The revealing of the phenomenon of superhydrophobicity (the "lotus-effect") has stimulated an interest in wetting of real (rough and chemically heterogeneous) surfaces. In spite of the fact that wetting has been exposed to intensive research for more than 200 years, there still is a broad field open for theoretical and experimental research, including recently revealed superhydrophobic, superoleophobic and superhydrophilic surfaces, so-called liquid marbles, wetting transitions, etc. This book integrates all these aspects within a general framework of wetting of real surfaces, where physical and chemical heterogeneity is essential. Wetting of rough/heterogeneous surfaces is discussed through the use of the variational approach developed recently by the author. It allows natural and elegant grounding of main equations describing wetting of solid surfaces, i.e. Young, Wenzel and Cassie-Baxter equations. The problems of superhydrophobicity, wetting transitions and contact angle hysteresis are discussed in much detail, in view of novel models and new experimental data. The second edition surveys the last achievements in the field of wetting of real surfaces, including new chapters devoted to the wetting of lubricated and gradient surfaces and reactive wetting, which have seen the rapid progress in the last decade. Additional reading, surveying the progress across the entire field of wetting of real surfaces, is suggested to the reader. Contents What is surface tension? Wetting of ideal surfaces Contact angle hysteresis Dynamics of wetting Wetting of rough and chemically heterogeneous surfaces: the Wenzel and Cassie Models Superhydrophobicity, superhydrophilicity, and the rose petal effect Wetting transitions on rough surfaces Electrowetting and wetting in the presence of external fields Nonstick droplets Wetting of lubricated surfaces

Motivated by a plethora of phenomena from nature, this textbook introduces into the physics of wetting of surfaces. After a brief discussion of the foundations of surface tension, its implementation for floating objects, capillary waves, bouncing droplets, walking of water striders, etc. is discussed. Furthermore, Marangoni flows, surface tension inspired instabilities, condensation and evaporation of droplets, liquid marbles, superhydrophobicity and superoleophobicity (lotus effect) are introduced. All relevant concepts are illustrated by the numerous qualitative and quantitative exercises. Contents What is surface tension? Wetting of surfaces: the contact angle Surface tension-assisted floating of heavy and light objects and walking of water striders Capillary interactions between particles. Particles placed on liquid surfaces. Elasticity of liquid surfaces, covered by colloidal particles Capillary waves Oscillation of droplets Marangoni flow and surface instabilities Evaporation of droplets. The Kelvin and the coffee-stain effects Condensation, growth and coalescence of droplets and the breath-figure self-assembly Dynamics of wetting: bouncing, spreading and rolling of droplets (water hammer effect - water entry and drag-out problems)Superhydrophobicity and superoleophobicity: the Wenzel and Cassie wetting regimes The Leidenfrost effect. Liquid marbles: self-propulsion Physics, geometry, life and death of soap films and bubbles