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This book covers the broad subject of equilibrium statistical
mechanics along with many advanced and modern topics such as
nucleation, spinodal decomposition, inherent structures of liquids
and liquid crystals. Unlike other books on the market, this
comprehensive text not only deals with the primary fundamental
ideas of statistical mechanics but also covers contemporary topics
in this broad and rapidly developing area of chemistry and
materials science.
Building up from microscopic basics to observed complex functions,
this insightful monograph explains and describes how the unique
molecular properties of water give rise to its structural and
dynamical behaviour which in turn translates into its role in
biological and chemical processes. The discussion of the biological
functions of water details not only the stabilising effect of water
in proteins and DNA, but also the direct role that water molecules
themselves play in biochemical processes, such as enzyme kinetics,
protein synthesis and drug-DNA interaction. The overview of the
behaviour of water in chemical systems discusses hydrophilic,
hydrophobic and amphiphilic effects, as well as the interactions of
water with micelles, reverse micelles, microemulsions and carbon
nanotubes. Supported by extensive experimental and computer
simulation data, highlighting many of the recent advances in the
study of water in complex systems, this is an ideal resource for
anyone studying water at the molecular level.
This book brings together many different relaxation phenomena in
liquids under a common umbrella and provides a unified view of
apparently diverse phenomena. It aligns recent experimental results
obtained with modern techniques with recent theoretical
developments. Such close interaction between experiment and theory
in this area goes back to the works of Einstein, Smoluchowski,
Kramers' and de Gennes. Development of ultrafast laser spectroscopy
recently allowed study of various relaxation processes directly in
the time domain, with time scales going down to picosecond (ps) and
femtosecond (fs) time scales. This was a remarkable advance because
many of the fundamental chemical processes occur precisely in this
range and was inaccessible before the 1980s. Since then, an
enormous wealth of information has been generated by many groups
around the world, who have discovered many interesting phenomena
that has fueled further growth in this field. As emphasized
throughout the book, the seemingly different phenomena studied in
this area are often closely related at a fundamental level. Biman
Bagchi explains why relatively small although fairly sophisticated
theoretical tools have been successful in explaining a wealth of
experimental data at a semi-phenomenological level.
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