The human footprint on the global environment now touches every corner of the world. This book explores the myriad ways that environmental archives can be used to study the distribution and long-term trajectories of chemical contaminants. The volume first focuses on reviews that examine the integrity of the historic record, including factors related to hydrology, post-depositional diffusion, and mixing processes. This is followed by a series of chapters dealing with the diverse archives and methodologies available for long-term studies of environmental pollution, such as the use of sediments, ice cores, sclerochronology, and museum specimens.

The human footprint on the global environment now touches every corner of the world. This book explores the myriad ways that environmental archives can be used to study the distribution and long-term trajectories of chemical contaminants. The volume first focuses on reviews that examine the integrity of the historic record, including factors related to hydrology, post-depositional diffusion, and mixing processes. This is followed by a series of chapters dealing with the diverse archives and methodologies available for long-term studies of environmental pollution, such as the use of sediments, ice cores, sclerochronology, and museum specimens.

Numerical and statistical methods have rapidly become part of a palaeolimnologist s tool-kit. They are used to explore and summarise complex data, reconstruct past environmental variables from fossil assemblages, and test competing hypotheses about the causes of observed changes in lake biota through history. This book brings together a wide array of numerical and statistical techniques currently available for use in palaeolimnology and other branches of palaeoecology.

Visit http: //extras.springer.com the Springer's Extras website to view data-sets, figures, software, and R scripts used or mentioned in this book."

Chrysophycean algae are a diverse and often abundant group of primarily freshwater phytoplankton, characterized by the endogenous formation of siliceous cysts or stomatocysts (also called statospores or statocysts). Cyst morphology is highly variable, but believed to be species-specific. Recently, cysts have received considerable attention from phycologists and especially paleoecologists who wish to use these indicators for assessments of environmental change. Nonetheless, attempts at using cysts have often been hampered by taxonomic problems. This Atlas dispels some of the mystery surrounding stomatocysts, facilitating the accurate identification of individual cyst morphotypes, and encouraging other workers to begin using these important indicators. The terminology used to describe cysts is outlined in detail, followed by detailed descriptions of cyst morphotypes, following International Statospore Working Group (ISWG) guidelines, complemented by scanning electron and light micrographs, as well as line illustrations. Any available biogeographical and ecological information is also provided. These descriptions will further accelerate the continued effort to link cyst morphotypes to the algae that produce them. For paleoecologists who wish to include stomatocysts in their studies, researchers working with living chrysophycean algae, and those interested in the morphology and ultrastructure of cyst morphotypes.

Biology Distribution and ecology Taphonomy and preservation Field sampling and coring Laboratory procedures Data analysis and interpretation Summary Acknowledgements References 9. Chrysophyte scales and cysts. B. A. Zeeb & J. P. Smol 203 Introduction Taxonomy and nomenclature Methods Paleolimnological applications Future research directions Summary Acknowledgements References 10. Ebridians. A. Korhola & J. P. Smol 225 Introduction Morphology, taxonomy and preservation in the sediments Methodological aspects Brief history of use of ebridians in palaeoecological research Indicator value and future research priorities Summary Acknowledgements References 11. Phytoliths. D. R. Piperno 235 Introduction and history Phytolith production and taxonomy Laboratory methods Applications of phytolith analysis in lake sediments Summary of the major results Other potential applications of phytoliths in lake sediments Summary Acknowledgments References x 12. Freshwater sponges. 253 T. M. Frost Introduction Sponge species and their distribution Sponge life history Sponge spicules Paleolimnological studies using freshwater sponges Techniques for assessing sponge spicules in sediments Future applications of sponges in paleolimnology Summary Acknowledgements References 13. Siliceous protozoan plates and scales. M. S. V. Douglas & J. P. Smol 265 Introduction History and taxonomy Ecology Paleoecological potential Laboratory methods Data presentation Paleolimnological applications Other related siliceous indicators Summary Acknowledgements References 14. Biogenic silica. D.J. Conley & C.L Schelske 281 Introduction and history Methods Applications Future directions Summary Acknowledgements References 15. Sedimentary pigments.

Paleolimnology is a rapidly developing science that is now being used to study a suite of environmental and ecological problems. This volume is the fourth handbook in the Developments in Paleoenvironmental Research book series. The first volume (Last & Smol, 2001a) examined the acquisition and archiving of sediment cores, chronological techniques, and large-scale basin analysis methods. Volume 2 (Last & Smol, 2001b) focused on physical and chemical methods. Volume 3 (Smol et al. , 2001), along with this book, summarize the many biological methods and techniques that are available to study long-term environmental changeusing information preserved in sedimentary profiles. A subsequent volume (Birks et al. , in preparation) will deal with statistical and data handling procedures. It is our intent that these books will provide sufficient detail and breadth to be useful handbooks for both seasoned practitioners as well as newcomers to the area of paleolimnology. These books will also hopefully be useful to non-paleolimnologists (e. g. , limnologists, archeologists, palynologists, geographers, geologists, etc. ) who continue to hear and read about pal- limnology, but have little chance to explore the vast and sometimes difficult to access journal-based reference material for this rapidly expanding field. Although the chapters in these volumes target mainly lacustrine settings, many of the techniques described can also be readily applied to fluvial, glacial, marine, estuarine, and peatland environments. This current volume focuses on zoological indicators preserved in lake sediments, whilst Volume 3 focused on terrestrial, algal, and siliceous indicators.

Origins of fallout radionuclides Sediment records of fallout radionuclides Simple dating models Vertical mixing Numerical techniques Radiometric techniques Discussion Summary Acknowledgements References 10. chronostratigraphic techniques in paleolimnology. Svante Bjorck & Barbara Wohlfarth 205 Introduction Methods and problems Radiocarbon-dating different fractions of the sediment as a chronostratigraphic tool Dating of long (old) stratigraphies High resolution dating and wiggle matching dating versus absolute dating techniques of lacustrine sediments Concluding remarks Summary Useful www addresses Acknowledgements References 11. Varve chronology techniques. Scott Lamoureux 247 Introduction Methods Summary and future directions Acknowledgements References 12. Luminescence dating. Olav B. Lian & D. J. Huntley 261 Introduction The mechanism responsible for luminescence Dating and estimation of the paleodose Thermoluminescence dating Optical dating Evaluating the environmental dose rate xi Sample collection and preparation What types of depositional environments are suitable for luminescence dating? What can lead to an inaccurate optical age? Summary Acknowledgements References 13. Electron spin resonance (ESR) dating in lacustrine environments. Bonnie A. B. Blackwell 283 Introduction Principles of ESR analysis Sample collection ESR analysis ESR microscopy and other new techniques Applications and datable materials in limnological settings Summary Acknowledgements References 14. Use of paleomagnetism in studies of lake sediments. John King & John Peck 371 Introduction Recording fidelity of geomagnetic behavior by sediments Field and laboratory methods Holocene SV records Magnetostratigraphic studies of Neogene lake sediments Excursions, short events and relative paleointensity Conclusions Summary References 15. Amino acid racemization (AAR) dating and analysis in lacustrine environments."

Theory Instrumentation NIR analysis of sediment samples Uses of NIRS in palaeolimnology Future perspectives Summary References Fly-ash particles. Neil Rose 319 12. Introduction A brief history Methods of extraction and enumeration Temporal distribution Spatial distribution Source apportionment The future Summary Acknowledgements References Part III: Stable Isotope Techniques 13. Application of stable isotope techniques to inorganic and biogenic carbonates. Emi Ito 351 Introduction Nomenclature and systematics of lake-water Mg/Ca and Sr/Ca ratios of lake-water of dissolved inorganic carbon (DIC) Carbonates in lake-sediments Mollusks Ostracodes Charaphytes Isotope analysis Preparation of carbonate samples for isotope analysis Conclusions Summary Acknowledgments References 14. Carbon and oxygen isotope analysis of lake sediment cellulose: methods and applications. Brent B. Wolfe, Thomas W. D. Edwards, Richard J. Elgood & Kristina R. M. Beuning 373 xi Introduction Stable isotope tracers in lake Historical development Methods Key criteria for paleohydrologic reconstruction Applications Future research directions Summary Acknowledgements References Nitrogen isotopes in palaeolimnology. Michael R. Talbot 15. 401 Introduction Nitrogen in lakes: forms and distribution Nitrogen isotopes Nitrogen isotope studies in palaeolimnology: sampling and measurement Some examples Closing remarks Summary Acknowledgments References Glossary, acronyms and abbreviations 441 Index 493 xiii PREFACE The explosive growth of paleolimnology over the past two decades has provided impetus for the publication of this series of monographs detailing the numerous advances and new techniques being applied to the interpretation of lake histories. This is the second volume in the series and deals mainly with physical and geochemical analytical techniques.

This Atlas attempts to dispel some of the mystery surrounding stomatocysts, to facilitate the accurate identification of individual cyst morphotypes, and to encourage other workers to begin using these important indicators of environmental change. The terminology is outlined in detail. This is followed by detailed descriptions of cyst morphotypes, which continues from work completed in the first Atlas. Any available biogeographical and ecological information is also provided.
We believe this Atlas will be useful to paleoecologists who wish to include stomatocysts in their studies. We also expect this book will be used by researchers working with living chrysophytes, and those interested in the morphology and ultrastructure of cyst morphotypes. Hopefully these descriptions will further accelerate the continued effort to link cyst morphotypes to the algae that produce them.

Concerns about the effects of global climate change have focused attention on the vulnerability of circumpolar regions. Long-term historical data are needed to better understand the magnitude and direction of environmental change related to both natural and anthropogenic causes, as well as to assess patterns of natural variability. The paucity of instrumental data requires that proxy methods be used. The abundance of lakes throughout the Arctic and Antarctic makes paleolimnological approaches especially powerful tools to assist interpretations of environmental change.

This book provides a synthesis of the broad spectrum of techniques available for generating long-term environmental records from circumpolar lakes. It also provides overviews of the geographic extent of paleolimnological work completed thus far in these regions. It explores the diverse ways in which paleolimnology is used to address the pressing and emerging environmental issues of high-latitude regions. By providing both an introduction and in-depth reviews, this volume is of interest to students and advanced researchers alike who are studying earth, atmospheric and environmental sciences.

During the last few years, lake acidification has become a topic of international interest because of the detrimental effects of this problem on lake ecosystems. The stratigraphic record of diatoms and other paleoindicators in lake sediments has been used increasingly to document past limnological conditions. Because many diatom taxa are sensitive indicators of lakewater pH, this approach is especially useful in assessing impacts of atmospheric pollutants and watershed land use on lake pH. The idea that a book be prepared on this subject originated at a workshop entitled 'Reconstructing pH from sedimentary diatom remains - recent insights and update on methods' organized by R.B. Davis and held at the XXII Congress of the International Association of Limnology at Lyon, France in August 1983. At this workshop, presentations were made by many of the authors in this volume. The rapid progress in this field was evident when a second workshop, this time organized by R.W. Battarbee and R.J. Flower, was held one year later at the VII International Symposium on Diatoms at Paris, France. Many individuals helped with the preparation of this volume, most notable were our referees, who thoughtfully reviewed the manuscripts and suggested many improvements. I would also like to thank my colleagues at Queen's University who helped in innumerable ways over the last two years. A special word of gratitude is due to Dr. M.M. Boucherle, Dr. S.R. Brown, Ms. T.C. Oliver, and Mr. P.R. Leavitt. J.

During the last few years, lake acidification has become a topic of international interest because of the detrimental effects of this problem on lake ecosystems. The stratigraphic record of diatoms and other paleoindicators in lake sediments has been used increasingly to document past limnological conditions. Because many diatom taxa are sensitive indicators of lakewater pH, this approach is especially useful in assessing impacts of atmospheric pollutants and watershed land use on lake pH. The idea that a book be prepared on this subject originated at a workshop entitled 'Reconstructing pH from sedimentary diatom remains - recent insights and update on methods' organized by R.B. Davis and held at the XXII Congress of the International Association of Limnology at Lyon, France in August 1983. At this workshop, presentations were made by many of the authors in this volume. The rapid progress in this field was evident when a second workshop, this time organized by R.W. Battarbee and R.J. Flower, was held one year later at the VII International Symposium on Diatoms at Paris, France. Many individuals helped with the preparation of this volume, most notable were our referees, who thoughtfully reviewed the manuscripts and suggested many improvements. I would also like to thank my colleagues at Queen's University who helped in innumerable ways over the last two years. A special word of gratitude is due to Dr. M.M. Boucherle, Dr. S.R. Brown, Ms. T.C. Oliver, and Mr. P.R. Leavitt. J.

Paleolimnology is a rapidly developing science that is now being used to study a suite of environmental and ecological problems. This volume is the fourth handbook in the Developments in Paleoenvironmental Research book series. The first volume (Last & Smol, 2001a) examined the acquisition and archiving of sediment cores, chronological techniques, and large-scale basin analysis methods. Volume 2 (Last & Smol, 2001b) focused on physical and chemical methods. Volume 3 (Smol et al. , 2001), along with this book, summarize the many biological methods and techniques that are available to study long-term environmental changeusing information preserved in sedimentary profiles. A subsequent volume (Birks et al. , in preparation) will deal with statistical and data handling procedures. It is our intent that these books will provide sufficient detail and breadth to be useful handbooks for both seasoned practitioners as well as newcomers to the area of paleolimnology. These books will also hopefully be useful to non-paleolimnologists (e. g. , limnologists, archeologists, palynologists, geographers, geologists, etc. ) who continue to hear and read about pal- limnology, but have little chance to explore the vast and sometimes difficult to access journal-based reference material for this rapidly expanding field. Although the chapters in these volumes target mainly lacustrine settings, many of the techniques described can also be readily applied to fluvial, glacial, marine, estuarine, and peatland environments. This current volume focuses on zoological indicators preserved in lake sediments, whilst Volume 3 focused on terrestrial, algal, and siliceous indicators.

Biology Distribution and ecology Taphonomy and preservation Field sampling and coring Laboratory procedures Data analysis and interpretation Summary Acknowledgements References 9. Chrysophyte scales and cysts. B. A. Zeeb & J. P. Smol 203 Introduction Taxonomy and nomenclature Methods Paleolimnological applications Future research directions Summary Acknowledgements References 10. Ebridians. A. Korhola & J. P. Smol 225 Introduction Morphology, taxonomy and preservation in the sediments Methodological aspects Brief history of use of ebridians in palaeoecological research Indicator value and future research priorities Summary Acknowledgements References 11. Phytoliths. D. R. Piperno 235 Introduction and history Phytolith production and taxonomy Laboratory methods Applications of phytolith analysis in lake sediments Summary of the major results Other potential applications of phytoliths in lake sediments Summary Acknowledgments References x 12. Freshwater sponges. 253 T. M. Frost Introduction Sponge species and their distribution Sponge life history Sponge spicules Paleolimnological studies using freshwater sponges Techniques for assessing sponge spicules in sediments Future applications of sponges in paleolimnology Summary Acknowledgements References 13. Siliceous protozoan plates and scales. M. S. V. Douglas & J. P. Smol 265 Introduction History and taxonomy Ecology Paleoecological potential Laboratory methods Data presentation Paleolimnological applications Other related siliceous indicators Summary Acknowledgements References 14. Biogenic silica. D.J. Conley & C.L Schelske 281 Introduction and history Methods Applications Future directions Summary Acknowledgements References 15. Sedimentary pigments.

Theory Instrumentation NIR analysis of sediment samples Uses of NIRS in palaeolimnology Future perspectives Summary References Fly-ash particles. Neil Rose 319 12. Introduction A brief history Methods of extraction and enumeration Temporal distribution Spatial distribution Source apportionment The future Summary Acknowledgements References Part III: Stable Isotope Techniques 13. Application of stable isotope techniques to inorganic and biogenic carbonates. Emi Ito 351 Introduction Nomenclature and systematics of lake-water Mg/Ca and Sr/Ca ratios of lake-water of dissolved inorganic carbon (DIC) Carbonates in lake-sediments Mollusks Ostracodes Charaphytes Isotope analysis Preparation of carbonate samples for isotope analysis Conclusions Summary Acknowledgments References 14. Carbon and oxygen isotope analysis of lake sediment cellulose: methods and applications. Brent B. Wolfe, Thomas W. D. Edwards, Richard J. Elgood & Kristina R. M. Beuning 373 xi Introduction Stable isotope tracers in lake Historical development Methods Key criteria for paleohydrologic reconstruction Applications Future research directions Summary Acknowledgements References Nitrogen isotopes in palaeolimnology. Michael R. Talbot 15. 401 Introduction Nitrogen in lakes: forms and distribution Nitrogen isotopes Nitrogen isotope studies in palaeolimnology: sampling and measurement Some examples Closing remarks Summary Acknowledgments References Glossary, acronyms and abbreviations 441 Index 493 xiii PREFACE The explosive growth of paleolimnology over the past two decades has provided impetus for the publication of this series of monographs detailing the numerous advances and new techniques being applied to the interpretation of lake histories. This is the second volume in the series and deals mainly with physical and geochemical analytical techniques.

Origins of fallout radionuclides Sediment records of fallout radionuclides Simple dating models Vertical mixing Numerical techniques Radiometric techniques Discussion Summary Acknowledgements References 10. chronostratigraphic techniques in paleolimnology. Svante Bjorck & Barbara Wohlfarth 205 Introduction Methods and problems Radiocarbon-dating different fractions of the sediment as a chronostratigraphic tool Dating of long (old) stratigraphies High resolution dating and wiggle matching dating versus absolute dating techniques of lacustrine sediments Concluding remarks Summary Useful www addresses Acknowledgements References 11. Varve chronology techniques. Scott Lamoureux 247 Introduction Methods Summary and future directions Acknowledgements References 12. Luminescence dating. Olav B. Lian & D. J. Huntley 261 Introduction The mechanism responsible for luminescence Dating and estimation of the paleodose Thermoluminescence dating Optical dating Evaluating the environmental dose rate xi Sample collection and preparation What types of depositional environments are suitable for luminescence dating? What can lead to an inaccurate optical age? Summary Acknowledgements References 13. Electron spin resonance (ESR) dating in lacustrine environments. Bonnie A. B. Blackwell 283 Introduction Principles of ESR analysis Sample collection ESR analysis ESR microscopy and other new techniques Applications and datable materials in limnological settings Summary Acknowledgements References 14. Use of paleomagnetism in studies of lake sediments. John King & John Peck 371 Introduction Recording fidelity of geomagnetic behavior by sediments Field and laboratory methods Holocene SV records Magnetostratigraphic studies of Neogene lake sediments Excursions, short events and relative paleointensity Conclusions Summary References 15. Amino acid racemization (AAR) dating and analysis in lacustrine environments."

This much revised and expanded edition provides a valuable and detailed summary of the many uses of diatoms in a wide range of applications in the environmental and earth sciences. Particular emphasis is placed on the use of diatoms in analysing ecological problems related to climate change, acidification, eutrophication, and other pollution issues. The chapters are divided into sections for easy reference, with separate sections covering indicators in different aquatic environments. A final section explores diatom use in other fields of study such as forensics, oil and gas exploration, nanotechnology, and archaeology. Sixteen new chapters have been added since the first edition, including introductory chapters on diatom biology and the numerical approaches used by diatomists. The extensive glossary has also been expanded and now includes over 1,000 detailed entries, which will help non-specialists to use the book effectively.

This much revised and expanded edition provides a valuable and detailed summary of the many uses of diatoms in a wide range of applications in the environmental and earth sciences. Particular emphasis is placed on the use of diatoms in analysing ecological problems related to climate change, acidification, eutrophication, and other pollution issues. The chapters are divided into sections for easy reference, with separate sections covering indicators in different aquatic environments. A final section explores diatom use in other fields of study such as forensics, oil and gas exploration, nanotechnology, and archaeology. Sixteen new chapters have been added since the first edition, including introductory chapters on diatom biology and the numerical approaches used by diatomists. The extensive glossary has also been expanded and now includes over 1,000 detailed entries, which will help non-specialists to use the book effectively.