This book comprehensively reviews the key topics in microbial fuel cells (MFC) and its applications in areas related to energy and environmental mitigation. It covers the microbial electrochemistry and the generation of electricity from waste, various synthesis and characterization approaches of polymer-based MFC electrodes, the multifunctional properties of a MFC which allows its simultaneous use as a fuel cell, bioremediation and biosensor device. It provides new direction to the readers to better understand the chemistry in MFC and methods to improve their desired properties. This book is a very valuable reference source for graduates and postgraduates, engineers and research scholars in the areas related to fuel cells electrochemistry and pollution mitigation.