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Since the early 1930's, Soviet chemists have played a lead ing role
in the study of unfamiliar oxidation state compounds of the
peroxide, superoxide, and ozonide types. Interest in the alkali and
alkaline earth metal derivatives is now widespread and diverse, and
numerous practical applications of these com pounds have evolved,
ranging from their use as air revitaliza tion materials in space
cabins to their use in compounding semiconductor materials.
Professor Vol'nov is eminently qualified to write this monograph
since for many years he has been a leading investi gator and
prolific writer in the field of peroxide, superoxide, and ozonide
chemistry. He has succeeded in presenting a lucid and detailed
discussion of past work, the present state, and the future
potential of this area of unfamiliar oxidation state chemistry. Of
particular interest is Professor Vol 'nov's extensive compilation
of available thermodynamic, kinetic, and structural data for the
alkali and alkaline earth peroxides, superoxides, and ozonides. In
addition, he has reviewed the known methods of synthesis, as well
as the practical applications for which these compounds are suited.
This monograph will be of interest and value to chemists, not only
for the information it imparts, but equally for the information it
does not impart, thereby illuminating the re search paths and
investigation which must be undertaken in order to increase our
knowledge concerning the chemistry of this important class of
chemical compounds."
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