Leading investigators in their fields present a broad perspective of recent major research trends in synthetic fluorine chemistry. Coverage includes: various aspects of organic and inorganic fluorine chemistry, fluorination methods, organometallic fluorine chemistry and its use in synthesis, the synthesis of perfluoropolyethers (an extraordinary class of new fluorinated compounds) and much more.

Comprehensive and up-to-date, the book brings together for the first time synthetic nitration methods and mechanistic aspects of both aromatic and aliphatic nitrations. Researchers and students will appreciate the complete perspective of the whole field that this unique work offers.

Inspired by a symposium held at the University of Southern California, in March 1988, dedicated to Paul van R. Schleyer, contributors examine the role of 'hypercarbons' in several areas of chemistry in this book. The multicenter bonding of 'hypercarbons' relative to the chemistry of main group elements, organometallics, cluster chemistry, carbocations, and hydrocarbon chemistry are systematically covered.

The autobiography of a Nobel Prize winner, this book tells us about George Olah's fascinating research into extremely strong superacids and how it yielded the common term "magic acids." Olah guides us through his long and remarkable journey, from Budapest to Cleveland to Los Angeles, with a stopover in Stockholm. This updated autobiography of a Nobel Prize winner George A. Olah: * Chronicles the distinguished career of a chemist whose work in a broad range of chemistry areas, and most notably that in methane chemistry, led to technologies that impact the processing and utility of alternative fuels * Is based on Olah's work on extremely strong superacids and how they yielded the common term, "magic acids" * Details events since the publication of the first edition in 2000 * Inspires readers with details on Dr. Olah's successful recent research on methanol, intended to help provide a solution to "the oil problem"

Completely revised and updated, the third edition of this bestseller discusses the concept and ongoing development of using methanol as a transportation fuel, energy storage medium, and as a raw material to replace oil. The contents have also been expanded by 15% with new chapters on energy storage, methanol from biomass and waste products, as well as on carbon dioxide recycling. Written by Nobel laureate George Olah, this is an inspiring read for anyone concerned with the major challenge posed by tomorrow?s energy and environmental problems.

Comprehensive and up-to-date coverage of onium ions—an indispensable reference for academic and industrial chemists

In Onium Ions, Nobel Prize-winning chemist George Olah joins forces with coauthors Kenneth Laali, Qi Wang, and G. K. Surya Prakash to offer an in-depth look at the chemistry and reactions of these important electron-deficient compounds. While other texts have covered various individual types of onium ions, this work addresses the structure and chemistry of numerous different classes of onium ions. Contents include:

• Discussions of well-established classes of onium ions, such as azonium, oxonium, sulfonium, selenonium, telluronium, and phosphonium ions.
• Coverage of more recent types, from siliconium, halonium, and carbonium to carboxonium, carbosulfonium, and carbazonium ions.
• Clear explanations of definition, classification, preparation, and chemistry of each major group of onium ions.
• An exploration of superelectrophilic activation of onium ions through contact with superacid media.

Enriched with numerous illustrations and a full listing of references for each chapter, Onium Ions should be a staple text in the professional chemist's library.

This book provides an unparalleled contemporary assessment of hydrocarbon chemistry presenting basic concepts, current research, and future applications. Comprehensive and updated review and discussion of the field of hydrocarbon chemistry Includes literature coverage since the publication of the previous edition Expands or adds coverage of: carboxylation, sustainable hydrocarbons, extraterrestrial hydrocarbons Addresses a topic of special relevance in contemporary science, since hydrocarbons play a role as a possible replacement for coal, petroleum oil, and natural gas as well as their environmentally safe use Reviews of prior edition: ...literature coverage is comprehensive and ideal for quickly reviewing specific topics...of most value to industrial chemists...(Angewandte Chemie) and ...useful for chemical engineers as well as engineers in the chemical and petrochemical industries. (Petroleum Science and Technology)

The essential new edition of the book that put hypercarbon chemistry on the map

A comprehensive and contemporary treatment of the chemistry of hydrocarbons (alkanes, alkenes, alkynes, and aromatics) towards electrophiles, Hypercarbon Chemistry, Second Edition deals with all major aspects of such chemistry involved in hydrocarbon transformations, and of the structural and reaction chemistry of carboranes, mixed hydrides in which both carbon and boron atoms participate in the polyhedral molecular frameworks.

Despite the firmly established tetravalency, carbon can bond simultaneously to five or more other atoms. "Hypercarbon" bonding permeates much organic, inorganic and organometallic chemistry, and the book serves as the compendium for this phenomenon.

Copious diagrams illustrate the rich variety of hypercarbon structures now known, and patterns therein. Individual chapters deal with specific categories of compound (e.g. organometallics, carboranes, carbocations) or transformations that proceed through transient hypercarbon species, detailing fundamental chemistry, including reactivity, selectivity, stereochemistry, mechanistic factors and more.

The first comprehensive book on superelectrophiles and their applications in synthetic and mechanistic organic chemistry

This reference presents a comprehensive review and discussion of the substantial experimental and theoretical work in the field of superelectrophiles and their reactions in recent years. It covers:

The differentiation of usual electrophiles from superelectrophiles

Ways to increase electrophilic strength

The classification into gitonic and distonic superelectrophiles

Methods of study, including substituent and solvent effects as well as the role of electrophilic solvation in chemical reactions as studied by kinetic investigations, spectroscopic studies, gas-phase studies, and theoretical methodologies

A review of the superelectrophiles that have been identified and studied

A discussion of the significance of superelectrophilic chemistry and its future

In addition to a discussion of the basics of this emerging field, Superelectrophiles and Their Chemistry includes tools to help the reader apply the chemistry. It's an invaluable reference for chemists in academia and research, industrial chemists in pharmaceutical and petrochemical fields, and graduate students studying inorganic and physical organic chemistry.