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Awarded the 2009 Olle Prize! The field of coordination polymer
research has undergone rapid expansion in recent years. No longer
are these materials the vaguely defined 'insoluble material' at the
bottom of your vessel that spell death for your reaction. They have
gone from 'polymeric rubbish' to 'materials of the future'. Great
leaps in the deliberate design of coordination polymers were made
in the 1990s. These were allied with similar advances in related
areas such as organic crystal engineering, metallosupramolecular
chemistry and X-ray diffraction. No longer did we assemble things
atom by atom. Whole molecules were used as building blocks and new
materials were made. This is the first book to provide a broad
overview of all the major facets of coordination polymer research
in one place. It combines chapters on nets and interpenetration
with wide-ranging surveys of transition metal and lanthanoid
coordination polymers and their properties. The aim is to provide a
flavour of each aspect whilst introducing the important concepts
and developments using carefully selected examples. After an
introduction, the text is split into three sections: -Design (nets,
interpenetration, malleability) -Analysis (transition metal
coordination polymers, lanthanoid coordination polymers,
organometallic networks, organic-inorganic hybrids) -Application
(magnetic properties, porosity, acentric and chiral networks,
reactive coordination polymers, other properties). Written in the
style of a tutorial review, the book is suitable for both senior
specialists and new postgraduate students taking their first steps
in the field. It also provides an authoritative and detailed
reference source.
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