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Providing new insights into the molecular and electronic processes
involved in the conversion of sunlight into chemical products,
Photoelectrochemical Solar Conversion Systems: Molecular and
Electronic Aspects begins with an historical overview and a survey
of recent developments in the electrochemistry of semiconductors
and spectroscopic techniques. It then provides a comprehensive
introduction to the science of conversion cells, reviews current
issues and potential directions, and covers a wide range of
materials from organic to inorganic cells. Employing a tutorial
organization with balanced coverage of electrochemistry and solar
energy conversion, this book covers: The conversion of sunlight
into chemical energy and different actual conversion concepts
Electrochemical methods for the construction and characterization
of electrolyte-metal-oxide-semiconductor contacts (EMOS) in the
nanodimensions, the so-called nano-emitter concept, including the
electrochemical formation of metal clusters of catalytic metals and
the formation of passivating layers by anodization The fundamentals
of electrocatalysis with emphasis on the hydrogen evolution
reaction and the electrochemical CO2 reduction Classical and
quantum mechanical theories of electron transfer reactions in
metal-electrolyte interfaces and their relation with surface
electronics The physicochemical characterization of the model
system Si-SiOx-metal-electrolyte by means of modern
electrochemical, surface, and spectroscopic methods Improvements of
conversion efficiency by means of optical effects, for example, the
generation of surface plasmons by nano-dimensioned arrangements of
optically active metals
Providing new insights into the molecular and electronic processes
involved in the conversion of sunlight into chemical products,
Photoelectrochemical Solar Conversion Systems: Molecular and
Electronic Aspects begins with an historical overview and a survey
of recent developments in the electrochemistry of semiconductors
and spectroscopic techniques. It then provides a comprehensive
introduction to the science of conversion cells, reviews current
issues and potential directions, and covers a wide range of
materials from organic to inorganic cells. Employing a tutorial
organization with balanced coverage of electrochemistry and solar
energy conversion, this book covers: The conversion of sunlight
into chemical energy and different actual conversion concepts
Electrochemical methods for the construction and characterization
of electrolyte-metal-oxide-semiconductor contacts (EMOS) in the
nanodimensions, the so-called nano-emitter concept, including the
electrochemical formation of metal clusters of catalytic metals and
the formation of passivating layers by anodization The fundamentals
of electrocatalysis with emphasis on the hydrogen evolution
reaction and the electrochemical CO2 reduction Classical and
quantum mechanical theories of electron transfer reactions in
metal-electrolyte interfaces and their relation with surface
electronics The physicochemical characterization of the model
system Si-SiOx-metal-electrolyte by means of modern
electrochemical, surface, and spectroscopic methods Improvements of
conversion efficiency by means of optical effects, for example, the
generation of surface plasmons by nano-dimensioned arrangements of
optically active metals
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