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This volume presents a collection of papers given at the 16th Mid
-America Symposium on Spectroscopy held in Chicago, June 14-17,
1965. The Mid-America Symposium is sponsored annually by the
Chicago Section of the Society for Applied Spectroscopy in
cooperation with the St. Louis, Niagara Frontier, Cleveland,
Detroit, lndianapolis, and Milwaukee Sections of the Society and
the Chicago Gas Chromatography Discussion Group. Although we refer
to this meeting as the Mid-America Symposium, it continues to
attract attendance, interest, and inquiry from many parts of the
world. Sessions on lnfrared, Raman, Ultraviolet, Visible, Emis
sion, Flame, Atomic Absorption, Nuclear Particle, Gamma Ray,
Nuclear Magnetic Resonance, X-Ray Spectroscopy, Spec troscopy,
Spectrophosphorimetry, and Gas Chromatography provided interesting
papers involving both applied and theo retical principles. This
volume continues a series of the Proceedings initiated in 1961 and
is composed of a collection of 37 papers presented at this meeting.
It is the opinion of the Symposium Committee that although not a
complete account of the proceedings, publication of this collection
as a reference is warranted. As editors of this volume, we wish to
express our gratitude to the authors who gave their time and effort
in submitting their manuscripts so that this volume could be
published. The Symposium Committee, L. S. Gray, W. Baer, Vivian
Biske, W. Los eki , M. S. Wang, F. Leahy, J. L. Ogilvie, B. D.
Volume 9 of Developments in Applied Spectroscopy pr e- sents a
collection of tventy-three selected papers presented during the
21st Mid-America Symposium on Spectroscopy, held in Chicago, June
2-5, 1970, In general. these papers are those of the symposium type
and not papers pertaining to a specific research topic that one
voul~ expect to find in the journals. The 21st Mid-America
Symposium vas sponsored by the Chicago Section in cooperation vith
Cincinnati, Cleveland, Indiana, Nev England, Nev York, Niagara
Frontier and Ohio Vall ey Sections of the Society of Applied
Spectroscopy, and the Chicago Gas Chromatography Group. Although
the Mid- America is stiIl occasionally thought of as a regional
meet- ing, its attendees and authors come from all parts of the
United States and Canada as vell as other countries outside North
America. Both theoretieal and applied principles vere presented in
sessions on emission, molecular and atomic absorption, x-ray, mass,
nuclear, electron, and nuclear magnetic and electron spin resonanee
spectroscopy; air and Water pOllution analyses; biomedical
technology; polymers and elastomeric materials; and computer
applications. The chairmen of the Symposium Committees, Mr. E.
Baclavski. Dr. W. K. Baer, Mr. J. E. Burroughs, Dr. C. R. Brundle,
Mr. C. Hastings, Mr. J. B. Himes, Mr. R. Isaac, Dr. R. J. Jakobsen,
Mr. J. Kinder, Dr. J. L. Koenig, Mr. W. A. Loseke, Dr. R. Mattoon,
Miss V. McMahon, Dr. C.E. Moore, Mr. C. S. Naiman, Dr. M. J.
Oestmann, Mr. C. R.
From the first appearance of the classic The Spectrum Analysis in
1885 to the present the field of emission spectroscopy has been
evolving and changing. Over the last 20 to 30 years in particular
there has been an explosion of new ideas and developments. Of late,
the aura of glamour has supposedly been transferred to other
techniques, but, nevertheless, it is estimated that 75% or more of
the analyses done by the metal industry are accomplished by
emission spectroscopy. Further, the excellent sensitivity of plasma
sources has created a demand for this technique in such divergent
areas as direct trace element analyses in polluted waters.
Developments in the replication process and advances in the art of
pro ducing ruled and holographic gratings as well as improvements
in the materials from which these gratings are made have made
excellent gratings available at reasonable prices. This
availability and the development of plane grating mounts have
contributed to the increasing popularity of grating spectrometers
as com pared with the large prism spectrograph and concave grating
mounts. Other areas of progress include new and improved methods
for excitation, the use of controlled atmospheres and the extension
of spectrometry into the vacuum region, the widespread application
of the techniques for analysis of nonmetals in metals, the
increasing use of polychrometers with concave or echelle gratings
and improved readout systems for better reading of spectrographic
plates and more efficient data handling."
Volume 7 of Developments in Applied Spectroscopy is a collection of
forty-two papers selected from those that were presented at the 7th
National Meeting of the Society of Applied Spectroscopy, held (in
place of the 19th Mid-America Symposium on Spectroscopy) in
Chicago, May 13-17, 1968. These papers, selected by the editors and
reviewed by persons knowledgeable in the field, are those of the
symposium type and not those pertaining to specific research topics
that one would expect to be submitted to a journal. It is the
opinion of the committee that this type of publication has an
important place in the literature. The relatively large number of
papers would result in quite a sizable volume if bound in one set
of covers. For this reason, and to present the material in areas of
more specific mterest, Volume 7 was divided into two parts, Part A,
Physical-Inorganic, and Part B, Physical-Organic Developments. The
7th National Meeting was sponsored by the Chicago Section as host
in cooperation with the St. Louis, New England, Penn York,
Niagara-Frontier, Cincinnati, Ohio Valley, New York,
Baltimore-Washington, North Texas, Rocky Mountain, and Southeastern
Sections of the Society for Applied Spectroscopy and the Chicago
Gas Chromatography Group. The editors wish to express their
appreciation to the authors and to those who helped with the
reviewing. The latter include Dr. Elma Lanterman, Mr. John E.
Forrette, Dr. Carl Moore, Dr. B. Jaselskis, Mr. H. G. Zelinski, Mr.
Volume 7 of Developments in Applied Spectroscopy is a collection of
forty-two papers selected from those that were presented at the 7th
National Meeting of the Society of Applied Spectroscopy, held (in
place of the 19th Mid-America Symposium on Spectroscopy) in
Chicago, May 13-17, 1968. These papers, selected by the editors and
reviewed by persons knowledgeable in the field, are those of the
symposium type and not those pertaining to specific research topics
that one would expect to be submitted to a journal. It is the
opinion of the committee that this type of publication has an
important place in the literature. The relatively large number of
papers would result in quite a sizable volume if bound in one set
of covers. For this reason, and to present the material in areas of
more specific iilterest, Volume 7 was divided into two parts, Part
A, Physical-Inorganic, and Part B, Physical-Organic Developments.
The 7th National Meeting was sponsored by the Chicago Section as
host in cooperation with the St. Louis, New England, Penn York,
Niagara-Frontier, Cincinnati, Ohio Valley, New York,
Baltimore-Washington, North Texas, Rocky Mountain, and Southeastern
Sections of the Society for Applied Spectroscopy and the Chicago
Gas Chromatography Group. The editors wish to express their
appreciation to the authors and to those who helped with the
reviewing. The latter include Dr. Elma Lanterman, Mr. John E.
Forrette, Dr. Carl Moore, Dr. B. Jaselskis, Mr. H. G. Zelinski, Mr.
Volume 6 of Developments in Applied Spectroscopy presents a
collection of twenty-eight selected papers from those that were pre
sented at the Eighteenth Mid-America Symposium on Spectroscopy held
in Chicago, May 15 to 18, 1967. In general, the papers selected by
the editors are those of the symposium type and not those papers
pertaining to a specific research topic that one expects to be sub
mitted to a journal. Not all of the submitted papers were included.
Some revisions could not meet the deadline and others were not
accepted based on the advice of the reviewers. It is the opinion of
the committee that this type of publication has *an important place
in the literature. The Mid-America Symposium is sponsored annually
by the Chicago Section in cooperation with the Cincinnati, Detroit,
Indianapolis, Milwaukee, Niagara Frontier, and St. Louis Sections
of the Society of Applied Spectroscopy, and the Chicago Gas
Chromatography Group. Although the Mid-America is often thought of
as a regional meeting, its attendees and authors generally come
from all parts of the United States and Canada. Both applied and
theoretical principles were provided in sessions on X-ray,
emission, atomic-absorption, nuclear magnetic resonance, infrared,
Raman, nuclear-particle, and gamma ray spectroscopy; activation
analysis; and gas chromatography. In addition, there were symposia
on absorption spectra of biologically significant molecules; the
structure of ice, water, and aqueous solu tions; air and water
pollution analyses; and the practical application of statistics.
Volume 10 of Developments in Applied Spectroscopy presents a
collection of twenty selected papers presented during the 10th
National lleeting of the Society of Applied Spectroscopy held in
St. Louis, Oct. 18-22, 1971. The 10th National Meeting was
sponsored by the St. Louis Section, Society of Applied Spectroscopy
in cooperation with Baltimore-Washington, Chicago, Cleveland,
Cincinnati, Houston, Intermountain (Idaho Falls), Kansas City, New
England, Niagra Frontier, Northern California, North Texas,
Pittsburgh and Rocky Mountain (Denver) Sections of the Society and
combined with the 22nd Mid-American Symposium. Both theoretical and
applied principles were presented in sessions on emmision, atomic
absorp- tion, molecular, nuclear, mass, x-ray, flame, Massbauer,
and magnetic resonance spectroscopy. In addition special symposia
were held on on-line computers, spectra data processing and re-
trival, application of spectrographic techniques for the museum, in
environmental control, in space, in biomedicinal, sampling, the
analysis and characterization of electronic materials and gas
chromatography. The members of the Program Committee, I. Adler, L.
Beaver, J. E. Delmore Jr., J. Eichelberger, J. R. Ferraro, M.
Fishman, C. L. Grant, X. W. Heitsch, W. M. Hickam, M. T. Jones, S.
R. Koistyohann, J. Kopp, D. W. Larsen, F. Pogge, W. Ritchey, M. E.
Salmon, R. K. Skogerboe, J. J. Spijkerman, P. Urone, C. Veillon, M.
S. Wang, and J. S. Ziomek, and the other meeting committee members
are to be commended for the excellent program. Thanks are also
extended to the exhibitors for their part in making the meeting a
success.
Volume 8 of Developments in Applied Spectroscopy presents a
collection of selected papers presented at special symposia and
other sessions during the 20th Mid-America Symposium on
Spectroscopy, held in Chicago, May 12-15, 1969. In general, these
papers are those of the symposium type and not papers per taining
to a specific research topic that one would expect to find in the
journals. The 20th Mid-America Symposium was sponsored by the
Chicago Section in cooperation with the Niagara Frontier, Rocky
Mountain, St. Louis, and Southeastern Sections of the Society of
Applied Spectroscopy, and the Chicago Gas Chromatography Group.
Although the Mid-America is still occasionally thought of as a
regional meeting, its attendees and authors come from all parts of
the United States and Canada. Both theoretical and applied
principles were presented in sessions on emission, atomic
absorption, x-ray, nuclear particle, Raman and infrared, nuclear
magnetic resonance, and electron spin resonance spectroscopy;
computer applications; air and water pollution, instrumental
applications to biomedicine toxicology; spectra and
characterization; matrix isolation and gas chromatography-mass
spectrometry. In addition, there were symposia on trace element
analyses, silicate analyses, Mossbauer spectroscopy, electron
spectroscopy for chemical analyses (ESCA), spectroscopy of
materials under high pressure, and reference spectra and retrieval
systems. The various chairmen of the Symposium Committee, H.
Bedell, Dr. Charles Bell, Dr. Eleanor Berman, Dr. Roy Bible, Sam
Booras, James E. Burroughs, Adrian Chisholm, Dr. Paul Day, Tod
Engelskirchen, G. A. Ettelt, Dr. L. S.
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