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"Nitrogen" Suppt. Vol. B 1 describes the compounds of nitrogen with
noble gases and, in the major part, binary compounds composed of
one nitrogen atom and hydrogen. Nitrogen hydrogen compounds with
two and more nitrogen atoms are covered in "Nitrogen" Suppt. Vol.
82. There is some information on various nitrogen-noble gas
species, to a large extent because of the interest in their bonding
behavior. Experimental data have been obtained chiefly for some
singly charged cations, particularly those formed by argon Like ArN
+ and ArNi. The existence of others has only been established by
mass spectrometry. The binary compounds of nitrogen and hydrogen
comprise NH, NH , NH , NH , the corre 2 4 5 sponding ions, and some
adducts. NH and NH1 are not treated. The predominant part 3 of the
volume covers the description of the molecules NH and NH . 8oth
species are present 2 in photolytic processes in the atmosphere.
They play an essential role in combustion systems regardless of
whether the nitrogen stems from the nitrogen-containing fuel or
from the air. Thus, much work has been devoted to the understanding
of the nitrogen chemistry in combustion and in the atmosphere. The
production and detection methods as weiL as the reactions have been
comprehensively described. ln addition detailed information is
given on the spectral behavior, the knowledge of which is important
for detecting the mole cules and for studying their kinetics.
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