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Some seven years before Kerr's death, Larmor proposed that electric
birefringence had its origin in the orientation of anisotropic
molecules or elements within the apparently isotropic medium. The
theory for this concept was formulated by Langevin. During the next
half century, occasional measurements were made both to
characterise the phenomenon and to evaluate the relevant
physico-chemical parameters of pure liquids and molecular fluids.
During the 1930-40 era, Staudinger and others demonstrated the
existence in nature of giant molecules and colloidal particles.
Since that time it has slowly but increasingly been realised that
these big molecules or particles often have relatively large dipole
moments, are generally anisotropic in structure and hence, in
solution or suspension, give rise to significant electric
birefringence signals. Furthermore, there have been three
electronic innovations which have greatly eased the experimental
measurement of the effect for such materials. These were the
development of photomultiplier tubes for detection, of oscillo
scope for display and of high voltage generators developing bursts
or pulses of potential difference. The last mentioned enable the
experi menter to study the Kerr effect not only for its amplitude
but also in the time domain. The rates of molecular response to the
switching of the electric field lead directly to information on the
size and geo metry of the constituent molecules and particles in a
dilute solution or suspension."
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