Zeolites have unusual properties and as a result they are some of the most interesting inorganic materials known today. In contrast to conventional nanomaterials, zeolites exhibit a long-term stable inner void system on the nanometer scale and their properties are almost independent from the crystal size. This volume summarizes the known properties of natural zeolites and, importantly, shows how they can be synthesized by simulating the conditions of natural formation. Systematically, a direct correlation between the glassy precursor composition and that of the zeolite product is established. The zeolite crystal morphology obtained at given synthesis conditions allows direct conclusions on the conditions of formation in nature. This book is a valuable practical guide and tool for solid-state chemists, physicists, mineralogists and engineers.

More than seventeen years have passed now since Glauco Gottardi and Ermano Galli 1 have published their remarkable book on "NATURAL ZEOLITES" where properties and features of naturally occuring phases then available have been compiled. Several new natural zeolites have been found since then, but also natural counterparts ofzeolites which have only been known as synthesis products. The natural formation conditions of zeolites could only be deduced and estimated from their geological environment at the time when NATURAL ZEOLITES has been published, as zeolite synthesis was mainly focused on procedures at low pressures such as those introduced by Barrer and co workers'. Natural zeolites, however, had only been obtained "occasionally" and systematic study to reconstruct these formation conditions has not been performed ever since. This book is focused on the synthesis of natural zeolites by simulating the natural synthesis conditions in the laboratory which are essentially different in means and results from those obtained by conventional synthesis methods. Although the synthesis in the laboratory has undoubtly a great number of advantages over nature such as the employment of proper precursors or the choice of pressure and temperature in a wide range, the synthesis time is very limited in respect to natural conditions: synthesis times ofyears or even tens ofyears which would be necessary to obtain synthesis results for some zeolites- e.g. at 4 DegreesC (deep sea conditions) are rather unrealistic.