COMMERCIAL WAXES NATURAL AND SYNTHETIi Including Properties, Uses, Methods of Handling and Formulas for Making Commercial Wax Compositions. A SYMPOSIUM AND COMPILATION Edited by H. BENNETT. PREFACE: Natural waxes and wax-lifle materials have been used, from time immemorial, for candles, waterproofing, sealing, decorative, preservative, and other purposes. Synthetic waxes and wax-like materials, developed in the last decade, are finding increasing use and are supplanting natural waxes for many purposes. Since different waxes have different properties, each one is used to obtain certain end results. Whereas certain waxes are used alone, as paraffin wax in waxed papers, other uses require com binations of different waxes, resins, etc., to obtain a desired result. Because there is no one source of information available on the waxes used in industry, the writer was asked to prepare a book on commercial waxes for the chemist, engineer, superin tendent, purchasing agent, and student. It is hoped that this book will be helpful to these and others who are interested in commercial waxes and wax compositions. Much of the data given herein is from the writer's own laboratory and has never been disclosed. Grateful acknowledgment is made to Allan B. Olsen, both for data supplied by him and his constructive criticism of the manuscript. H. BENNETT. Contents include: PREFACE iii INTRODUCTION xi ABBREVIATIONS xv I. NATURAL WAXES 1 Mineral Waxes 1 Paraffin Wax 1 Macrocrystalline Waxes 60 Petrolatum Wax 68 Ozokerite 68 Ceresin 71 Utah Wax 71 Montan Wax 72 Vegetable Waxes 73 Botanical Origin of Waxes 73 Solubility of Vegetable Waxes 74 Carnauba Wax 74 Candelilla Wax . . .: 77 Japan Wax 79 Ucuhuba Wax 80Bayberry Wax 80 Ouricury Wax 81 Cocoa Butter 82 Fiber Wax 82 Cotton Wax 83 Flax Wax 84 Sugar Cane Wax 84 Animal Waxes 85 Spermaceti 85 v vi Table of Contents CHAPTER PAGE I. NATURAL WAXES ( Cont.): Insect Waxes 86 Beeswax 86 Chinese Wax 89 Shellac Wax 89 II. MANUFACTURED AND SYNTHETIC WAXES 91 Fatty Alcohols 91 Cetyl Alcohol 91 Lanette Wax 93 Technical Stearyl Alcohol 94 Fatty Acids 94 Stearic Acid 94 Palmitic Acid 97 Myristic Acid 98 Distilled Fatty Acids 99 Polyglycols 101 Carbowax 101 Polyhydric Alcohol Fatty Acid Esters 105 Glyceryl Stearates 105 Glycol Stearates 107 Sorbitol Stearates 110 Pentaerythritol Stearates Ill Pentawaxes Ill Hydrogenated Oils Ill Opalwax 112 Chlorinated Naphthalenes 117 Halowax 117 Seekay Wax 117 Acrawaxes 119 Acrawax B 120 Acrawax C 121 I. G. Waxes 123 Miscellaneous Synthetic Waxes 127 Albacer 128 Adheso Wax 128 Table of Contents vii CHAPTER PAGE II. MANUFACTURED AND SYNTHETIC' WAXES ( Cont.): Miscellaneous Synthetic Waxes ( Cont.): B. Z. Wax A 129 Ceraflux ( Tech) 129 Diolin 129 Flexo Wax C 130 Gelowax 130 Glycowax A 131 Nipocer 131 Ozowax 132 Rezowax A 132 Rezowax B 132 Stroba Wax 133 Ketones, Amines, Amides, Nitriles 133 16-Hentriacontanone 133 Octadecyl-Hexadecyl Amine 135 Octadecylamine 135 CD Amides 136 Octadecanamide-Hexadecanamide 139 Octadecane nitrile 140 Octadecane-Hexadecane Nitrile 140 Santowaxes 141 Santowax OSA and Santowax PSA 148 Santowax R ( Regular) 148 III. PHYSICAL PROPERTIES OF WAXES AND WAX COMPOSITIONS 153 IV. WAX TECHNOLOGY 233 Commercial Wax Solutions 253 Emulsions 261 V. WAXES IN INDUSTRY 267 Dental Waxes 267 Lipsticks 268.

Contents - PREFACE TO THE SECOND EDITION - PREFACE TO THE FIRST EDITION - INTRODUCTION - ABBREVIATIONS - 1. NATURAL WAXES - Mineral Waxes: Paraffin Wax; Microcrystalline Waxes; Petrolatum Wax; Ozokerite; Ceresin; Utah Wax; Montan Wax - Vegetable Waxes: Botanical Origin of Waxes - Solubility of Vegetable Waxes - Carnauba Wax - Flower Wax - First Wax - Medium Wax - Sandy Wax - Fat Wax - Candelilla Wax - Japan Wax - Ucuhuba Wax - 2. MANUFACTURED AND SYNTHETIC WAXES - Fatty Alcohols: Cetyl Alcohol; Lanette Wax; Technical Stearyl Alcohol - Fatty Acids: Stearic Acid; Palmitic Acid; Myristic Acid; Distilled Fatty Acids; Solubility of Fatty Acids - Polyglycols: Carbowaxes - Polyhydric Alcohol Fatty Acid Esters: Glyceryl Stearates - Glycol Fatty-Acid Esters - Sorbitol Stearates - Pentawaxes - Hydrogenated Oils: Opalwax - Chlorinated Naphthalenes: Halowax; Seekay Wax - Acrawaxes: Acrawax B; Acrawax C. - I. G. Waxes - Miscellaneous Synthetic Waxes - COMMERCIAL WAXES - Albacer - Diolin- Flexo Wax - C-Glyco Waxes- Stroba Wax - Ketones, Amines, Amides, and Nitriles- 16-Hentriacontanone - Octadecyl-Hexadecyl Amine - Octadecylamine- Armids- Octadecanamide-Hexadecanamide - Octadecane Nitrile-Octadecane-Hexadecane Nitrile - Santowaxes - Santowax R - Alcowaxes - Alcowax-M - Alcowax-G - 3. PHYSICAL PROPERTIES OF WAXES AND WAX COMPOSITIONS - Increasing the Viscosity of Molten Waxes - Penetration - Surface Tension of Waxes - Adhesiveness - Increasing Compatibility - Raising the Melting Point of Waxes: Raising the Melting Point of Petrolatum - Effects of a Wax Sizing on the Moisture Absorption of Insulating Board - Pliolite-Paraffin Wax Compositions - Specific Heat of Petroleum Waxes - Melting Points of Binary Wax Mixtures - Solubility of Waxes: Solubility of Waxes in Different Solvents - Compatibility of Paraffin Waxes with Other Substances - Compatibility of Mixed Fatty Acids - Compounded Waxes - 4. WAX TECHNOLOGY - Adulteration - Quality Variations Simple Tests: Melting Point - Specific Gravity - Moisture and Insoluble Matter - Accurate Determination of Specific Gravity: Preparation of Sample - Determination of Specific Gravity at 25/25 C - Identification of Mixed Waxes: Schematic Outline for Identification - Separation and Comparison of the Properties of the Wax Components - Spermaceti - Beeswax - Carnauba Wax - Candelilla Wax - Montan Wax - Paraffin Wax - Ozokerite - 5. WAXES IN INDUSTRY - Dental Waxes: Method of Producing Base-Plate Wax - Lipsticks - Pharmaceutical Preparations - Embalming Preparations - Pyrotechnics - Candles: Wicks- Winding- Candle Sizes - Machinery - Wax Candles - Paraffin Candles - Temperature Control-Colors, Sizes, and Shapes - Standard Candle - Melting Point of Wax Mixtures - Congealing Point of Candles - Leather Finishes - Paper Finishes - Waterproofing Kraft Papers - Evaluation of Waxes for Paper Board: Stain and Flow Test at 130 F - Softening and Melting Point - Flexibility and Strength - Viscosity - Surface Tension - Permeability - Degree of Impregnation - Effect of Wax on the Strength of Board - Electrolyte Penetration Test - 6. GLOSSARY - SPECIAL TABLES AND SUBSTITUTES 7. WAX FORMULARY - Adhesives and Cements - Agricultural and Garden Specialties - Building Materials- Carbon Paper, Inks, and Crayons - Cosmetics and Medicinal Preparations - Dental Preparations - Emulsions - Full TOC available on Website

There is hardly any technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. Chemists both experienced and beginner, continually refer to them. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. -CONTENTS - I. Introduction - II. Adhesives - III. Beverages and Foods - IV. Cosmetics - V. Coatings - VI. Detergents and Disinfectants - VII. Drug Products - VIII. Elastomers, Plastics, and Resins - IX. Metals - X. Polishes - XI. Textile Specialties - XII. Miscellaneous - Appendix - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend considerable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort. Manufacturers and sellers of chemicals will find, In these formulae, new uses for their products. Non-chemical executives, professional men, and Interested laymen will make through this volume a "speaking acquaintance" with products which they may be using, trying or selling. It often happens that two Individuals using the same Ingredients in the same formula get different results. This may be due to slight deviations in the raw materials or unfamiliarity with the intricacies of a new technique. Accordingly, repeated experiments may be necessary to get the best results. Although many of the formulas given are being used commercially, many have been taken from the literature and may be subject to various errors and omissions. This should be taken into consideration. Wherever possible, it is advisable to consult with other chemists or technical workers regarding commercial production.

There is hardly a technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. Chemists both experienced and beginner, continually refer to them. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. - CONTENTS - I. Introduction - II. Adhesives - III. Beverages and Foods - IV. Cosmetics - V. Coatings - VI. Detergents and Disinfectants - VII. Drug Products - VIII. Metal Treatments - IX. Polishes - X. Textile Specialties - XI. Miscellaneous - Appendix - Index - Preface - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend considerable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort. Manufacturers and sellers of chemicals will find, In these formulae, new uses for their products. Non-chemical executives, professional men, and Interested laymen will make through this volume a "speaking acquaintance" with products which they may be using, trying or selling. It often happens that two Individuals using the same Ingredients in the same formula get different results. This may be due to slight deviations in the raw materials or unfamiliarity with the intricacies of a new technique. Accordingly, repeated experiments may be necessary to get the best results. Although many of the formulas given are being used commercially, many have been taken from the literature and may be subject to various errors and omissions. This should be taken into consideration. Wherever possible, it is advisable to consult with other chemists or technical workers regarding commercial production.

There is hardly a technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. Chemists both experienced and beginner, continually refer to them. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. -CONTENTS - I. Introduction - II. Adhesives - III. Coatings - IV. Cosmetics - V. Detergents and Disinfectants - VI. Drug Products - VII. Elastomers, Plastics and Resins - VIII. Foods and Beverages - IX. Polishes - X. Textile Specialties - XI. Miscellaneous - Appendix - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend considerable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort. Manufacturers and sellers of chemicals will find, In these formulae, new uses for their products. Non-chemical executives, professional men, and Interested laymen will make through this volume a "speaking acquaintance" with products which they may be using, trying or selling. It often happens that two Individuals using the same Ingredients in the same formula get different results. This may be due to slight deviations in the raw materials or unfamiliarity with the intricacies of a new technique. Accordingly, repeated experiments may be necessary to get the best results. Although many of the formulas given are being used commercially, many have been taken from the literature and may be subject to various errors and omissions. This should be taken into consideration. Wherever possible, it is advisable to consult with other chemists or technical workers regarding commercial production.

There is hardly a technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. - CONTENTS - I. Introduction - II. Adhesives - III. Coatings - IV. Cosmetics - V. Detergents and Disinfectants - VI. Drug Products - VII. Suspensions and Emulsions - VIII. Food Products - IX. Metals and Their Treatment - X. Polish - XI. Textile Chemical Specialties - XII. Miscellaneous - Appendix - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend conslderable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort.

There is hardly a technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. - CONTENTS - I. Introduction - II. Adhesives - III. Beverages and Food - IV. Cosmetics - V. Paints and Coatings - VI. Cleaners and Polishes - VII. Drugs - VIII. Elastomers, Plastics and Resins - IX. Miscellaneous - Appendix - Trademark Chemicals - Trademark Chemicals Suppliers - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend conslderable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort.

CONTENTS - INTRODUCTION - 1. BASIC CONSIDERATIONS - Solutions-Suspensions-Emulsions-Surface Activity - 2. PROPERTIES OF EMULSIONS - Particle size and arrangement ; Rheology ; Micelle Theory ; Stability and Interfacial Phenomena ; Causes of Unstable Emulsions - 3. INGREDIENTS AND ADDITIVES - Surfactants-Emulsifying Agents ; Wetting Agents ; Foamers ; Protective Colloids ; Preservatives - 4. ANALYSIS AND TESTING OF EMULSIONS - Type of Emulsion ; Density ; Viscosity ; Surface Tension ; Particle Size ; Water ; PH-Color OdorCorrosion ; Stability ; Performance ; Analytical Procedures ; ASTM Specifications - 5. TECHNIQUES OF EMULSIFICATION - English Method-Continental Method - 6. EMULSIFYING EQUIPMENT - Low-Shear-High-Shear-Rotor-Stator ; Pressurized Fluid ; Vibrational Devices ; Laboratory Equipment - 7. EMULSION PLANTS AND PRODUCTION MACHINERY - Over-all Plan ; Modes of Operation ; Power Requirements ; Mixing Tanks ; Pumps ; Conveyors ; Materials of Construction ; Instrumentation ; Packaging - 8. SELECTED TOPICS - Formulation of Emulsions-HLB-Biodegradability - Regulations - BIBLIOGRAPHY - LIST OF EMULSIFYING AGENTS - SUPPLIERS OF EMULSIFYING AGENTS - GLOSSARY - INDEX - Introduction - Emulsions, though not new, are finding new and wider applications daily. One of the first references to emulsions was recorded by Galen (131-c.201), the Greek physician. Beginning with that early reference to the emulsifying power of beeswax, the art and science of emulsification has flourished. Emulsions are prepared and used for a variety of reasons. As oil paint cannot be applied to a damp surface, it is emulsified in water. The oil paint, then, in the form of an emulsion, can be applied to a damp surface. Therefore, the emulsion can change the application characteristics of a material. Water is a desirable, cheap diluent, and an emulsion is an easy method of using water to dilute materials that are not soluble in water. In addition, the fire hazard of flammable water-insoluble materials can be decreased through emulsification. The odor and taste of water-insoluble materials can be reduced by the use of an emulsion. Cod-liver oil, for example, loses much of its fishy, oily taste when it is emulsified. The kinetics of many reactions are enhanced through the use of emulsion polymerization techniques. On the other hand, emulsions are difficult to manufacture. A small deviation in temperature or mixing speed or small amounts of impurities can prevent the formation of a stable emulsion. Emulsions are sensitive in varying degrees to heat, cold, and age. The production of good, stable emulsions, therefore, is the combination of science and art. It is the purpose of this book to describe the art and technique of emulsification.

There is hardly a technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. - CONTENTS - I. Introduction - II. Adhesives - III. Beverages and Foods - IV. Cosmetics - V. Coatings - VI. Detergents - VII. Drugs - VIII. Polishes - IX. Miscellaneous - Appendix - Trademark Chemicals - Trademark Chemicals Suppliers - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend conslderable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort.

There is hardly a technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. - CONTENTS - I. Introduction - II. Adhesives - III. Beverages and Foods - IV. Cosmetics - V. Coatings - VI. Detergents - VII. Drugs - VIII. Polishes - IX. Elastomers, Polymers and Resins - X. Miscellaneous - Appendix - Trademark Chemicals - Trademark Chemicals Suppliers - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend conslderable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort.

This title is Volume 2 of a 2 Volume set. - Contents - PART 1. - COMPOUNDED WAXES - 1. GENERAL - Compatibility - Hardness - Melting Point - Penetration - Refractive Index - Solubility in Oil - Viscosity - 2. PARAFFIN WAX COMPOUNDS - 3. ETHYL CELLULOSE AND WAX MIXTURES - Compounding Ethyl Cellulose with Incompatible Substances - Methods of Preparing Mixtures of Waxes with Ethyl Cellulose - 4. COMPOSITIONS WITH RESINS AND RUBBER - Resin Wax Compositions - Compatibility of Varnish Resins with Waxes - Cumarone-Indene Resins and Wax Compositions - Methacrylate Resin Hot-Melt Blends - Microcrystalline Wax-Resin Blends - Wax-Rubber Compositions - 5. COMMERCIAL WAX ADDITIVES - PART 2 - WAX TECHNOLOGY - 6. TESTS AND TECHNIQUES - The Melting' Points of Waxes - Odor and Taste - Emulsions - Fluorescence of Waxes - Solubility of Waxes - Commercial Wax Solutions - Surface Tension of Waxes - Specific Gravity - Specific Heat of Petroleum Waxes - To Alter Properties of Paraffin Wax - Simple Tests - Identification of Mixed Waxes - Separation and Comparison of Properties - Detecting Wax Additives - Evaluation of Waxes for Paperboard - Determinations of Properties - Testing for Quality Control - Opacifying Waxes - Coloring Waxes - 7. INDUSTRIAL USES OF WAXES - Adhesives - Candles - Coatings - Cosmetics - Electrical Applications - Inks - Leather Goods - Paper Products - Pharmaceutical Preparations - Photomechanics - Plastics - Polishes - Pyrotechnics - Rubber - Textile Processing - Abbreviations - Alphabetic Listing of Trademark Products - Index -

This title is Volume 1 of a 2 Volume set. - Contents - Introduction - Abbreviations - PART 1. NATURAL WAXES - 1. PARAFFIN WAX - Occurrence in Nature - Composition of Petroleum - Grades of Paraffin Wax - Manufacture of Paraffin Waxes - Composition of Paraffin Waxes - Properties of Paraffin Waxes - Wax-Oil Mixtures - Miscellaneous Data - Physical Properties of Some Commercial Waxes - 2. MICROCRYSTALLINE WAXES - Differences Between Microcrystalline and Paraffin Waxes - Fractional Crystallization of Petroleum Waxes - Properties of Microcrystalline Waxes - Oxidized Microcrystalline Waxes - Petrolatum - Uses of Microcrystalline Waxes - Miscellaneous Data - Properties of Some Commercial Microcrystalline Waxes - 3. OTHER MINERAL WAXES - Montan Wax - Lignite Wax - Ozocerite - Ceresin - Utah Wax - Peat Wax - 4. VEGETABLE WAXES - Bayberry - Candelilla - Carnauba - Cotton - Esparto - Fir - Japan - Ouricury - Palm - Rice-Oil - Sugar Cane - Ucuhuba - Cocoa Butter - 5. ANIMAL WAXES - Beeswax - Chinese Wax - Shellac Wax - Spermaceti - Wool Wax - PART 2. : SYNTHETIC WAXES 6. FATTY ALCOHOLS AND ACID - Cetyl Alcohol - Lanette Wax - Stearyl Alcohol - Stearic Acid - Palmitic Acid - Myristic Acid - 7. FATTY ACID ESTERS AND GLYCERIDES - Glyceryl Stearates - Glycol Fatty-Acid Stearates - Sorbitol Stearates - Polyethylene Glycol Stearates - Properties of Selected Commercial Products - 8. HYDROGENATED OILS - Properties of Selected Commercial Products - 9. KETONES, AMINES, AMIDES - Stearone, Laurone - Aliphatic Amines - Aliphatic Amides - Properties of Some Commercial Products - 10. CHLORONAPHTHALENES - 11. SYNTHETIC MINERAL WAXES - Fisher-Tropsch Waxes - Duroxon Waxes - 12. SYNTHETIC ANIMAL WAXES - Synthetic Beeswax - Modified Spermaceti Waxes - Modified Lanolin Waxes - 13. MISCELLANEOUS SYNTHETIC WAXES - Oxazoline - Experimental Waxes -

There is hardly a technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. - CONTENTS - I. Introduction - II. Adhesives - III. Beverages and Foods - IV. Cosmetics - V. Coatings - VI. Detergents - VII. Drugs - VIII. Metal Treatments - IX. Polishes - X. Elastomers, Polymers and Resins - XI. Miscellaneous - Appendix - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend conslderable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort.

There is hardly a technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. - CONTENTS - I. Introduction - II. Adhesives - III. Foods and Beverages - IV. Cosmetics - V. Coatings - VI. Detergents - VII. Drugs - VIII. Metal Treatments - IX. Polishes - X. Elastomers, Polymers and Resins - Xl. Miscellaneous - Appendix - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend conslderable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort.

There is hardly any technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. Chemists both experienced and beginner, continually refer to them. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. -CONTENTS - I. Introduction - II. Adhesives - III. Beverages and Foods - IV. Cosmetics - V. Coatings - VI. Detergents - VII. Drug Products - VIII. Metal Treatments - IX. Polishes - X. Textile Specialties - XI. Miscellaneous - Appendix - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend considerable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort. Manufacturers and sellers of chemicals will find, In these formulae, new uses for their products. Non-chemical executives, professional men, and Interested laymen will make through this volume a "speaking acquaintance" with products which they may be using, trying or selling. It often happens that two Individuals using the same Ingredients in the same formula get different results. This may be due to slight deviations in the raw materials or unfamiliarity with the intricacies of a new technique. Accordingly, repeated experiments may be necessary to get the best results. Although many of the formulas given are being used commercially, many have been taken from the literature and may be subject to various errors and omissions. This should be taken into consideration. Wherever possible, it is advisable to consult with other chemists or technical workers regarding commercial production.

CONTENTS - 1. AGRICULTURAL EMULSIONS - 2. BITUMINOUS EMULSIONS - 3. CLEANERS - 4. COSMETICS - 5. EMULSION POLYMERIZATION - 6. FOAMS AND ANTIFOAMS - 7. GASOLINE EMULSIONS - 8. FOOD EMULSIONS - 9. LEATHER AND PAPER TREATMENT EMULSIONS - 10. MEDICAL EMULSIONS - 11. CUTTING OILS, SOLUBLE OILS, MISCIBLE OILS - 12. PAINT - 13. POLISHES - 14. RESIN AND RUBBER EMULSIONS - 15. TEXTILE EMULSIONS - APPENDIX - Conversion Tables - Viscosity Comparison Chart - Color Standards Comparator - Temperature Conversion Table - Rate of Flow Chart - List of Emulsifying Agents - Suppliers of Emulsifying Agents - INDEX - FOREWARD - The first volume of Practical Emulsions has attempted to convey a general impression of the science of the formulation and manufacture of emulsions. Salient points have been presented in as simple a manner as possible, while detailed examination of specific points of the theory has been left to those whose qualifications and interests better fit them for such tasks. In this volume, I have compiled basic formulations of many types of emulsion. This compilation is intended to provide graphic illustration of the breadth of emulsion technology. The formulations can also provide a starting point for the development of new and improved emulsion products and represent the types of product that can be made and their major constituents. These formulations are provided by manufacturers to illustrate the use of their products. The suitability of any product for marketing, or the determination of the patent position regarding any formulation, is the responsibility of the person who manufactures and/or sells the product. Many firms have generously provided formulation suggestions, and they merit my sincere appreciation for their help. Their contributions are acknowledged by appropriate references at the end of each chapter.

There is hardly any technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. Chemists both experienced and beginner, continually refer to them. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. -CONTENTS - I. Introduction - II. Beverages and Foods - III. Coatings - IV. Cosmetics - V. Drug Products - VI. Detergents and Sanitizers - VII. Elastomers and Plastics - VIII. Metals - IX. Polishes - X. Textile Specialties - XI. Miscellaneous - Appendix - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend considerable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort. Manufacturers and sellers of chemicals will find, In these formulae, new uses for their products. Non-chemical executives, professional men, and Interested laymen will make through this volume a "speaking acquaintance" with products which they may be using, trying or selling. It often happens that two Individuals using the same Ingredients in the same formula get different results. This may be due to slight deviations in the raw materials or unfamiliarity with the intricacies of a new technique. Accordingly, repeated experiments may be necessary to get the best results. Although many of the formulas given are being used commercially, many have been taken from the literature and may be subject to various errors and omissions. This should be taken into consideration. Wherever possible, it is advisable to consult with other chemists or technical workers regarding commercial production.

There is hardly a technical library in the world in which the volumes of the Chemical Formulary (Volumes 1-34) do not occupy a prominent place. It does not duplicate any of the formulas included in previous volumes, but lists a wide array of modern and salable products from all branches of the chemical industries. An excellent reference for formulation problems. - CONTENTS - I. Introduction - II. Adhesives - III. Beverages and Food - IV. Cosmetics - V. Coatings - VI. Detergents and Disinfectants - VII. Drugs - VIII. Polishes, Abrasives - IX. Miscellaneous - Appendix - Trademark Chemicals - Trademark Chemicals Suppliers - Index - PREFACE - Chemistry, as taught in our schools and colleges, concerns chiefly synthesis, analysis, and engineering-and properly so. It is part of the right foundation for the education of the chemist. Many a chemist entering an Industry soon finds that most of the products manufactured by his concern are not synthetic or definite complex compounds, but are mixtures, blends, or highly complex compounds of which he knows little or nothing. The literature in this field, if any, may be meager, scattered, or obsolete. Even chemists with years of experience In one or more Industries spend conslderable time and effort in acquainting themselves with any new field which they may enter. Consulting chemists similarly have to solve problems brought to them from industries foreign to them. There was a definite need for an up-to-date compilation of formulae for chemical compounding and treatment. Since the fields to be covered are many and varied, an editorial board of chemists and engineers engaged in many industries was formed. Many publications, laboratories, manufacturing firms, and Individuals have been consulted to obtain the latest and best information. It is felt that the formulas given in this volume will save chemists and allied workers much time and effort.

In 1993, William J. Clinton began his eight year stint as forty-second president of the United States. A key figure of change in the Democratic Party, Clinton's political and personal actions ensured his lasting status as an important if controversial leader at a critical moment in recent American history. In Bill Clinton: Building a Bridge to the New Millennium, David H. Bennett traces Clinton's life and career from childhood through his two terms in the White House. From childhood to college, state government to the executive branch, Bennett provides a concise and readable biography that places Clinton's achievements, problems, and legacy in historical context. Situating the former president in the trajectory of 20th century liberalism, Bennett draws on Clinton's life to illuminate the political landscape of America in the 1990s and the role of the U.S. in the global context of the post-Cold War world. Combining keen scholarship with accessible prose, this will be an essential resource for students and all those interested in understanding the recent history of the U.S.

In 1993, William J. Clinton began his eight year stint as forty-second president of the United States. A key figure of change in the Democratic Party, Clinton's political and personal actions ensured his lasting status as an important if controversial leader at a critical moment in recent American history. In "Bill Clinton: Building a Bridge to the New Millennium," David H. Bennett traces Clinton's life and career from childhood through his two terms in the White House. From childhood to college, state government to the executive branch, Bennett provides a concise and readable biography that places Clinton's achievements, problems, and legacy in historical context.

Situating the former president in the trajectory of 20th century liberalism, Bennett draws on Clinton's life to illuminate the political landscape of America in the 1990s and the role of the U.S. in the global context of the post-Cold War world. Combining keen scholarship with accessible prose, this will be an essential resource for students and all those interested in understanding the recent history of the U.S.

This text is a compilation of practical information on the analysis of mineral type materials and products by the fused, cast bead method. It discusses the necessary equipment and its use; the processes involved in loss of ignition and decomposition by fusion and their chemistry. The book is also concerned with spectrometric parameters and the analytical procedures for a wide range of materials which, together with tables in the appendices, aim to allow easy reference to the parameters to be adopted to follow a defined procedure for most types of sample. The overall aim of the work is to help towards standardizing procedures, equipment and software, which should help to reduce costs and make for a better inter-laboratory comparison of results.

Originally published in 1955, this volume incorporates the substance of the Gregynog Lectures delivered at the University College of Wales, Aberystwyth during the Session 1952-3. The text was created to give an account of the lives of a few men and women of the fifteenth century, enabling the reader to understand something of what existence was like at that time. Chapters are included on the following figures: Humphrey, Duke of Gloucester; Sir John Fastolf; Thomas Hoccleve; Margaret Paston; Margery Kempe; Richard Bradwater. This book will be of value to anyone with an interest in British history and the fifteenth century.