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The spectra of molecules containing more than one atom are
necessarily of single atoms. They are correspondingly much more
complex than those richer, not only in the number of spectral
lines, but also in qualitatively different phenomena which do not
have any counterpart in single atoms. Historically, molecular
spectra have revealed much fundamental phy sics, such as the
connection between nuclear spin statistics. They have pro vided
models of physical systems which have been useful in quite
different areas, such as particle physics. Most especially,
molecular spectra are of fundamental importance in understanding
chemical bonding. They reveal not only bond lengths but also the
strength of the bonding potential between atoms. Moreover, these
measurements are obtained for electronic excited states, as well as
for the ground state, and for unstable short-lived molecules. In
recent years, tunable lasers have provided powerful tools for the
measurement and analysis of molecular spectra. Even before that,
molecules were being used in lasers, most notably in the carbon
dioxide laser, which finds many industrial applications."
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