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Water in the proximity of a surface (interfacial water) is abundant
on the earth. It is involved in various physical and chemical
processes and crucial for biological function. Despite numerous
studies of interfacial water, systematic analysis of its properties
is missing in scientific literature. This book is a first
comprehensive review of experimental and simulation studies of
water in various confining environments, such as hydrophilic and
hydrophobic surfaces, surfaces of biomolecules, porous media, etc.
Systematic analysis of interfacial and confined water is based on
the firm physical ground, which accounts for variety of the
thermodynamic states of water near the surface, surface phase
transitions, surface critical behaviour, effect of confinement on
the bulk and surface phase transitions of water, clustering and
formation of a spanning hydrogen-bonded water network via
percolation transition. This allows distinguishing between
universal features, common for all fluids, and some specific water
properties, related to intermolecular hydrogen bonds. Special
attention is paid to the properties of hydration water, which
covers biomolecules and enables their biological activity. This
book provides readers with basic information on interfacial and
confined water, which will be useful for scientists and engineers
working in the fields of bioscienses, nanociences and
nanotechnologies.
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