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Today is Sunday, June 17, 2007. Father's Day. Naturally, the obligatory, carefully selected cards, phone calls, and small gifts arrived from the children and grandchildren. Best wishes for Father's Day were also the first words in the morning from Heidel, my wife of 54 years, although for many years I had made the comment: "I am not your father. " But, in the frame of my life's experiences th th in the 20 century, as I intend to summarize them over the next few years, the 17 of June has much deeper significance. This was the day in 1953 when we finally fled from our life of oppression which had lasted 20 years. Two successive dictatorships, one of Hitler and the other of Stalin, caused the most horrific slaughter of civilians and soldiers, eclipsing all prior history. During these first years of my life, I was plainly lucky to survive. After this day, I had a much better chance to experience the freedom needed to lead a life of creativity, satisfaction, and ultimately prosperity, all directed largely by our own decisions. th The 17 of June 1953 was a Wednesday. I stayed in the apartment of my parents in my hometown of Brandenburg, in the German Democratic Republic (GDR), the former Russian occupied zone of Germany. The summer vacation of the Humboldt University in East Berlin, some 40 mi further east, had just started. But, I was alone with my father, "Vati.
Thermal analysis is an old technique. It has been neglected to some degree because developments of convenient methods of measurement have been slow and teaching of the understanding of the basics of thermal analysis is often wanting. Flexible, linear macromolecules, also not as accurately simply called polymers, make up the final, third, class of molecules which only was identified in 1920. Polymers have neverbeenfullyintegratedintothedisciplinesofscienceandengineering. Thisbook is designed to teach thermal analysis and the understanding of all materials, flexible macromolecules, as well as those of the small molecules and rigid macromolecules. The macroscopic tool of inquiry is thermal analysis, and the results are linked to microscopic molecular structure and motion. Measurements of heat and mass are the two roots of quantitative science. The macroscopic heat is connected to the microscopic atomic motion, while the macroscopic mass is linked to the microscopic atomic structure. The macroscopic unitsofmeasurementofheatandmassarethejouleandthegram, chosentobeeasily discernable by the human senses. The microscopic units of motion and structure are 12 10 the picosecond (10 seconds) and the angstrom (10 meters), chosen to fit the atomic scales. One notes a factor of 10,000 between the two atomic units when expressed in human units, second and gram with one gram being equal to one cubic centimeter when considering water. Perhaps this is the reason for the much better understanding and greater interest in the structure of materials, being closer to human experience when compared to molecular motion."
This third volume completes the first part of the project " Macromolecular Physics." The first volume dealt with the description of macromolecular crystals; the second volume dealt with crystal growth; and the third volume summarizes our knowledge of the melting of linear, flexible macromolecules. The discussion in the three volumes goes from reasonably well-established topics, such as the structure, morphology, and defects in crystals, to topics still in flux, such as crystal nucleation, detailed growth mechanisms, and annealing processes, to arrive at the present topics of equilibrium, nonequilibrium, and copolymer melting. Our knowledge is quite limited on many aspects of these latter topics.
The broad field of conformational motion disorder in crystals is described with particular attention to the separation from the well known mesophases of liquid crystals and plastic crystals. Structure, thermodynamics and motion of a larger number of small and large molecules are discussed. Of special interest are the borderlines between smectic and high viscosity liquid crystals and condis crystals and between plastic crystals and condis crystals as complicated by pseudorotation, jumping between symmetry-related states and hindered rotation. This paper illustrates the wide distribution of conformational disorder in nature. Condis crystals and glasses ("Con"formational "Dis"order) can be found in small and large molecule systems made of organic, inorganic and biological compounds. The condis state was newly discovered only four years ago. In this article over 100 examples are discussed as example of the condis state. In many cases the condis state was suggested for the first time. Motion in the Condensed State, Condis Crystals and their Relation to Plastic Crystals, Condis Crystals of Flexible Macromolecules, Condis Crystals and their Relation to Liquid Crystals, Condis Crystals of Stiff Macromolecules.
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