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While books have been written on many topics of Polymer Science,no
comp- hensive treatise o n l ong-chain b ranching has e ver b een c
omposed.This se ries o f reviews in Volume 142 an d 143 o f
Advances in P olymer Science tries to fill this gap by highlighting
active areas of research on branched polymers. Long-chain branching
is a p henomenon observed in s ynthetic polymers and in some
natural polysaccharides.It has l ong been r ecognized as a ma jor
molecular parameter of macromolecules.Its presence was first
surmised by H.Staudinger and G.V.Schulz
(Ber.68,2320,1935).Interestingly,their method of identifica- on b y
m eans o f the a bnormal r elation b etween in trinsic viscosity an
d mo lecular weight has s urvived to this day.Indeed,the most
sophisticated method for a- lysis o f long-chain b ranching use s
size ex clusion fractionation with the simul- neous recording of
mass,molecular weight and intrinsic viscosity of the fr- tions.
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