Leading investigators in their fields present a broad perspective of recent major research trends in synthetic fluorine chemistry. Coverage includes: various aspects of organic and inorganic fluorine chemistry, fluorination methods, organometallic fluorine chemistry and its use in synthesis, the synthesis of perfluoropolyethers (an extraordinary class of new fluorinated compounds) and much more.

Comprehensive and up-to-date, the book brings together for the first time synthetic nitration methods and mechanistic aspects of both aromatic and aliphatic nitrations. Researchers and students will appreciate the complete perspective of the whole field that this unique work offers.

Inspired by a symposium held at the University of Southern California, in March 1988, dedicated to Paul van R. Schleyer, contributors examine the role of 'hypercarbons' in several areas of chemistry in this book. The multicenter bonding of 'hypercarbons' relative to the chemistry of main group elements, organometallics, cluster chemistry, carbocations, and hydrocarbon chemistry are systematically covered.

The autobiography of a Nobel Prize winner, this book tells us about George Olah's fascinating research into extremely strong superacids and how it yielded the common term "magic acids." Olah guides us through his long and remarkable journey, from Budapest to Cleveland to Los Angeles, with a stopover in Stockholm. This updated autobiography of a Nobel Prize winner George A. Olah: * Chronicles the distinguished career of a chemist whose work in a broad range of chemistry areas, and most notably that in methane chemistry, led to technologies that impact the processing and utility of alternative fuels * Is based on Olah's work on extremely strong superacids and how they yielded the common term, "magic acids" * Details events since the publication of the first edition in 2000 * Inspires readers with details on Dr. Olah's successful recent research on methanol, intended to help provide a solution to "the oil problem"

Completely revised and updated, the third edition of this bestseller discusses the concept and ongoing development of using methanol as a transportation fuel, energy storage medium, and as a raw material to replace oil. The contents have also been expanded by 15% with new chapters on energy storage, methanol from biomass and waste products, as well as on carbon dioxide recycling. Written by Nobel laureate George Olah, this is an inspiring read for anyone concerned with the major challenge posed by tomorrow?s energy and environmental problems.

A detailed understanding of reactive intermediates is at the heart of chemical transformations, and thus of modern organic synthetic chemistry. Carbocations are electron deficient species that are the most important intermediates in organic chemistry. This comprehensive review gives practical information on the synthesis, mechanisms, and spectral studies related to carbocation chemistry
* A detailed reference for all aspects of charbocation chemistry.
* With numerous classical examples of studies of carbocations to serve as illustrative principles in organic and physical organic chemistry.
* Provides insight into future developments in the field and practical applications.

The first comprehensive book on superelectrophiles and their applications in synthetic and mechanistic organic chemistry

This reference presents a comprehensive review and discussion of the substantial experimental and theoretical work in the field of superelectrophiles and their reactions in recent years. It covers:

The differentiation of usual electrophiles from superelectrophiles

Ways to increase electrophilic strength

The classification into gitonic and distonic superelectrophiles

Methods of study, including substituent and solvent effects as well as the role of electrophilic solvation in chemical reactions as studied by kinetic investigations, spectroscopic studies, gas-phase studies, and theoretical methodologies

A review of the superelectrophiles that have been identified and studied

A discussion of the significance of superelectrophilic chemistry and its future

In addition to a discussion of the basics of this emerging field, Superelectrophiles and Their Chemistry includes tools to help the reader apply the chemistry. It's an invaluable reference for chemists in academia and research, industrial chemists in pharmaceutical and petrochemical fields, and graduate students studying inorganic and physical organic chemistry.