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This book is an expanded and updated version of Part III of the
authors' previous work, Advanced Structural Inorganic Chemistry
(OUP 2008). The original part deals with main-group elements, the
rare-earth elements, transition-metal clusters, and supramolecular
systems. In this new book, selected material from significant
advances in the past decade has been added, with particular
emphasis on compounds that exemplify new types of bonds such as
sigma-hole, triel bond, tetrel bond, pnictogen bond, chalcogen
bond, halogen bond, halogen-halogen interaction, aerogen bond, as
well as quintuple and sextuple metal-metal bonds. Other new topics
include actinide compounds, metallophilicity, heterometallic
macrocycles and cages, com- and dis-proportionation reactions,
hydrogen-bonded organic frameworks (HOFs), halogen-bonded organic
frameworks, halogen-halogen interactions in supramolecular
frameworks, covalent organic frameworks (COFs), and metal-organic
frameworks (MOFs).
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