialized for a number of applications from scratch-resistant and anti-adhesive coatings to optical materials with active and passive properties. Biomedical applications, holographic recordings, fuel cells and hydrogen storage, resists and catalysts are among the potential uses. The novel mechanical, optical and electronic properties of nanocomposite materials depend not only on the individual component materials, but also on their morphology and nanoscale interfacial characteristics. Sol-gel is a highly versatile method for obtaining both the matrix and the filler of the nanocomposite and for chemically adjusting the interface to optimize structure and properties. Although nanocomposites are widely discussed in the literature, the focus has been mainly on polymer nanocomposites. This book addresses nanocomposites based on inorganic or hybrid organic-inorganic matrices, with an emphasis on the scientific principles which are the basis for nanocomposite sol-gel synthesis and applications. A didactic approach is followed, with different topics developed from a fundamental point of view together with key examples and case studies. First comprehensive treatment of nanocomposites obtained by sol-gel methods Focuses on nanocomposites with inorganic and hybrid organic-inorganic matrices Describes design tools to optimize structure and properties for various applications Covers synthesis, processing, characterization, and modeling Uses first principles to describe the influence of interfacial characteristics on materials properties Presents case studies for both films and bulk applications Provides examples of products on the market, with descriptions of the scientific principles at the base of their success Includes contributions from recognized leaders in this multidisciplinary area.
Sol-gel processing is a low temperature, low cost wet chemistry route to a range of different materials, particularly glassy and ceramic oxides, including nanoparticles and powders, fibers, thin films and membranes, or monoliths and composites. Thin films and coatings represent by far the most important category of sol-gel derived products with optical, electronic and magnetic functionalities, for example photoresist and dielectric spin-on-glass layers, flat screen displays, anti-reflection, conducting and magnetic disk coatings, as well as photochromic, electrochromic and photovoltaic coatings. Sol-gel derived materials are homogeneous at the molecular level and are a good example of a bottom-up approach to materials synthesis. There is increasing need of new optical and photonic materials with improved performance, where molecular level homogeneity and easy fabrication in film form may be especially convenient, highlighting a decisive advantage of sol-gel over other more established technologies to obtain graded index optical components, solar control coatings, phosphors, glass ceramics or multilayer photonic structures. There is no book available yet which focuses in particular on optical and photonic sol-gel derived materials. This is what makes this book unique at this point for those especially or exclusively interested in optical and photonic functional materials and applications. This book represents an important tool to update scientists and engineers with recent advances in the rapidly evolving field of optical and photonic materials, components and devices. Our target audience are those working in materials science, physics, engineering and chemistry disciplines, in particular academics and researchers working in advanced optical/photonic processing technologies, research and development engineers in high technology industries and research project leaders. This book will also be an essential tool for graduate students pursuing a PhD or even a Master's degree.
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