NMR is a growing technique which represents a generalized, spread, common tool for spectroscopy and for structural and dynamic investigation. Part of the field of competence of NMR is represented by molecules with unpaired electrons, which are called paramagnetic. The presence of unpaired electrons is at the same time a drawback (negative effect) and a precious source of information about structure and dynamics. New phenomena and effects are described which are due to the high magnetic fields and advances in the methodology. "Solution NMR of Paramagnetic Molecules" is unique in dealing with these matters. The scope is that of presenting a complete description, which is both rigorous and pictorial, of theory and experiments of NMR of paramagnetic molecules in solution. Pertinent examples are described. From the time dependent behaviour of electrons in the various metal ions including polimetallic systems to the hyperfine-based information, and from NMR experiments to constraints for solution structure determination. The book's major theme is how to perform high resolution NMR experiments and how to obtain structural and dynamic information on paramagnetic metal ion containing systems.

Providing a broad overview of foundational concepts, this second edition of Fundamentals of Astronomy covers topics ranging from spherical astronomy to reference systems, and celestial mechanics to astronomical photometry and spectroscopy. It expounds arguments of classical astronomy that provided the foundation for modern astrometry, whilst presenting the latest results of the very-long-baseline interferometry (VLBI) radio technique, optical interferometers and satellites such as Hipparcos and GAIA, and recent resolutions of the IAU and IERS regarding precession, forced and free nutation, and Earth figure and rotation. Concepts of general relativity are explored, such as the advance of Mercury's perihelion, light deflection and black holes, in addition to the physical properties, orbits, and ephemerides of planets, comets and asteroids with an extension to visual binary stars orbital reconstruction. Extrasolar planets are also discussed, with reference to radial velocity and transits measurements by ground and space telescopes. Basic concepts of astronomical photometry, spectroscopy and polarimetry are given, including the influence of the terrestrial atmosphere. Classical works, such as Hipparchus, are mentioned in order to provide a flavor of the historical development of the field. It is an ideal textbook for undergraduate and graduate students studying astronomy, astrophysics, mathematics, and engineering. Supplementary and explanatory notes provide readers with references to additional material published in other literature and scientific journals, whilst solved and unsolved exercises allow students to review their understanding of the material. Features: Provides an introductory vision of arguments from spherical astronomy to celestial mechanics to astronomical photometry and spectroscopy Presents the information at an introductory level without sacrificing scientific rigor Fully updated throughout with the latest results in the field

Providing a broad overview of foundational concepts, this second edition of Fundamentals of Astronomy covers topics ranging from spherical astronomy to reference systems, and celestial mechanics to astronomical photometry and spectroscopy. It expounds arguments of classical astronomy that provided the foundation for modern astrometry, whilst presenting the latest results of the very-long-baseline interferometry (VLBI) radio technique, optical interferometers and satellites such as Hipparcos and GAIA, and recent resolutions of the IAU and IERS regarding precession, forced and free nutation, and Earth figure and rotation. Concepts of general relativity are explored, such as the advance of Mercury's perihelion, light deflection and black holes, in addition to the physical properties, orbits, and ephemerides of planets, comets and asteroids with an extension to visual binary stars orbital reconstruction. Extrasolar planets are also discussed, with reference to radial velocity and transits measurements by ground and space telescopes. Basic concepts of astronomical photometry, spectroscopy and polarimetry are given, including the influence of the terrestrial atmosphere. Classical works, such as Hipparchus, are mentioned in order to provide a flavor of the historical development of the field. It is an ideal textbook for undergraduate and graduate students studying astronomy, astrophysics, mathematics, and engineering. Supplementary and explanatory notes provide readers with references to additional material published in other literature and scientific journals, whilst solved and unsolved exercises allow students to review their understanding of the material. Features: Provides an introductory vision of arguments from spherical astronomy to celestial mechanics to astronomical photometry and spectroscopy Presents the information at an introductory level without sacrificing scientific rigor Fully updated throughout with the latest results in the field

NMR of Paramagnetic Molecules: Applications to Metallobiomolecules and Models, Second Edition is a self-contained, comprehensive reference for chemists, physicists, and life scientists whose research involves analyzing paramagnetic compounds. Since the previous edition of this book was published, there have been many advancements in the field of paramagnetic NMR spectroscopy. This completely updated and expanded edition contains the latest fundamental theory and methods for mastery of this analytical technique. Users will learn how to interpret the NMR spectra of paramagnetic molecules, improve experimental techniques, and strengthen their understanding of the underlying theory and applications.

This Handbook on Metalloproteins focuses on the available structural information of proteins and their metal ion coordination spheres. It centers on the metal ions indispensable for life but also considers metal ions used as substitution probes in studies of metalloproteins. Emphasizing the structure-function relationship, the book covers the common and distinct characterstics of metallo- enzymes, proteins, and amino acids bonded to copper, zinc, iron, and more.