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In plating, electrochemical surface finishing, elec- trochemical
reactors as well as in electrochemical energy conversion, there is
an increasing demand for high speed and high efficiency processes.
These ob- jectives are largely influenced by cell design. The study
of such systems requires, besides know-how, a perfect scientific
insight into the interaction bet- ween electrode kinetics, cell
geometry and mass and charge transport. Needless to say, for that
purpose, computer modelling has gained rapidly in importance over
the last few years. Indeed, up to the 1960's, only problems with
rather simple geometries and amenable to analytical techni- ques
were treated. In 1964, Klingert et al. [60], as well as Fleck et
al. [42] outlined the first computer programs for calculating
current distributions by the finite dif- ference method. F~ve years
later, Riggs et al. [94J presented the first electrode shape change
simulations. They used also the finite difference method. In 1978,
Bergh [ 12J applied at first the - nite element method to predict
electrode shape changes. Since then, an increasing number of publi-
cations on-computer modelling of electrochemical sys- tems,
appeared. Mainly the finite difference or the finite element method
were used.
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