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This book describes the physical basis of polarization modulation
infrared reflection-absorption spectroscopy and its application in
electrochemical studies. It provides a concise yet comprehensive
review of the research done in this field in the last 20 years.
Electrochemical methods are used to determine the rate and
mechanism of charge transfer reactions between an electrode and
species adsorbed or diffusing to its surface. In the past two
decades PM-IRRAS has grown to be one of the most important
vibrational spectroscopy techniques applied to investigate
structural changes taking place at the electrochemical interface.
The monograph presents foundations of this technique and reviews in
situ studies of redox-inactive and redox-active films adsorbed on
electrode surfaces. It also discusses experimental conditions
required in electrochemical and spectroscopic studies and presents
practical solutions to perform efficient experiments. As such, it
offers an invaluable resource for graduate and postgraduate
students, as well as for all researchers in academic and industrial
laboratories.
This book describes the physical basis of polarization modulation
infrared reflection-absorption spectroscopy and its application in
electrochemical studies. It provides a concise yet comprehensive
review of the research done in this field in the last 20 years.
Electrochemical methods are used to determine the rate and
mechanism of charge transfer reactions between an electrode and
species adsorbed or diffusing to its surface. In the past two
decades PM-IRRAS has grown to be one of the most important
vibrational spectroscopy techniques applied to investigate
structural changes taking place at the electrochemical interface.
The monograph presents foundations of this technique and reviews in
situ studies of redox-inactive and redox-active films adsorbed on
electrode surfaces. It also discusses experimental conditions
required in electrochemical and spectroscopic studies and presents
practical solutions to perform efficient experiments. As such, it
offers an invaluable resource for graduate and postgraduate
students, as well as for all researchers in academic and industrial
laboratories.
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