This updated edition presents topical knowledge and technologies for the thermal, chemo- and enzymatic-catalytic conversion of biomass into chemicals, materials and fuels. International experts from academia and industry cover the complete value chain from raw materials into final products. A new focus discusses feedstock, processes and products in potential concepts of future biorefining.

This book provides an analysis of the reaction mechanisms relevant to a number of processes in which CO2 is converted into valuable products. Several different processes are considered that convert CO2 either in specialty chemicals or in bulk products or fuels. For each reaction, the mechanism is discussed and the assessed steps besides the dark sites of the reaction pathway are highlighted. From the insertion of CO2 into E-X bonds to the reduction of CO2 to CO or other C1 molecules or else to C2 or Cn molecules, the reactions are analysed in order to highlight the known and obscure reaction steps. Besides well known reaction mechanisms and energy profiles, several lesser known situations are discussed. Advancing knowledge of the latter would help to develop efficient routes for the conversion of CO2 into valuable products useful either in the chemical or in the energy industry. The content of this book is quite different from other books reporting the use of CO2. On account of its clear presentation, "Reaction Mechanisms in Carbon Dioxide Conversion" targets in particular researchers, teachers and PhD students.

This book focuses on carbon dioxide and its global role in our everyday life. Starting with society's dependency on energy, it demonstrates the various sources of carbon dioxide and discusses the putative effects of its accumulation in the atmosphere and its impact on the climate. It then provides an overview of how we can reduce carbon dioxide production and reviews innovative technologies and alternative energy resources. The book closes with a perspective on how carbon dioxide can be utilized reasonably and how mimicking nature can provide us with a solution. Using simple language, this book discusses one of today's biggest challenges for the future of our planet in a way that is understandable for the general public. The authors also provide deep insights into specific issues, making the book a useful resource for researchers and students.

Biorefineries compiles the basic science and technologies used to convert terrestrial and aquatic biomass into essential molecular compounds and polymeric materials. The book provides in depth insights into this fairly recent concept of industrial chemistry that aims to achieve optimal economic profits while minimizing the environmental impact. Chapters written by renowned experts cover, amongst others, the application of catalysis, downstream processing, biomass sourced olefins, lignin biorefinery techniques and biogas. The authors thoroughly examine and explain the value chain for biomass conversion into platform molecules and their transformation into final products. A comprehensive thematic overview on the topic giving beginners access to fundamental concepts is presented. Supplemented by numerous full color figures and tables, the contents impart knowledge about the involved techniques. Advanced students and experts in the field will find the summary of state-of-the-art research and current literature of valuable interest. Explores the enormous potential of biomass conversion as a future source for fuels and chemicals Focuses on both general scientific background and current innovations in the field of biorefinery Targets students and researchers in Chemistry, Chemical Engineering, Biotechnology, and Materials Science About the Editors Prof. Michele Aresta, Chair of the Scientific Committee of CIRCC in Italy and holds the IMM Chair at the Department of Chemical and Biomolecular Engineering at NUS, Singapore. He is author of over 200 papers and Author or Editor of nine books. Prof. Angela Dibenedetto, Associate Professor at the Department of Chemistry of the University of Bari (Italy) focused on carbon dioxide utilization by applying biorefinery concepts; and Director of the Interuniversity Consortium on Chemical Reactivity and Catalysis-CIRCC. Prof. Franck Dumeignil, Deputy Director of the CNRS joint Unit of Catalysis and Chemistry of Solid (UCCS) of Lille University (France); project coordinator of several projects on chemistry, including the EuroBioRef Project for designing next generation biorefineries.

The demand for new materials with novel properties on the micro- and nano-scale continues to grow. This book provides an overview of state-of-the-art techniques for the synthesis and characterization of inorganic nanomaterials including sonochemistry, microwave dielectric heating, sonoelectrochemistry and RAPET, high-throughput experimentation in heterogeneous catalyst research, photoluminescence, and methods for surface structuring. Imaging techniques include X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, single crystal and powder X-ray diffraction, X-ray microimaging (SAXS,WAXS & GISAXS), electron microscopy, and solid state NMR. The work is essential reading for all researchers in academia and industry working in the field of nanosciences.

This book provides an introduction to the basic science and technologies for the conversion of biomass (terrestrial and aquatic) into chemicals and fuels, as well as an overview of innovations in the field. The entire value chain for converting raw materials into platform molecules and their transformation into final products are presented in detail. Both cellulosic and oleaginous biomass are considered. The book contains contributions by both academic scientists and industrial technologists so that each topic combines state-of-the-art scientific knowledge with innovative technologies relevant to chemical industries. Selected topics include: Refinery of the future: feedstock, processes, products The terrestrial and aquatic biomass production and properties Chemical technologies and biotechnologies for the conversion of cellulose, hemicellulose, lignine, algae, residual biomass Thermal, catalytic and enzymatic conversion of biomass Production of chemicals, polymeric materials, fuels (biogas, biodiesel, bioethanol, biohydrogen) Policy aspects of biomass product chains LCA applied to the energetic, economic and environmental evaluation of the production of fuels from biomass: ethanol, biooil and biodiesel, biogas, biohydrogen

This book focuses on carbon dioxide and its global role in our everyday life. Starting with society's dependency on energy, it demonstrates the various sources of carbon dioxide and discusses the putative effects of its accumulation in the atmosphere and its impact on the climate. It then provides an overview of how we can reduce carbon dioxide production and reviews innovative technologies and alternative energy resources. The book closes with a perspective on how carbon dioxide can be utilized reasonably and how mimicking nature can provide us with a solution. Using simple language, this book discusses one of today's biggest challenges for the future of our planet in a way that is understandable for the general public. The authors also provide deep insights into specific issues, making the book a useful resource for researchers and students.

This book provides an analysis of the reaction mechanisms relevant to a number of processes in which CO2 is converted into valuable products. Several different processes are considered that convert CO2 either in specialty chemicals or in bulk products or fuels. For each reaction, the mechanism is discussed and the assessed steps besides the dark sites of the reaction pathway are highlighted. From the insertion of CO2 into E-X bonds to the reduction of CO2 to CO or other C1 molecules or else to C2 or Cn molecules, the reactions are analysed in order to highlight the known and obscure reaction steps. Besides well known reaction mechanisms and energy profiles, several lesser known situations are discussed. Advancing knowledge of the latter would help to develop efficient routes for the conversion of CO2 into valuable products useful either in the chemical or in the energy industry. The content of this book is quite different from other books reporting the use of CO2. On account of its clear presentation, "Reaction Mechanisms in Carbon Dioxide Conversion" targets in particular researchers, teachers and PhD students.