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Because it is grounded in math, chemical thermodynamics is often
perceived as a difficult subject and many students are never fully
comfortable with it. The first authoritative textbook presentation
of equilibrium chemical and phase thermodynamics in a reformulated
geometrical framework, Chemical and Phase Thermodynamics shows how
this famously difficult subject can be accurately expressed with
only elementary high-school geometry concepts. Featuring numerous
suggestions for research-level extensions, this simplified
alternative to standard calculus-based thermodynamics expositions
is perfect for undergraduate and beginning graduate students as
well as researchers.
This book explores chemical bonds, their intrinsic energies, and
the corresponding dissociation energies which are relevant in
reactivity problems. It offers the first book on conceptual quantum
chemistry, a key area for understanding chemical principles and
predicting chemical properties. It presents NBO mathematical
algorithms embedded in a well-tested and widely used computer
program (currently, NBO 5.9). While encouraging a "look under the
hood" (Appendix A), this book mainly enables students to gain
proficiency in using the NBO program to re-express complex
wavefunctions in terms of intuitive chemical concepts and orbital
imagery.
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